This study examined the effect of short-term changes in ambient temperature on hospital admissions among children aged less than 5 years old in Hanoi, Vietnam. Data on daily hospital admissions from January 2010 to June 2014 were collected from two hospitals. Daily meteorological data were obtained for the same period. We applied time series analysis to evaluate the risk of hospitalisation related to hot and cold weather by age and causes. We found that a 1 °C decrease in minimum temperature during the cold weather months was associated with 2.2% increase in hospital admission for respiratory infection among children 3–5 years old. A 1 °C increase in diurnal temperature range (DTR) in cold weather was associated with an increase of 1.9% and 1.7% in hospitalisation for all causes and respiratory infection, respectively, among children < 3 years old and an increase of 1.8% and 3.4% in hospitalisation for all causes and respiratory infection, respectively, among children of 3–5 years old. Negative associations between hot weather and hospital admissions were demonstrated. These findings suggested that low temperature and DTRs in winter are important risk factors for hospital admissions among children aged < 5 years old in Hanoi. Other factors may have modified the effect of high temperature on hospital admissions of children in Hanoi.

In view of the suspected negative impact of synthetic fungicides to the human health, nutritional quality, and non-targeted organisms, the use of plant-based antifungal agents has gained considerable interest to the agri-food industries. The aim of this study was to explore the antifungal and aflatoxin B₁ (AFB₁) inhibitory activity of chitosan (low molecular weight) encapsulated methyl salicylate. The nanoencapsulation of methyl salicylate (Ne-MS) has been characterized by SEM, FTIR, and XRD analysis. The encapsulation efficiency and loading capacity of Ne-MS ranged between 32–34% and 5–7% respectively. The minimum inhibitory concentration of Ne-MS (1.00 μL/mL) against the growth and aflatoxin B₁ production by Aspergillus flavus was found to be lower than the free MS (1.50 μL/mL). Mode of action studies demonstrated that the Ne-MS cause a significant decrease in the ergosterol content, leakage of vital ions (Ca²⁺, Mg²⁺, and K⁺), utilization of different carbon source by the A. flavus. Further, the docking result showed ver1 and omt A gene of AFB₁ biosynthesis are the possible molecular site of action of methyl salicylate. The in situ study revealed that Ne-MS had no significant negative impact on the organoleptic properties of the food system (maize) which strengthen its potential as a biorational alternative of synthetic fungicides.

Polyethylene (PE) is one of the major persistent plastic that is not biodegradable at considerable rates in most environments, and is the major source of unceasing environmental pollution. Recently, biodegradation of plastic wastes through waxworms and mealworms were reported. The present study focuses on the high-density polyethylene (HDPE) degradation capabilities of the larvae of Achroia grisella (lesser waxworm) and its ability to complete its life cycle when fed with HDPE. Effects of added nutrition on PE degradation were assessed, providing wax comb as co-feed (PE-WC). The egested frass of the waxworm fed on waxcomb (WC), PE, and PE-WC were studied by analyzing the changes in physiochemical properties through FTIR and ¹H NMR techniques in addition to weight loss percentage of PE and survival rates of the tested lesser waxworms. The post-degradation studies of WC and PE showed 90.5 ± 1.2% and 43.3 ± 1.6% weight loss, respectively, by a group of 100 lesser waxworms. Over an 8-day period, PE consumption increased with an ingestion of 1.83 mg of PE per day per larvae. Supplementing the PE feed of lesser waxworms with WC facilitated enhanced PE degradation showing 69.6 ± 3.2% weight loss. Twenty-eight day survival rates for lesser waxworms fed on WC, PE, and PE-WC were 91.3 ± 1.01%, 74.6 ± 2.9%, and 86 ± 1.4%, respectively. The FTIR and ¹H NMR analysis of egested frass indicated formation of new functional organic groups, supporting biodegradation of PE in lesser waxworms. The frass of the lesser waxworm fed on PE samples shows the presence of new carbonyl and alcoholic groups with increase in unsaturated hydrocarbon indicating formation of biodegraded intermediates. Lesser waxworms fed with WC, PE, and PE-WC completed all life cycle stages (larvae, pupae, moth, and egg) developing into a second generation. The second generation of PE-WC fed larvae of A. grisella efficiently degrades PE at par with first generation counterparts.

The objective of the study is to conduct the socio-economic and environmental survey about the feasibility of Saudi Arabia-China-Pakistan Economic Corridor (SCPEC) in five different dimensions, i.e., (i) key strengths of SCPEC project, (ii) prospective weaknesses of SCPEC project, (iii) opportunities attain Pakistan from SCPEC project, (iv) opportunities gain SCPEC from Pakistan, and (v) possible threats from SCPEC to other countries, including India. The larger number of intellects participated in this survey, including armed personnel working in strategic industries, academicians of higher education institutes, colleges, and public/private schools, doctors, civil servants, employees of non-governmental organizations, and others. The survey identified five major key strengths, including tourism promotion, infrastructure development, technology diffusion, energy demand, and mutual trade gains, while the prospective weaknesses are financial constraints, political instability, international dumping, corruption, and lack of good governance. The survey results show that Pakistan economy could attain maximum opportunities from SCPEC project in the form of economic empowerment, mutual trade gains, transportation development, entrepreneurship, and development of Gwadar port, while the SCPEC project gains from Pakistan in the form of economic stabilization, trade gains, and low transportation cost. The possible threats to SCPEC project to the other countries including India are political threats, security issues, Kashmir issue, and economic issues. The survey results conclude that the large number of intellects confirmed the positivity of SCPEC project for both the Pakistan and for the Chinese economy, while few intellects in numbers are incompatible with the SCPEC project due to economic, environmental, and security threats.

Mining tailing areas may contain metal minerals such as Cu, Pb, Zn, Cr, and Cd at high concentrations and low nutrients for the growth of plants. This kind of conditions of the area, as well as lack of tailing structure, may limit the development of plants on these areas. Thus, the present study determined the metal, macronutrient, and micronutrient concentrations in the tissues of the roots and shoots of the Solanum viarum Dunal species as well as it evaluated the potential use of the plant for phytoremediation of mining tailing areas contaminated with heavy metals. The macronutrients, micronutrients, and heavy metals in the roots and shoots were determined by the digestion method with nitric and perchloric acid (HNO₃-HClO₄) and quantified by the ICP-OES. In S. viarum, the average concentrations of the metals presented in the dry biomass varied between the shoots and roots, being higher in the roots for metals such as Cu (229 mg kg⁻¹), Zn (232 mg kg⁻¹), Mn (251 mg kg⁻¹), Cr (382 mg kg⁻¹), Ni (178 mg kg⁻¹), Pb (33 mg kg⁻¹), and Ba (1123 mg kg⁻¹). S. viarum indicates the possibility of a potential application in phytoremediation and treatment of areas contaminated with heavy metals.

Sewage treatment plants are sources of inorganic and organic matter as well as contaminants for the receiving watercourses. We analyzed the ecological consequences of such effluents by following a holistic and synecological ecotoxicological approach based on quantifying extracellular enzyme activities (EEA), primary production and bacterial cell, and biomass production rates. Samples were obtained at three locations at the Rivers Holtemme and Elbe, Germany and Lower Jordan River, Israel and West Bank, as well as from their adjacent sewage treatment plants. Blending river samples with sewage treatment plant effluents mainly resulted in a stimulation of EEAs, which was diminished in blends with 0.2-μm filtered sewage treatment plant effluents. Stimulation for primary production and bacterial cell and biomass production of River Holtemme and Elbe samples was observed, and inhibition of these rates for Lower Jordan River samples probably linked to generally high turbidity. The quantified bacterial biomass versus cell production rates showed almost unbalanced (≫ 1) growth. Very high biomass to cell production ratios were found for sewage and sewage-containing samples, which provides a semi-quantitative indicator function for high quantities of microbial easy utilizable dissolved organic matter as nutrition source. The presented approach enables the simultaneous quantification of inhibitory and stimulating toxic responses as well as supplying ecosystem-based data for policy decision-making, and for direct incorporation in models to derive management and remediation strategies.

In this paper, a new magnetic polymer–supported phosphate adsorbent MPVC-EDA-Ce was prepared by loading cerium (hydr)oxides onto ethylenediamine-functionalized polyvinyl chloride for the first time. MPVC-EDA-Ce showed excellent adsorption performances towards phosphate and easy recovery. The adsorption isotherm and kinetics of MPVC-EDA-Ce followed Langmuir monolayer model and the pseudo-second-order model, respectively. The pH results demonstrated that the MPVC-EDA-Ce could effectively remove phosphate in a wide range of pH with insignificant cerium leaching. Furthermore, analyses on adsorption mechanism and effect of competing anions demonstrated the formation of strong inner-sphere complexation between cerium (hydr)oxides and phosphate, which was a selective adsorption process, while positively charged quaternary ammonium groups adsorbed phosphate via relatively weak electrostatic attraction which was a non-selective adsorption process. The study provided a good reference to design novel phosphate adsorbents with two even more functional adsorption sites and a deep insight to investigate the adsorption mechanism towards phosphate.

Sediments are reservoirs and sources of DDTs to the aquatic ecosystem. However, the role of sediment particulate matter and benthic organisms in transferring DDTs remains unclear. In this study, microcosms were built up with different groups to simulate a freshwater system with DDT-contaminated sediment and organisms. The impacts of different exposure routes (water and sediment) on the changes of DDT and its metabolites (DDD and DDE) in carp (Cyprinus carpio) were investigated. The bioturbation of Tubifex tubifex (Oligochaeta, Tubificidae) was investigated to understand the fate and transfer of DDTs in aquatic environment. For the sediment treatment, the concentrations of o,p’-DDT in carp were significantly higher than those of p,p’-DDT, and the metallothionein (MT) content decreased. The bioaccumulation of DDTs in carp via sediment particulate matter was significantly higher/faster than that via overlying water. T. tubifex and sediment particulate matter accelerate DDT bioaccumulation in carp. Selective enrichment of the (+)-o,p’-DDT and (+)-o,p’-DDD was found in carp. These results help to reduce uncertainty in ecological and health risk assessments and to better understand the risk of DDTs in the environment.

The original publication of this paper contain typographical mistakes.

A novel biochar was prepared by loading birnessite to improve its capability to simultaneously adsorb As(III), As(V), and Cd(II) in water and soil. Layer sheet–structured birnessite was successfully loaded onto the biochar surface with increased functional groups. SEM, XRD, and FTIR combining with XPS analysis were utilized to characterize birnessite-loaded biochar and its adsorption mechanisms for As and Cd(II). The saturated adsorption capabilities of the birnessite-loaded biochar (BRB) for As(III), As(V), and Cd(II) were as large as 3543, 2412, and 9068 mg/kg (calculated by Langmuir isotherm model), much higher than for the corresponding non-loaded biochar (no adsorption of As, 4335 mg/kg for Cd). Adsorption of Cd and As onto BRB was controlled by multi mechanisms; Cd(II) appeared to coordinate to vacant sites of birnessite, while As formed surface complex with functional groups. Furthermore, BRB showed higher abilities for co-adsorption of As(III) and Cd or As(V) and Cd, which may be due to the formation of Cd₃(AsO₄)₂ surface precipitate as well as synergistic reaction between anions and cations. After conditioning to soil, BRB showed potential for Cd and As remediation under both flooded and unflooded conditions. These results suggested that BRB can be used as an effective sorbent for simultaneous immobilization of heavy metals, especially As and Cd, in environmental and agricultural systems.