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Hydrocarbon composition and distribution in a coastal region under influence of oil production in northeast Brazil Full text
2011
Wagener, Angela de L.R. | Carreira, Renato S. | Hamacher, Claudia | Scofield, Arthur de L. | Farias, Cassia O. | Cordeiro, Lívia G.M.S. | Luz, Letícia G. | Baêta, Aída P. | Kalas, Francine A.
Waters and sediments from the Potiguar Basin (NE Brazilian coast) were investigated for the presence and nature of polycyclic aromatic hydrocarbons (PAH) and aliphatic hydrocarbons. The region receives treated produced waters through a submarine outfall system serving the industrial district. The total dispersed/dissolved concentrations in the water column ranged from 10–50ngL⁻¹ for ∑16PAH and 5–10μgL⁻¹ for total aliphatic hydrocarbons. In the sediments, hydrocarbon concentrations were low (0.5–10ngg⁻¹for ∑16PAH and 0.01–5.0μgg⁻¹ for total aliphatic hydrocarbons) and were consistent with the low organic carbon content of the local sandy sediments. These data indicate little and/or absence of anthropogenic influence on hydrocarbon distribution in water and sediment. Therefore, the measured values may be taken as background values for the region and can be used as future reference following new developments of the petroleum industry in the Potiguar Basin.
Show more [+] Less [-]Characterization of organic matter in sediment cores of the Todos os Santos Bay, Bahia, Brazil, by elemental analysis and ¹³C NMR Full text
2011
Costa, A.B. | Novotny, E.H. | Bloise, A.C. | de Azevedo, E.R. | Bonagamba, T.J. | Zucchi, M.R. | Santos, V.L.C.S. | Azevedo, A.E.G.
The impact of human activity on the sediments of Todos os Santos Bay in Brazil was evaluated by elemental analysis and ¹³C Nuclear Magnetic Resonance (¹³C NMR). This article reports a study of six sediment cores collected at different depths and regions of Todos os Santos Bay. The elemental profiles of cores collected on the eastern side of Frades Island suggest an abrupt change in the sedimentation regime. Autoregressive Integrated Moving Average (ARIMA) analysis corroborates this result. The range of depths of the cores corresponds to about 50years ago, coinciding with the implantation of major onshore industrial projects in the region. Principal Component Analysis of the ¹³C NMR spectra clearly differentiates sediment samples closer to the Subaé estuary, which have high contents of terrestrial organic matter, from those closer to a local oil refinery. The results presented in this article illustrate several important aspects of environmental impact of human activity on this bay.
Show more [+] Less [-]Vessel traffic patterns in the Port of Kaohsiung and the management implications for preventing the introduction of non-indigenous aquatic species Full text
2011
Liu, Dagang | Tsai, Tzung-Kuen
Data on shipping traffic in one of the busiest seaports in the world, the Port of Kaohsiung, were analyzed to evaluate the implications for ballast water management. Results show that 67% of the arriving vessels were registered to a flag of convenience, which typically have a lower degree of environmental records. The top five donor countries historically suffer from harmful algal bloom problems. The short journey and busy trading between these countries and Taiwan lead to a higher risk of inoculation. In addition, only 1.4% of all vessels visited more than once every year during the 9-year span, indicating that the port authority encounters many new vessels each year. These findings could influence the design and application of ballast water management strategies as well as highlight the challenges in their implementation. We suggest that an analysis of vessel traffic patterns should be coupled with other useful vessel information to make risk assessment successful.
Show more [+] Less [-]Effects of alumina refinery wastewater and signature metal constituents at the upper thermal tolerance of: 1. The tropical diatom Nitzschia closterium Full text
2011
Harford, A.J. | Hogan, A.C. | Tsang, J.J. | Parry, D.L. | Negri, A.P. | Adams, M.S. | Stauber, J.L. | van Dam, R.A.
Ecotoxicological studies, using the tropical marine diatom, Nitzschia closterium (72-h growth rate), were undertaken to assess potential issues relating to the discharge from an alumina refinery in northern Australia. The studies assessed: (i) the species’ upper thermal tolerance; (ii) the effects of three signature metals, aluminium (Al), vanadium (V) and gallium (Ga) (at 32°C); and (iii) the effects of wastewater (at 27 and 32°C). The critical thermal maximum and median inhibition temperature for N. closterium were 32.7°C and 33.1°C, respectively. Single metal toxicity tests found that N. closterium was more sensitive to Al compared to Ga and V, with IC₅₀s (95% confidence limits) of 190 (140–280), 19,640 (11,600–25,200) and 42,000 (32,770–56,000)μgL⁻¹, respectively. The undiluted wastewater samples were of low toxicity to N. closterium (IC₅₀s>100% wastewater). Environmental chemistry data suggested that the key metals and discharge are a very low risk to this species.
Show more [+] Less [-]Characterization of marine debris in North Carolina salt marshes Full text
2011
Viehman, Shay | Vander Pluym, Jenny L. | Schellinger, Jennifer
Marine debris composition, density, abundance, and accumulation were evaluated in salt marshes in Carteret County, North Carolina seasonally between 2007 and 2009. We assessed relationships between human use patterns and debris type. Wave effects on marine debris density were examined using a GIS-based forecasting tool. We assessed the influence of site wave exposure, period, and height on debris quantity. Presence and abundance of debris were related to wave exposure, vegetation type and proximity of the strata to human population and human use patterns. Plastic pieces accounted for the majority of all debris. Small debris (0–5cm) was primarily composed of foam pieces and was frequently affiliated with natural wrack. Large debris (>100cm) was encountered in all marsh habitat types surveyed and was primarily composed of anthropogenic wood and derelict fishing gear. Marsh cleanup efforts should be targeted to specific habitat types or debris types to minimize further damage to sensitive habitats.
Show more [+] Less [-]Temporal changes of polyphenols and enzyme activities in seedlings of Kandelia obovata under lead and manganese stresses Full text
2011
Yan, Zhong Zheng | Tam, Nora Fung Yee
The temporal responses of peroxidase (POD), superoxide dismutase (SOD), total polyphenols (TP), extractable condensed tannins (ECT) to different levels of lead (Pb) or manganese (Mn) stress, as well as the metal accumulation, in seedlings of Kandelia obovata were investigated. Both stress time and stress intensity had significant effects with significant accumulation of Pb and Mn in roots at Day 1. Pb and Mn showed no significant effects on root or leaf TP and ECT at Day 1. Prolonged exposure to metals caused significant drops of root TP and ECT but increased in leaves at Days 7 and 49. POD activities decreased in both roots and leaves at Day 1, while POD and SOD both increased under moderate levels of Pb and Mn at Day 7. The present study showed that antioxidative enzyme activities were more sensitive indicators to Pb or Mn stresses than phenolic compounds.
Show more [+] Less [-]Spatial and temporal distribution of heavy metal concentrations in mussels (Mytilus edulis) from the Baie des Chaleurs, New Brunswick, Canada Full text
2011
Fraser, Marc | Surette, Céline | Vaillancourt, Cathy
Previous studies on heavy metal contamination of the Baie des Chaleurs focus only on industrial centers and overlooked the ecosystem as a whole. To fill this gap, the objective of this study is to establish a baseline of the spatio-temporal distribution of heavy metals in mussels from the Baie des Chaleurs based on the ecosystem approach. Our results show, for the first time, a cadmium contamination in mussels across the south coast of the Baie des Chaleurs and not only in industrial centers. Our results also confirm previous studies showing heavy metal contamination of the Belledune area. This study demonstrates that the use of the ecosystemic approach is essential to obtain a comprehensive picture of environmental contamination in marine ecosystems.
Show more [+] Less [-]Spatial patterns of chemical contamination (metals, PAHs, PCBs, PCDDs/PCDFS) in sediments of a non-industrialized but densely populated coral atoll/small island state (Bermuda) Full text
2011
Jones, Ross J.
There is a recognized dearth of standard environmental quality data in the wider Caribbean area, especially on coral atolls/small island states. Extensive surveys of sediment contamination (n=109 samples) in Bermuda revealed a wide spectrum of environmental quality. Zinc and especially copper levels were elevated at some locations, associated with boating (antifouling paints and boatyard discharges). Mercury contamination was surprisingly prevalent, with total levels as high as 12mgkg⁻¹DW, although methyl mercury levels were quite low. PAH, PCB and PCDD/PCDF contamination was detected a several hotspots associated with road run-off, a marine landfill, and a former US Naval annexe. NOAA sediment quality guidelines were exceeded at several locations, indicating biological effects are possible, or at some locations probable. Overall, and despite lack of industrialization, anthropogenic chemicals in sediments of the atoll presented a risk to benthic biodiversity at a number of hotspots suggesting a need for sediment management strategies.
Show more [+] Less [-]Anthropogenic metal contamination and sapropel imprints in deep Mediterranean sediments Full text
2011
Angelidis, M.O. | Radakovitch, O. | Veron, A. | Aloupi, M. | Heussner, S. | Price, B.
Anthropogenic metal contamination and sapropel imprints in deep Mediterranean sediments Full text
2011
Angelidis, M.O. | Radakovitch, O. | Veron, A. | Aloupi, M. | Heussner, S. | Price, B.
Sediment cores from the deep Balearic basin and the Cretan Sea provide evidence for the accumulation of Cd, Pd and Zn in the top few centimeters of the abyssal Mediterranean sea-bottom. In both cores, 206Pb/207Pb profiles confirm this anthropogenic impact with less radiogenic imprints toward surface sediments. The similarity between excess 210Pb accumulated in the top core and the 210Pb flux suggests that top core metal inventories reasonably reflect long-term atmospheric deposition to the open Mediterranean. Pb inventory in the western core for the past 100years represents 20–30% of sediment coastal inventories, suggesting that long-term atmospheric deposition determined from coastal areas has to be used cautiously for mass balance calculations in the open Mediterranean. In the deeper section of both cores, Al normalized trace metal profiles suggest diagenetic remobilization of Fe, Mn, Cu and, to a lesser extent, Pb that likely corresponds to sapropel event S1.
Show more [+] Less [-]Anthropogenic metal contamination and sapropel imprints in deep Mediterranean sediments Full text
2011
Angelidis, M. O. | Radakovitch, Olivier | Veron, Alain | Aloupi, M. | Heussner, S. | Price, B. | Centre Européen de Recherche et d'Enseignement des Géosciences de l'Environnement (CEREGE) ; Institut de Recherche pour le Développement (IRD)-Institut National de la Recherche Agronomique (INRA)-Aix Marseille Université (AMU)-Collège de France (CdF (institution))-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)
Sediment cores from the deep Balearic basin and the Cretan Sea provide evidence for the accumulation of Cd, Pd and Zn in the top few centimeters of the abyssal Mediterranean sea-bottom. In both cores, 206Pb/207Pb profiles confirm this anthropogenic impact with less radiogenic imprints toward surface sediments. The similarity between excess 210Pb accumulated in the top core and the 210Pb flux suggests that top core metal inventories reasonably reflect long-term atmospheric deposition to the open Mediterranean. Pb inventory in the western core for the past 100 years represents 20-30% of sediment coastal inventories, suggesting that long-term atmospheric deposition determined from coastal areas has to be used cautiously for mass balance calculations in the open Mediterranean. In the deeper section of both cores, Al normalized trace metal profiles suggest diagenetic remobilization of Fe, Mn, Cu and, to a lesser extent, Pb that likely corresponds to sapropel event Si
Show more [+] Less [-]Fish consumption and risk of contamination by mercury – Considerations on the definition of edible parts based on the case study of European sea bass Full text
2011
Mieiro, C.L. | Pacheco, M. | Duarte, A.C. | Pereira, M.E.
Fish consumption and risk of contamination by mercury – Considerations on the definition of edible parts based on the case study of European sea bass Full text
2011
Mieiro, C.L. | Pacheco, M. | Duarte, A.C. | Pereira, M.E.
In the present study, the risk to humans by consuming European sea bass (Dicentrarchus labrax), captured at three sites along a Hg contamination gradient, was evaluated by comparing muscle and kidney total Hg (T-Hg) levels with the European regulations for marketed fish. Moreover, T-Hg and organic Hg (O-Hg) levels in muscle were compared with the Provisional Tolerable Weekly Intake (PTWI) and the Reference Dose (RfD). Although T-Hg levels in muscle were below the European value allowable for marketed fish, kidney’s levels were higher than the set value, stressing the importance of redefining the concept of edible tissue and which tissues should be considered. Mercury weekly ingestion in the contaminated areas was higher than the PTWI, and O-Hg daily ingestion rates were higher than the RfD in all sampling sites. Thus, populations consuming sea bass from the contaminated sites may be at risk, with particular relevance for children and pregnant women.
Show more [+] Less [-]Fish consumption and risk of contamination by mercury - Considerations on the definition of edible parts based on the case study of European sea bass Full text
1000
Mieiro, C. L. | Pacheco, M. | Duarte, A. C. | Pereira, M. E.
In the present study, the risk to humans by consuming European sea bass (Dicentrarchus labrax), captured at three sites along a Hg contamination gradient, was evaluated by comparing muscle and kidney total Hg (T-Hg) levels with the European regulations for marketed fish. Moreover, T-Hg and organic Hg (O-Hg) levels in muscle were compared with the Provisional Tolerable Weekly Intake (PTWI) and the Reference Dose (RfD). Although T-Hg levels in muscle were below the European value allowable for marketed fish, kidney’s levels were higher than the set value, stressing the importance of redefining the concept of edible tissue and which tissues should be considered. Mercury weekly ingestion in the contaminated areas was higher than the PTWI, and O-Hg daily ingestion rates were higher than the RfD in all sampling sites. Thus, populations consuming sea bass from the contaminated sites may be at risk, with particular relevance for children and pregnant women.
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