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Effect of Ozonation and Sonication on Biochemical Methane Potential of Biosludge from Textile Mill Effluent
2009
Desiana, D | Setiadi, T
The aim of this study was to justify the method to determine biochemical methane potential (BMP) of biosludges and investigate the effect of ozonation and sonication on the biosludge from textile mill effluent to its biodegradability and toxicity. This study revealed that the exented anaerobic toxicity assay at a chemical oxygen demand (COD) concentration in the assay of about 1,500 mg/L was the appropiate technique to determine BMP of the biosludge. Moreover, it was found that the biodegradability of biosludge was satisfactorily increased by both of ozonation and sonication. The use of ozone dose of 0.005 g O₃/g COD and 0.01 O₃/g COD increased the biodegradability from 62% to 69% and 76%, respectively. While for sonication on frequency 51 kHz ±6%, 120 W for 30 and 60 min increased the biodegradability from 62% to 68% and 73%, respectively.
Show more [+] Less [-]A Novel Method to Capture and Analyze Flow in a Gross Pollutant Trap Using Image-Based Vector Visualization
2009
Madhani, Jehangir T | Young, Joseph | Kelson, Neil A | Brown, Richard J
A novel method is developed to capture and analyze several experimental flow regimes through a gross pollutant trap (GPT) with fully and partially blocked screens. Typical flow conditions and screen blockages are based on findings from field investigations that show a high content of organic matter in urban areas. Fluid motion of neutral buoyant particles is tracked using a high-speed camera and particle image velocimetry (PIV) software. The recorded fluid motion is visualized through an image-based, line integral convolution (LIC) algorithm, generally suitable for large computational fluid dynamics (CFD) datasets. The LIC method, a dense representation of streamlines, is found to be superior to the point-based flow visualization (e.g., hedgehog or arrow plots) in highlighting main flow features that are important for understanding litter capture and retention in the GPT. Detailed comparisons are made between the flow regimes, and the results are compared with CFD data previously obtained for fully blocked screens. The LIC technique is a useful tool for identifying flow structures in the GPT and areas that are subjected to abnormalities difficult to detect by conventional methods. The novel method is found to be useful both in the laboratory and in the field, with little preparation and cost. The enhancements and pitfalls of the LIC technique along with the experimentally captured flow field are presented and discussed.
Show more [+] Less [-]Inundation Analysis in the Coastal Area Considering Climate Change Due to Global Warming
2009
Pokharel, Parameshor | Takeda, Makoto | Naoki, Matsuo
This paper describes the possible inundation scenarios under sea level rise conditions due to global climate change with particular reference to Nagoya, Japan. The study was carried out by using a two-dimensional sea model integrated with one-dimensional river flow model and two-dimensional overland flow model. For the connections of models, the upstream discharge or downstream water level in each grid is considered as the boundary conditions. The governing equations used for the analysis have been solved by finite volume method. The analysis results implicate that some parts of densely populated coastal area of Nagoya city will be vulnerable to inundation if the sea level rise due to global warming by 1 m. Moreover, the performances of existing sewer system and inundation scenario under various conditions have been analyzed.
Show more [+] Less [-]Indoor Air Quality Assessment of Elementary Schools in Curitiba, Brazil
2009
Godoi, R. H. M | Avigo, D Jr | Campos, V. P | Tavares, T. M | de Marchi, M. R. R | Van Grieken, R | Godoi, A. F. L
The promotion of good indoor air quality in schools is of particular public concern for two main reasons: (1) school-age children spend at least 30% of their time inside classrooms and (2) indoor air quality in urban areas is substantially influenced by the outdoor pollutants, exposing tenants to potentially toxic substances. Two schools in Curitiba, Brazil, were selected to characterize the gaseous compounds indoor and outdoor of the classrooms. The concentrations of benzene, toluene, ethylbenzene, and the isomers xylenes (BTEX); NO₂; SO₂; O₃; acetic acid (HAc); and formic acid (HFor) were assessed using passive diffusion tubes. BTEX were analyzed by gas chromatography-ion trap mass spectrometry and other collected gasses by ion chromatography. The concentration of NO₂ varied between 9.5 and 23 µg m⁻³, whereas SO₂ showed an interval from 0.1 to 4.8 µg m⁻³. Within the schools, BTEX concentrations were predominant. Formic and acetic acids inside the classrooms revealed intermediate concentrations of 1.5 µg m⁻³ and 1.2 µg m⁻³, respectively.
Show more [+] Less [-]Effect of MSW Source-Classified Collection on Polycyclic Aromatic Hydrocarbons in Residues from Full-Scale Incineration in China
2009
Municipal solid waste (MSW) source-classified collection represents an advancement in resource recycling and secondary pollution control in China. Comparative experiments were performed to assess the effect of a newly-established MSW source-classified collection system on polycyclic aromatic hydrocarbons (PAHs) in bottom ash from an incinerator (BA), fly ash from a boiler (FAB) and fly ash from a bag filter (FABF) of a full-scale MSW incinerator in China. Compared with FAB or FABF, PAHs were mainly concentrated in BA with a range of 1,961.0-2,420.2 μg/kg. Total amounts of 16 high priority PAHs in BA, FAB and FABF from the classified MSW incineration were significantly reduced by 19.0%, 42.4% and 59.8% respectively in comparison with those from the traditional mixed MSW incineration. Moreover, the toxic equivalent quantity (B[a]Peq) of carcinogenic PAHs in these three kinds of residues from the classified MSW incineration were significantly decreased, with the maximum decrease observed in FABF. As a result of source-classification with effective presorting and dewatering, plastics and metals in the MSW were lower, but combustibles and heat values of the MSW increased. Due to variations of the characteristics of the feed waste, complete combustion conditions including continuous higher incineration temperature, lower CO concentration and higher air excess ratio were observed during the process of classified MSW incineration. Incineration temperature and CO concentration showed a negative and positive correlation, respectively, with total PAHs, indicating that incomplete combustion products such as PAHs could be reduced by controlling combustion conditions directly related to properties of the feed waste. The newly established MSW source-classified collection process could be a feasible method for reducing PAHs formation and emission in residues from MSW incineration.
Show more [+] Less [-]Gastropod Assemblages as Indicators of Sediment Metal Contamination in Mangroves of Dumai, Sumatra, Indonesia
2009
Amin, Bintal | Ismail, Ahmad | Arshad, Aziz | Yap, Chee Kong | Kamarudin, Mohd Salleh
Impacts of heavy metal concentrations in sediments on the gastropod community structure were assessed in the coastal waters of Dumai, Sumatra, Indonesia. The objective of this study was to relate the levels of heavy metal pollution with the changes of gastropod community structure in the study area. Concentrations of Cd, Cu, Pb, Zn, Ni, and Fe in surface sediments collected from five sampling stations were analyzed and correlated with the abundance, species richness, and diversity of gastropod populations. Sediments at stations with more anthropogenic activities accumulated higher concentrations of heavy metals and consequently displayed lower abundances, lower species richness and diversity; while stations with lower heavy metal concentrations in sediments showed the opposite pattern in gastropod community metrics. The above findings are complemented by significant negative correlations p < 0.05-0.01) between concentrations of Cd, Cu, Pb, Zn, and Ni in the sediments and gastropod abundance and species richness. Among the metals analyzed, Cu and Zn had strongest negative correlations with the gastropod diversity which suggests that these metals may be the most detrimental to gastropod populations in the mangrove area of Dumai coastal waters.
Show more [+] Less [-]Petroleum Hydrocarbons Rhizodegradation by Sebastiania commersoniana (Baill.) L. B. SM. & Downs
2009
Toledo Ramos, Débora | Maranho, Leila Teresinha | Godoi, Ana Flávia Locateli | Carvalho Filho, Marco Aurélio da Silva | Lacerda, Luiz Gustavo | de Vasconcelos, Eliane Carvalho
Petroliferous activities in Brazil have an accelerated development in the last years. As a consequence, the incidence of environmental accidents such as oil spills and contamination of soils has increased significantly. Therefore, it is extremely necessary to develop remediation techniques with lower costs, decontamination efficiency and impact minimisation. The aim of this work was to evaluate Sebastiania commersoniana phytoremediation potential in soil contaminated by petroleum. This species, which is a native tree, was selected due to its proven capacity for surviving in areas contaminated by petroleum. Experiments were carried out with soils that were vegetated but non-contaminated, soils that were freshly contaminated (25, 50 and 75 g kg⁻¹) but non-vegetated, and soils that were vegetated and contaminated, samples were collected 60 and 424 days after contamination with the purpose of evaluating the percentage of petroleum degradation in relation to the time. The results obtained in the present study allow us to state that S. commersoniana proves to be tolerant to petroleum contamination with respect to plant's growth. The degradation of petroleum hydrocarbons was evaluated by gas chromatography with a flame ionisation detector (GC-FID) equipped with a capillary column HP-5 (5% phenyl-methylpolysiloxane, 30 m; 0.25 mm; 0.25 μm). According to chromatographic analysis, samples in contact with S. commersoniana showed a significant area reduction of the hydrocarbon peaks. Analysis of the 60-day samples showed a reduction of petroleum hydrocarbons area higher than 60% and the 424-day samples showed a reduction higher than 94%, which demonstrates that a petroleum degradation process is occurring.
Show more [+] Less [-]Influence of Freshwater Sediment Characteristics on Persistence of Fecal Indicator Bacteria
2009
Haller, Laurence | Amedegnato, Essoêfli | Poté, John | Wildi, Walter
Extended persistence of enteric bacteria in coastal sediments and potential remobilization of pathogens during natural turbulence or human activities may induce an increased risk of human infections. In this study, the effect of sediment characteristics such as particle grain size and nutrient and organic matter contents on the survival of fecal indicator bacteria (FIB) including total coliforms, Escherichia coli, and Enterococcus was investigated. The experimentation was carried out for 50 days in microcosms containing lake water and different contaminated freshwater sediments in continuous-flow and batch conditions. Results of this study revealed: (1) extended FIB survival in sediments up to 50 days, (2) higher growth and lower decay rates of FIB in sediments with high levels of organic matter and nutrients and small (mainly silt) grain size, and (3) longer survival of Enterococcus sp. compared to E. coli and total coliforms. FIB survival in sediments and possible resuspension are of considerable significance for the understanding of permanent microbial pollution in water column and therefore human risk during recreational activities.
Show more [+] Less [-]Microfauna Community as an Indicator of Effluent Quality and Operational Parameters in an Activated Sludge System for Treating Piggery Wastewater
2009
Puigagut Juárez, Jaume | García, Joan | Salvadó, Humbert
In order to study the potential use of microfauna as an indicator of effluent quality and operational parameters in an activated sludge system for treating piggery wastewater, an experimental sequencing batch reactor was set up and evaluated by biological and physical-chemical analyses for 12 months. Results show that microfauna (and specifically ciliate protozoa) are a good parameter for assessing effluent quality in terms of both chemical oxygen demand (COD) and ammonia and for assessing the organic and nitrogen load of the system. Specifically, the abundance of ciliates decreases from 20,000 individuals·mL⁻¹ to ca. 2,500 individuals·mL⁻¹ and from ca. 10,000 individuals mL⁻¹ to ca. 200 individuals mL⁻¹ when effluent concentration is between 550 and 750 mg L⁻¹ and above 100 mg L⁻¹ to the COD and ammonia concentrations, respectively. Furthermore, microfauna abundance is reduced from ca. 18,000 individuals mL⁻¹ (organic load between 0.1 and 0.2 mg COD mg total suspended solids (TSS)⁻¹ day⁻¹) to ca. 500 individuals mL⁻¹ (organic load between 0.3 and 04 mg COD mg TSS⁻¹ day⁻¹). Microfauna abundance also decreases as nitrogen loading increases. Nitrogen loading in the range of 5-60 mg NH₄-N g TSS⁻¹ day⁻¹ does not have any significant effect on microfauna abundance. However, ammonia loading from 60 to 120 mg NH₄-N g TSS⁻¹ day⁻¹ reduces microfauna abundance ca. 6-fold. Ciliate protozoa were the largest microfauna group during the whole period of study, representing ca. 75% of the total microfauna abundance. The largest group in the ciliate community was that of the free-swimming ciliates. This was followed by the group of attached and crawling ciliates. Specifically, the dominant ciliate species during the whole study period were Uronema nigricans, Vorticella microstoma-complex, Epistylis coronata, and Acineria uncinata.
Show more [+] Less [-]Concentration Effects on Competitive Sorption of Trichloroethylene and Tetrachloroethylene to the Roots of Typha latifolia: Implications for Phytomonitoring
2009
Ma, Xingmao | Archer, Todd | Wang, Chen
Uptake of organic contaminants by plant roots consists of two consecutive steps: sorption to plant roots and entrance into root xylem tissues through epidermal and endodermic membranes. Most research pertaining to phytoremediation assumed that sorption to plant roots is linear and non-competitive. A growing body of evidence, however, is suggesting that sorption to plant roots is nonlinear and competitive. The objective of this study was to examine the concentration effects of chemical constituents on the competitive sorption of trichloroethylene (TCE) and tetrachloroethylene (PCE) to the roots of Typha latifolia. Competitive sorption was clearly demonstrated by the reduced sorption of TCE and PCE in bi-solute systems than in single-solute systems. Concentration is an important factor affecting the extent of competition. In bi-solute systems, the PCE/TCE ratio on root surface approximately reflected the contaminant footprints in solution. The result was attributed to limited high energetically favorable sorption sites on the root surface and similar sorption mechanisms of TCE and PCE. The results hold significant importance for the application of phytomonitoring of organic contaminant mixtures.
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