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An ecotoxicological analysis of the sediment quality in a European Atlantic harbor emphasizes the current limitations of the Water Framework Directive Full text
2013
Gonçalves, Sandra F. | Calado, Ricardo | Gomes, Newton C.M. | Soares, Amadeu M.V.M. | Loureiro, Susana
An ecotoxicological analysis of the sediment quality in a European Atlantic harbor emphasizes the current limitations of the Water Framework Directive Full text
2013
Gonçalves, Sandra F. | Calado, Ricardo | Gomes, Newton C.M. | Soares, Amadeu M.V.M. | Loureiro, Susana
The “PortoNovo” project was developed to standardize the methodologies for water quality management in the port areas of coastal Atlantic regions to improve the Water Frame Directive (WFD) for these specific water bodies. Under this scope, water and sediment samples were collected from five sites within the Port of Aveiro, Portugal. According to the physical and chemical parameters that were analyzed (i.e., metals, total organic carbon, polychlorinated biphenyls and polycyclic aromatic hydrocarbons), the sediments were not considered at risk based on European sediment quality laws. However, the bioassays that were performed on the sediment samples (Microtox®) and the standardized acute toxicity test using the marine rotifer, Brachionus plicatilis, on sediment elutriates revealed higher toxicity levels. The use of bioassays to assess sediment quality clearly complements more conservative approaches and highlights current gaps within the WFD. The approach presented here can be easily transferred to other port areas for more reliable water quality management.
Show more [+] Less [-]An ecotoxicological analysis of the sediment quality in a European Atlantic harbor emphasizes the current limitations of the Water Framework Directive Full text
2013
Gonçalves, Sandra F. | Calado, Ricardo | Gomes, Newton C. M. | Soares, Amadeu M. V. M. | Loureiro, Susana
The "PortoNovo" project was developed to standardize the methodologies for water quality management in the port areas of coastal Atlantic regions to improve the Water Frame Directive (WFD) for these specific water bodies. Under this scope, water and sediment samples were collected from five sites within the Port of Aveiro, Portugal. According to the physical and chemical parameters that were analyzed (i.e., metals, total organic carbon, polychlorinated biphenyls and polycyclic aromatic hydrocarbons), the sediments were not considered at risk based on European sediment quality laws. However, the bioassays that were performed on the sediment samples (Microtox®) and the standardized acute toxicity test using the marine rotifer, Brachionus plicatilis, on sediment elutriates revealed higher toxicity levels. The use of bioassays to assess sediment quality clearly complements more conservative approaches and highlights current gaps within the WFD. The approach presented here can be easily transferred to other port areas for more reliable water quality management.
Show more [+] Less [-]Plastic pollution in the South Pacific subtropical gyre Full text
2013
Eriksen, Marcus | Maximenko, Nikolai | Thiel, Martin | Cummins, Anna | Lattin, Gwen | Wilson, Stiv | Hafner, Jan | Zellers, Ann | Rifman, Samuel
Plastic marine pollution in the open ocean of the southern hemisphere is largely undocumented. Here, we report the result of a (4489km) 2424 nautical mile transect through the South Pacific subtropical gyre, carried out in March–April 2011. Neuston samples were collected at 48 sites, averaging 50 nautical miles apart, using a manta trawl lined with a 333μm mesh. The transect bisected a predicted accumulation zone associated with the convergence of surface currents, driven by local winds. The results show an increase in surface abundance of plastic pollution as we neared the center and decrease as we moved away, verifying the presence of a garbage patch. The average abundance and mass was 26,898particles km−2 and 70.96gkm−2, respectively. 88.8% of the plastic pollution was found in the middle third of the samples with the highest value of 396,342particles km−2 occurring near the center of the predicted accumulation zone.
Show more [+] Less [-]Monitoring of impact of anthropogenic inputs on water quality of mangrove ecosystem of Uran, Navi Mumbai, west coast of India Full text
2013
Pawar, Prabhakar R.
Surface water samples were collected from substations along Sheva creek and Dharamtar creek mangrove ecosystems of Uran (Raigad), Navi Mumbai, west coast of India. Water samples were collected fortnightly from April 2009 to March 2011 during spring low and high tides and were analyzed for pH, Temperature, Turbidity, Total solids (TS), Total dissolved solids (TDS), Total suspended solids (TSS), Dissolved oxygen (DO), Biochemical oxygen demand (BOD), Carbon dioxide (CO2), Chemical oxygen demand (COD), Salinity, Orthophosphate (O-PO4), Nitrite–nitrogen (NO2–N), Nitrate–nitrogen (NO3–N), and Silicates. Variables like pH, turbidity, TDS, salinity, DO, and BOD show seasonal variations. Higher content of O-PO4, NO3–N, and silicates is recorded due to discharge of domestic wastes and sewage, effluents from industries, oil tanking depots and also from maritime activities of Jawaharlal Nehru Port Trust (JNPT), hectic activities of Container Freight Stations (CFS), and other port wastes. This study reveals that water quality from mangrove ecosystems of Uran is deteriorating due to industrial pollution and that mangrove from Uran is facing the threat due to anthropogenic stress.
Show more [+] Less [-]Benthic foraminiferal assemblages and trace metals reveal the environment outside the Pearl River Estuary Full text
2013
Li, Tao | Xiang, Rong | Li, Tuanjie
We investigated the distribution patterns of the benthic foraminiferal assemblages outside the Pearl River Estuary in relation to trace metals, organic carbon and sedimentary particle fractions. The study area is unpolluted to moderately polluted by Cr, Cu, Pb and Zn and is completely polluted by Ni. The highest levels are found in the western coastal zone. Spatial distributions of the measured elements are strongly related to the behavior of the sedimentary clay fraction. The analyses of species abundance and community diversity as well as subsequent canonical correspondence analysis were used to reveal the relationship between foraminifera data and environmental parameters. Four sampling site groups established by factor analysis were distributed from the coastal area to the inner shelf. Their distribution patterns have a strong correlation with Cu, Pb and Ba. This research shows that benthic foraminifera can be used as bioindicators of trace metal pollutants outside the Pearl River Estuary.
Show more [+] Less [-]Simulation of CO2–water–rock interactions on geologic CO2 sequestration under geological conditions of China Full text
2013
Wang, Tianye | Wang, Huaiyuan | Zhang, Fengjun | Xu, Tianfu
The main purpose of this study focused on the feasibility of geologic CO2 sequestration within the actual geological conditions of the first Carbon Capture and Storage (CCS) project in China. This study investigated CO2–water–rock interactions under simulated hydrothermal conditions via physicochemical analyses and scanning electron microscopy (SEM). Mass loss measurement and SEM showed that corrosion of feldspars, silica, and clay minerals increased with increasing temperature. Corrosion of sandstone samples in the CO2-containing fluid showed a positive correlation with temperature. During reaction at 70°C, 85°C, and 100°C, gibbsite (an intermediate mineral product) formed on the sample surface. This demonstrated mineral capture of CO2 and supported the feasibility of geologic CO2 sequestration. Chemical analyses suggested a dissolution–reprecipitation mechanism underlying the CO2–water–rock interactions. The results of this study suggested that mineral dissolution, new mineral precipitation, and carbonic acid formation-dissociation are closely interrelated in CO2–water–rock interactions.
Show more [+] Less [-]Mercury deposition during the previous century in an upwelling region; Cabo Frio, Brazil Full text
2013
Figueiredo, Thiago S. | Albuquerque, Ana Luiza S. | Sanders, Christian J. | Cordeiro, Lívia G.M.S. | Silva-Filho, Emmanoel V.
To investigate the upwelling influence on Hg biogeochemical cycles and the sedimentological changes during the previous ∼150years, four sediment box-cores were sampled along an inshore offshore transect on the Southeastern Brazilian continental shelf. Mercury values were found to be relatively low, with means ranging between 8.08 and 30.4ngg−1. Mercury fluxes along the sediment cores are directly related to the well documented historical regional activity and global atmospheric deposition. The narrow relationship between mercury and organic carbon suggest that upwelling phenomenon and primary production may play an important role on Hg input and distribution along continental shelf depositional settings.
Show more [+] Less [-]Revisiting hydrocarbons source appraisal in sediments exposed to multiple inputs Full text
2013
Massone, Carlos G. | Wagener, Angela de L.R. | Abreu, Henrique Monteiro de | Veiga, Alvaro
The aim of this work was to test the efficiency of statistical methods as compared to the traditional diagnostic ratios to improve hydrocarbon source identification in sediments subjected to multiple inputs. Hydrocarbon determination in Guanabara Bay sediments pointed out high degradation and ubiquitous petrogenic pollution through the presence of high unresolved complex mixture. Polycyclic aromatic hydrocarbon (PAHs) ratios suggested pervasive contamination derived from combustion in all sediments and failed discriminating samples despite the specificity of sources in different sampling sites. Principal component analysis (PCA) effectively distinguished the petrogenic imprint superimposed to the ubiquitous combustion contamination, since this technique reduces the influence of PAHs distribution which is common to all samples. PCA associated to multivariate linear regression (MLR) allowed a quantitative assessment of sources confirming predominance of the pervasive contaminant component superimposed to a generalized petrogenic imprint. The pervasive component derives from combustion contributions as well as from differential PAHs degradation.
Show more [+] Less [-]Chlorinated compounds and polybrominated diphenyl ethers (PBDEs) in mussels (Mytilus galloprovincialis) collected from Apulia Region coasts Full text
2013
Giandomenico, Santina | Spada, Lucia | Annicchiarico, Cristina | Assennato, Giorgio | Cardellicchio, Nicola | Ungaro, Nicola | Leo, Antonella Di
This project was carried out to assess the levels and spatial distribution of organochlorine compounds in the coastal marine environment, using mussels as bioindicators to evaluate the coastal water quality. Levels of polychlorobiphenils (PCB), chlorinated pesticides (DDT isomers, HCH isomers, Aldrin, Dieldrin, alfa-Endosulfan, Hexachlorobenzene, Pentachlorobenzene) and polybrominated diphenyl ethers (PBDEs) were determined in tissues from mussels (Mytilus galloprovincialis) collected along the Apulia Region coasts (Mediterranean Sea). Results indicate that contamination by organochlorine compounds is higher in mussels sampled in the Ionian Sea than in those from the Adriatic Sea, with PCB levels up to seven times higher in mussels from Ionian than from the Adriatic Sea. Although PCB levels were above the maximum values indicated by both European Community (EC) and National regulation in several sample sites, the PCB concentrations were particularly high in some stations, suggesting that these locations require a much specific attention. Conversely, results on the mussel contamination by PBDEs highlight their ubiquitous environmental distribution, and underline the need to establish the maximum level for these compounds in foodstuff, according to European Regulations.
Show more [+] Less [-]Prevalence and composition of marine debris in Brown Booby (Sula leucogaster) nests at Ashmore Reef Full text
2013
Lavers, Jennifer L. | Hodgson, Jarrod C. | Clarke, Rohan H.
Anthropogenic debris is ubiquitous in the marine environment and has been reported to negatively impact hundreds of species globally. Seabirds are particularly at risk from entanglement in debris due to their habit of collecting food and, in many cases, nesting material off the ocean’s surface. We compared the prevalence and composition of debris in nests and along the beach at two Brown Booby (Sula leucogaster) colonies on Ashmore Reef, Timor Sea, a remote area known to contain high densities of debris transported by ocean currents. The proportion of nests with debris varied across islands (range 3–31%), likely in response to the availability of natural nesting materials. Boobies exhibited a preference for debris colour (white and black), but not type. The ephemeral nature of Brown Booby nests on Ashmore Reef may limit their utility as indicators of marine pollution, however monitoring is recommended in light of increasing demand for plastic products.
Show more [+] Less [-]Assessment of contribution to PM10 concentrations from long range transport of pollutants using WRF/Chem over a subtropical urban airshed Full text
2013
Gupta, Medhavi | Mohan, Manju
A regional chemical transport model was implemented to simulate the Respirable Suspended Particulate Matter (PM10) concentration in order to study the impact of long–range transport of air pollutants over megacity Delhi with due consideration to different geographical domains extending up to entire Asia and corresponding emissions. PM10 concentration levels over megacity Delhi remain persistently high, often exceeding the ambient air quality standards. A chemical transport model namely Weather Research and Forecasting (WRF) model Version 3.2 coupled with chemistry module (WRF/Chem) was utilized with nested domains for this purpose, subsequent to model evaluation for the period during June, 2010 that includes extremely high PM10 concentrations. A highly satisfactory model performance was interpreted based on the several statistical parameters as per the current state of the science and their recommended values. Based on model simulations representing different geographical domains encompassing Asia, India, North India and Delhi and their corresponding emissions, it was clearly reflected that contributions due to emissions of the megacity Delhi alone is 11%–41% and thus remaining (59%–89%) proportion is expected to be contributed from the sources outside of the Delhi region which is significant. It is demonstrated that the WRF/Chem model performs well for a sub–tropical urban airshed though there is scope of improvement for the consistent under– prediction with more refined emission inventories. Nevertheless, this model could be implemented to assess the long– range transport of pollutants so as to adequately address the influence of the remote sources outside the urban airshed. This can serve as an important tool towards planning and implementing the regulatory policies for air pollution control for more effective outcomes.
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