In recent years, air pollution in China has posed serious threats to human health. In this study, we investigate the relationship between air pollution and residents’ health by nesting the household registration data of the China Migrant Dynamic Survey in 2014 with city characteristic data and pollution data. The results indicated that an increase in the concentration of air pollution significantly reduced residents’ health levels. After using the instrumental variable (IV)-Oprobit model to solve endogenous problem, we have found that the negative impact of air pollution on residents’ health remained significant. Moreover, the lag term of environmental indexes was introduced and found that air pollution significantly increased health risk. The results also demonstrated that the impact of air pollution on human health was heterogeneous. Men and urban residents were more sensitive to air pollution and more adversely affected. In addition to air pollution, the study found that, among the influencing factors at the individual level, males’ health was better than females’ health, and education positively impacted on residents’ health. The health effects were consistent with the theoretical predictions of the Grossman model. The financial expenditure and medical input were negatively correlated with residents’ health levels. Based on the results, we suggest the Chinese government should implement rigorous air pollution laws and regulations.

In recent years, biochar has received a significant amount of attention for its potential beneficial applications in various fields due to its bio-physico-chemical properties. The spent coffee ground biochar was prepared by slow pyrolysis for adsorption of 16-polycyclic aromatic hydrocarbons (PAHs) in ambient air. New materials and extraction methods were developed for PAHs analysis, particularly for low molecular weight (2–4 rings) PAHs, which are likely to evaporate at room temperature. Production and characterization of biochar and its extraction parameters after PAHs adsorption were investigated and optimized. The biochar production at 500 °C provided adequate quality for PAHs adsorption with a 35% yield. An effective clean-up method for biochar was proposed. A new method of PAHs extraction from biochar was developed using 25 mL of a mixture of dichloromethane and 2-propanol (4:1) for 30 min at low temperatures (5–10 °C). A test on the efficiency of the extraction method was carried out and recoveries of 85–104% of PAHs were obtained. The lab-made biochar was also tested for its potential in ambient PAHs sampling and compared with a commercial sorbent (XAD-2). The results revealed that almost the same concentrations of ambient PAHs (ng/m³) were absorbed by both sorbent types, particularly with regard to the 4 ring-PAHs.

In the last years, the upgrading of wastewater treatment plants (WWTPs) could be required in order to comply with the more stringent regulation requirements. Nevertheless, the main issue is related to the surface availability. A proper solution could be represented by the attached biomass processes, in particular the moving bed biofilm reactors (MBBR), that have a significant footprint reduction with respect to conventional activated sludge (CAS). However, MBBR showed an important disadvantage: the poor aeration energy efficiency due to the use of coarse bubble diffusers, which guarantee high reliability and low maintenance costs with respect to fine bubble ones. Moreover, the presence of carriers inside the reactor emphasizes this aspect. The aim of this work is to verify the benefits achievable by installing a fine bubble aeration system inside a MBBR system. The comparison, in terms of oxygen transfer efficiency, between a medium bubble aeration system and a fine ceramic bubble diffuser was studied and the effect of biofilm growth on oxygen transfer was assessed. Several tests were carried out in order to test the operation of a coarse and a fine bubble side aeration at different air flow rates, both in clean water conditions, in order to evaluate the influence of carriers (Chip M type) on the aeration efficiency, both in wastewater conditions with the aim to assess the effect of bacteria growth on the carriers. The main results are the following: (i) the fine bubble system placed off-center ensured good mixing even without using the mixer; (ii) the fine bubble side aeration system compared to the coarse ones did not show significant advantages in terms of oxygen transfer efficiency; (iii) the increase in specific air flow rate negatively influenced the aeration efficiency; (iv) the presence of biomass had a positive effect on the oxygen transfer yield.

Intertidal macroalgae suffer different environmental conditions and mat densities during growing period. In the present study, Ulva lactuca Linnaeus were collected from high, intermediate, and low tidal zones at Nan’ao Island, China. These algal photosynthetic pigments and photosynthesis behaviors with different mat densities were measured. The aim is to examine how the physiological responses and acclimation match the representative tidal distribution and algal mat density. The photosynthetic pigment (chlorophyll a and carotenoid) contents and irradiance-saturated maximum photosynthetic rates (Pₘₐₓ) were greater in low zone–grown U. lactuca compared with the algae grown at high and intermediate zones. Under low algal mat density, the Pₘₐₓ, apparent photosynthetic efficiency (α), and dark respiration rate (Rd) of U. lactuca grown at low zone were increased, whereas the irradiance saturation points (Iₖ) were decreased, compared with the algae grown at higher zone. However, the Pₘₐₓ of high and intermediate zone–grown U. lactuca at high algal mat density were greater than at low density. Moreover, the pH compensation point of low zone–grown thalli (9.98) was lower than the higher zone–grown thalli (more than 10.15); however, the chlorophyll fluorescence parameters (reflect photosynthetic system activity) of the thalli collected from the three different zones were similar. Therefore, we proposed that the effects of varied densities on the photosynthetic rates of these three tidal zone–grown U. lactuca thalli were different, which might be related with different capacity of HCO₃⁻ utilization of macroalgae at their zonations.

Selective estrogen receptor modulators such as tamoxifen (TAM) significantly reduce the risks of developing estrogen receptor–positive (ER+) breast cancer. Low concentrations (nanomolar range) of bisphenol A (BPA) shows estrogenic effects and further promotes the proliferation of hormone-dependent breast cancer cells. However, whether or not BPA can influence TAM-treatment resistance in breast cancer has not drawn much attention. In the current study, low concentrations of BPA reduced TAM-induced cytotoxicity of MCF-7 cells, which was proved by the suppression of cell apoptosis, transition of cell cycle from G1 to S phase, and upregulation of cyclin D1 and ERα. Simultaneously, the mRNA levels of estrogen-related receptor γ (ERRγ) and its coactivators, peroxisome proliferation–activated receptor γ coactivator-1α (PGC-1α), and PGC-1β, were increased. However, the similar effects were not observed in MDA-MB-231 cells. Our results indicated that low concentrations of BPA decreased the sensitivity of TAM in MCF-7 cells rather than in MDA-MB-231 cells. These different actions likely involved the interaction of relative receptors and coactivators. This study provided a possible support that the exposure of BPA in environmental media may potentially induce TAM resistance to breast cancer treatment.

Microalgae are key test organisms to assess the effects of chemicals on aquatic ecosystems. Zinc oxide nanoparticles (ZnO NPs) as a widely used metal oxide is considered a potential threat to these primary producers at the base of the food chain. This study investigates the toxicity of ZnO NPs, bulk ZnO, and Zn²⁺ to the representative of freshwater microalgae, Raphidocelis subcapitata. To examine the effect of shape and size of nanoparticles, two types of spherical ZnO NPs with different sizes (20 and 40 nm) and two types of rod-shaped ZnO NPs with different lengths (100 and 500 nm) were synthesized. Microalgal cells were exposed to eight concentrations of each ZnO NP type from 0.01 to 0.7 mg/L for 96 h. The results showed that 0.7 mg/L of ZnO NP could completely inhibit algal growth. Size did not interfere with toxicity in spherical ZnO NPs, but the toxicity decreased by increasing the size of rod-shaped ZnO NPs. Spherical ZnO NPs acted more destructive to microalgal cells than nanorod shape. The addition of 0.7 mg/L of ZnO nanorods to samples caused 30% cell death, while 50% cell death was observed by adding the same concentration of nanospherical ZnO. Nano ZnO revealed to be more toxic than bulk ZnO and Zn²⁺. The Zn²⁺ released from dissolution of ZnO NPs was one of the sources of toxicity, but the ZnO nanostructures were also an important factor in the toxicity.

Global DNA methylation, as an epigenetic modifications, can be a promising genomic marker for monitoring the contaminants and predicting their adverse health effects. The study aims to assess the effects of 16 PAH concentration on the altered DNA methylation levels in the kidney and liver of rock pigeon (Columba livia), as a sentinel species, from Tehran megacity as well as 40 days benzo(a)pyrene in vitro exposure: (0.1, 2.5, 5, 7.5, and 10 mg kg⁻¹ bw). Data indicated that the total LMW-PAH (low molecular weight PAHs) group (120.22, 121.34, 103.69, and 128.79 ng g⁻¹ dw in liver, kidney, skin, and muscle, respectively) in the Tehran samples have higher levels than the other PAHs groups. In addition, the DNA methylation level had negative relation with the total amount of PAHs in liver and kidney. A comparatively higher global DNA hypomethylation (by 8.65% in liver and 3.76% in kidney) was observed in birds exposed to B(a)P. Our results lead us to suggest that DNA hypomethylation in liver and kidney associated with the B(a)P may be useful biomarker discovery (more than the amount of PAH concentration in different tissues of C. livia) in urban areas. In conclusion, based on the overall results assessed, DNA methylation changes in pigeon may show a new target pathway for evaluation of environmental health.

Nitrous acid (HONO) is an important atmospheric pollutant that can strongly absorb ultraviolet irradiation in the region of 300–400 nm, as previously reported. Since the solar irradiance that reaches the surface of the earth has wavelengths greater than 290 nm, the photodissociation of HONO is considered the major method of hydroxyl radical formation in the troposphere. Thus, the photoinduced chemical reactivity of HONO is important. The present work investigated the reaction mechanism and kinetic parameters of HONO and sulfamethazine by using a laser flash photolysis technique and liquid chromatography-mass spectrometry. The results indicated that the sulfamethazine degradation rate was influenced by the HONO concentration and the initial concentration of sulfamethazine. Hydroxyl radicals derived from the photolysis of HONO attacked the aromatic ring of sulfamethazine to form sulfamethazine-OH adducts with a second-order rate constant of (3.8 ± 0.3) × 10⁹ L mol⁻¹ s⁻¹. This intermediate would then react with HO· and oxygen molecules. The reaction rate constants of sulfamethazine-OH adducts with oxygen are (1.3 ± 0.1) × 10⁷ L mol⁻¹ s⁻¹. The generation of sulfanilic acid and pyrimidine implies that the breaking down of S–N bonds of sulfamethazine and its HO adducts probably occur at the same time.

In this paper, the modified multi-walled carbon nanotubes were prepared by β-cyclodextrin denoted as β-CD-MWNTs. The structure and morphology of β-CD-MWNTs was characterized by TEM and the dynamic adsorption of p-nitrophenol on β-CD-MWNTs was studied by the Thomas model. Some affecting factors of dynamic adsorption and the adsorbent regeneration process such as the sewage concentration, the amount of absorbent in column, including the type of reagent, solid-liquid ratio, regeneration time, and regeneration times were investigated and optimized. The results indicated that the p-nitrophenol removal rate could reach 84% under stuffing 2 g β-CD-MWNTs. The curves of p-nitrophenol’s dynamic adsorption conformed to the Thomas model. Moreover, the adsorption capacity of regenerated β-CD-MWNTs was similar to the fresh β-CD-MWNT column. The optimal conditions of regenerations of β-CD-MWNTs were shown as follows: the type of reagent is anhydrous ethanol, the solid-liquid ratio is 200:40 (mg/mL) and the regeneration time is 120 min.

In this study, forward osmosis (FO) membranes and fouling solutions were systematically characterized to elucidate the effects of organic fouling on the rejection of two pharmaceutically active compounds, namely, sulfamethoxazole and carbamazepine. Municipal wastewater resulted in a more severe flux decline compared to humic acid and sodium alginate fouling solutions. This result is consistent with the molecular weight distribution of these foulant solutions. Liquid chromatography with organic carbon detection analysis shows that municipal wastewater consists of mostly low molecular weight acids and neutrals, which produce a more compact cake layer on the membrane surface. By contrast, humic acid and sodium alginate consist of large molecular weight humic substances and biopolymers, respectively. The results also show that membrane fouling can significantly alter the membrane surface charge and hydrophobicity as well as the reverse salt flux. In particular, the reverse salt flux of a fouled membrane was significantly higher than that under clean conditions. Although the rejection of sulfamethoxazole and carbamazepine by FO membrane was high, a discernible impact of fouling on their rejection could still be observed. The results show that size exclusion is a major rejection mechanism of both sulfamethoxazole and carbamazepine. However, they respond to membrane fouling differently. Membrane fouling results in an increase in sulfamethoxazole rejection while carbamazepine rejection decreases due to membrane fouling.