One of the major problems the world is currently facing is climate change. This is due to the use of fossil fuel combustion, which increases the presence of CO₂ emissions and other greenhouse gases in the atmosphere in several countries of the world, which Nigeria is not exempted from. Against this background, this study examines the impacts of globalization, real income, urbanization, and energy consumption on environmental degradation; and proffer way forward to achieving environmental sustainability targets in Nigeria, using quarterly frequency time series data over a period 1971–2018. To achieve our study objectives, this study makes use of quantile-quantile (Q-Q) approach, developed by Sim and Zhou J Bank Financ 55:1–8, (2015). This approach groups together nonparametric estimation and quantile regression. Empirical results show that, in all quantiles, globalization, real income, urbanization, and energy consumption impact positively on environmental degradation. Thus, we are of the opinion that for the nation to achieve any meaningful environmental sustainability targets, (i) it must shift from economic activities that are dependent and driven by non-renewable energy sources; (ii) enact environmental laws and regulations that prevent indigenous and multinationals firms from using non-renewable energy sources in production activities; (iii) discourage rural-urban migration by enacting policies that would improve life in the rural areas, such as diverting investment of indigenous and multinational companies to be situated in the rural areas; and lastly, (iv) learn from jurisdictional experiences that have successfully replaces non-renewable energy sources with renewable ones for an overall economic growth and environmental sustainability targets for both the immediate and future generations.

In this applied research work, the risk of rock instability in the Aqabat Al-Sulbat road section located in the north-west area of Aseer Province in Saudi Arabia was evaluated, and the primary natural trigger factors of rock slope instability on further environmental components (rock slope stability, road network, and urban areas) were estimated using satellite images (Landsat8), digital terrain models, and geoprocessing in geographical information systems software (classification, overlapping algorithms and production thematic mapping in Arctoolbox). Additionally, field geotechnical investigations testing and over-coring drilling sampling allowed the characterization of the section of road in terms of geological structure and environmental components (geology, morphology, road network, lineaments, and hydrology). As a result, rock slope instability vulnerability mapping was simulated using satellite imagery and geographical information systems (GIS) and ranking natural trigger factors using the combined fuzzy Delphi analytical hierarchic process with the technique for order performance by similarity to ideal solution (TOPSIS) as multiple-criteria decision-making (MCDM) techniques. Additionally, many rock layer discontinuity stations were implemented to evaluate rock slope instabilities, and these were visualized using the Dips program and combined with modeling using 3DEC software to predict rock slope failure based on the distinct element method (DEM) at a small scale. Thereafter, safety factors were computed depending on these previous geospatial data. Finally, vulnerability index mapping was combined with rock instability risk mapping for the Aqabat Al-Sulbat road. Within the framework of sustainable development, these results can be used to inform the urban planning of the municipality of Aseer Province.

This study sought to identify the spatial, temporal, and spatiotemporal clusters of COVID-19 cases in 366 cities in mainland China with the highest risks and to explore the possible influencing factors of imported risks and environmental factors on the spatiotemporal aggregation, which would be useful to the design and implementation of critical preventative measures. The retrospective analysis of temporal, spatial, and spatiotemporal clustering of COVID-19 during the period (January 15 to February 25, 2020) was based on Kulldorff’s time-space scanning statistics using the discrete Poisson probability model, and then the logistic regression model was used to evaluate the impact of imported risk and environmental factors on spatiotemporal aggregation. We found that the spatial distribution of COVID-19 cases was nonrandom; the Moran’s I value ranged from 0.017 to 0.453 (P < 0.001). One most likely cluster and three secondary likely clusters were discovered in spatial cluster analysis. The period from February 2 to February 9, 2020, was identified as the most likely cluster in the temporal cluster analysis. One most likely cluster and seven secondary likely clusters were discovered in spatiotemporal cluster analysis. Imported risk, humidity, and inhalable particulate matter PM₂.₅ had a significant impact on temporal and spatial accumulation, and temperature and PM₁₀ had a low correlation with the spatiotemporal aggregation of COVID-19. The information is useful for health departments to develop a better prevention strategy and potentially increase the effectiveness of public health interventions.

BACKGROUND: Bisphenol A (BPA) is found in many medical materials used in the paediatric intensive care unit (PICU). Our aim was to evaluate how the urinary free-BPA(fBPA) and total-BPA(tBPA) levels were associated with the use of medical devices in the PICU in a prospective study. METHODS: The procedures applied to the patient were recorded during the follow-up period. Three urine samples were taken on the first day of hospitalization; the seventh day, and after 30 days or when the patients were discharged. Urinary tBPA and fBPA levels were determined using high-pressure liquid chromatography. Generalized estimating equations with repetitive measures were used to determine the associations between PICU procedures and BPA levels. RESULTS: A total of 115 urine samples of 40 children were studied. Mean urinary levels were 189.2 μg/g-creatinine for tBPA and 27.8 μg/g-creatinine for fBPA, and the fBPA/tBPA ratio was 27.9%. Endotracheal intubation, catheter, and haemodialysis procedures caused higher urinary fBPA levels. External drains, inhaler treatment, and the use of four or more medical devices were associated with considerably higher values of fBPA%. The increase in tBPA was positively correlated with fBPA. CONCLUSIONS: fBPA levels and the fBPA/tBPA ratio varied according to the procedure and level of BPA exposure in children.

This paper uncover a new perception of the dynamic interconnection between CO₂ emission and economic growth, renewable energy use, trade openness, and technological innovation in the Portuguese economy utilizing innovative Morlet wavelet analysis. The research applied continuous wavelet transform, wavelet correlation, the multiple and partial wavelet coherence, and frequency domain causality analyses are applied on variables of investigation using dataset between 1980 and 2019. The result of these analyses disclosed that the interconnection among the indicators progresses over time and frequency. The present analysis finds notable wavelet coherence and significant lead and lag interconnections in the frequency domain, while conflicting relationships among the variables are found in the time domain. The wavelet analysis according to economic viewpoint affirms that renewable energy consumption helps to curb CO₂ while trade openness, technological innovation, and economic growth contribute to CO₂. The outcomes also proposed that renewable energy consumption decreases CO₂ in medium and long run in Portugal. Therefore, policymakers in Portugal should stimulate investment in renewable energy sources, establish restrictive laws, and enhance energy innovation.

Present work evaluated the zinc (Zn) concentration in soil, forage, blood plasma, hair, and feces samples of cows, buffaloes, and sheep taken from Mianwali, Punjab, Pakistan. The concentration of Zn was found in the ranged of 21.82–35.09mg/kg, 32.59–42.17mg/kg, 0.927–2.48mg/l, 1.03–2.84mg/kg, and 0.923–1.98mg/kg in soil, forage, blood plasma, hair, and feces samples, respectively. The Zn concentration in soil, forage, blood, hair, and feces was safer compared to standard limits. Statistical analysis described that values for BCF, PLI, EF, DIM, and HRI ranged 1.03–1.57mg/kg, 0.486–0.782mg/kg, 0.457–0.696mg/kg, 0.048–0.08mg/kg, and 0.160–0.272mg/kg, respectively. It can be concluded from the present work that Zn concentration was safe in soil, forages, and animal samples. BCF was noticed as greater than 1 while PLI, EF, DIM, and HRI were found less than 1, so regular heavy metal analysis was required to appraise the contamination level in environment.

Three-dimensional carbon aerogel (CA800) was prepared from waste corrugated cardboard (WCC) by the procedure of slurrying, solvent replacement, drying, and carbonization in turn, and the product was explored as an all-in-one evaporator for solar steam generation without bulk water. Carbonization of the precursor was investigated using thermogravimetric analyzer coupled with Fourier transform infrared spectrometer. Results showed that CO₂, CO, furfural, and levoglucosan were released during pyrolysis of WCC within the range of 300 to 390 °C, while polymerization of newly formed char between 390 and 580 °C mainly resulted in the formation of CO₂ and CO. Both pyrolysis and polymerization reactions can be described by diffusion-controlled mechanisms, and the activation energies were 155.62 and 11.17 kJ mol⁻¹, respectively. CA800 possessed a BET surface area of 210 m² g⁻¹. Light can be effectively absorbed and converted into heat by CA800, and its surface temperature achieving 73 °C under 1 kW m⁻² irradiation. CA800 had outstanding wettability due to the presence of hydrophilic minerals in carbon matrix, and it was able to store as much as 15 times its own weight in water due to its abundant interconnected channels and hierarchical nanopores. Solar-driven water evaporation rate over CA800 achieved 1.72 kg m⁻² (normalized to projection area), which was nearly 6 times higher than the value achieved by the bare water system. The photothermal conversion efficiency was calculated to be 118 %, and the overestimated efficiency was caused by the environmental energy gained by the cold evaporation surface of CA800.

The phytoremediation efficiency is largely depends on the bioavailability of heavy metal in soil. The activity of earthworms and oxidation of elemental sulfur (S⁰) in soil has influence on heavy metal speciation transformation in soil. By conducting pot experiment, we examined the possibility of enhancing phytoextraction efficiency of lead (Pb) in soil by ryegrass (Lolium perenne L.) with application of both S⁰ and earthworms. Results showed that the addition of S⁰ decreased soil pH and increased soil CEC, while a slight trend of decrease for soil pH and increase for CEC was found with earthworm application. In soil treated with earthworms, the addition of S⁰ increased the concentration of DTPA-extractable Pb by 9.9~20.8%. The concentration of diffusive gradients in thin film (DGT)-extractable Pb was increased by 26.31~32.9% with S⁰ and earthworm addition. In soil treated with earthworms, the addition of S⁰ increased the concentration of Pb in shoots of ryegrass by 55.7~110.4% and the translocation factor of Pb in ryegrass was also increased by S⁰ addition. Our results suggested that the combination application of earthworms and S⁰ could be an effective way to enhance the remediation efficiency of ryegrass for Pb-contaminated soil.

Understanding the spatiotemporal patterns of carbon footprints (CFs) of grains production is important to formulate regional heterogeneous greenhouse gas (GHG) mitigation strategies. This study evaluates the CFs, farm CFs (FCFs: CFs of per unit area), and production CFs (PCFs: CFs of per unit yield) of main grains production in China based on a new scale data set: agricultural statistics data of over 300 prefecture-level regions. A comparison of CFs of main grains production between main producing area (MPA) and non-main producing area (NMPA) are firstly discussed on a totally new scale. Results show that the CFs of main grains production of MPA accounts for 54–57% of country’s total although the area of farmland of MPA only accounts for 42%. The PCF and FCF of rice production are higher in MPA, while those of wheat and maize production are lower in MPA. It implies that there are less GHG emission of rice (main paddy grain) productions in NMPA and less GHG emission of wheat and maize (main dryland grains) production in MPA. In additional, the PCF of rice shows growth, while that of wheat and maize shows decline from 2008 to 2017. The growth of PCF of rice is mainly driven by the rise of PCF in MPA. Findings are expected to improve the understanding patterns of China’s CF of main grains production and subsequently contribute to GHG mitigation.

The purpose of this study was to learn more about the pathogenesis of amiodarone (AD) on alveoli and also the possible preventive effect of α-tocopherol (α-T) against these hazards. Rats were divided into 4 groups, one of which acted as a control, the second received α-T, the third AD, and the fourth AD and α-T for 2 weeks. Light microscopy (LM), immunohistochemistry, transmission electron microscopy (TEM), and malondialdehyde (MDA) activity were analyzed in sections of lung tissue. Alveoli of lung tissue AD examined with LM showed dilatation of alveolar spaces, aggregation of red blood cells, and narrowing of alveolar septa. When stained with vimentin (VIM), alveoli showed a positive reaction in the majority and a moderate reaction in others. In the pneumocytes of the type II, some cytoplasmic vesicles had been deflated, whereas others contained lamellar bodies, a damaged nucleus, and vesicles in their heterochromatin. In the interstitial space, collagen fibers with aggregation of red blood cells and a disrupted blood-air barrier were detected. In rat lung alveoli treated with AD and α-T, the alveolar septum thickened and the alveolar spaces expanded as estimated. The alveoli of this group had more or less intact type I and II pneumocytes and a better appearance of the blood-air barrier. In the cells of the alveolar lining, the VIM staining leads to a diffuse positive response. Finally, lung parenchyma also improved, suggesting that α-T may help minimize the effects of AD.