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Capability of Reused Waste from Aluminum Industry (Red Mud) in Iran to Improve Compressive Strength of Loose Soil Full text
2019
Daryabeigi Zand, A. | Rabiee Abyaneh, M. | Hoveidi, H.
Jajarm Alumina Plant, the only Alumina powder producer in Iran, generates 500,000 tons of red mud annually. The commonest method for final disposal of red mud in Iran is Tailing dam which is neither cost-effective nor environmentally-friendly. The main objective of this study is to evaluate the possibility of red mud recovery to be used for stabilization of loose soils. Red mud samples have been collected from tailing dam of Jajarm Alumina Plant to be characterized, using X-Ray Fluorescence (XRF). The soil stabilizer has been made by mixing red mud, steel slag, sodium metasilicate, and sodium hydroxide. In order to study the effect of soil stabilizer, five soil samples have been prepared which contain clay, sand, and wind-blown sand ranging from zero to 4 millimeters. Findings show that adding soil stabilizer with red mud significantly enhances compressive strength of soil samples (4.2, 18.2, 5.4, 4, and 4.1 in S1 to S5 samples, respectively). Also the results demonstrate that the red mud, produced from Aluminum industry in Iran, might be successfully used to stabilize loose soils, thereby enhancing their compressive characteristics, reducing environmental issues associated with uncontrolled disposal of such wastes as well as promoting integrated solid waste management strategies.
Show more [+] Less [-]The Study of CO Symptoms' Impacts on Individuals, Using GIS and Agent-based Modeling (ABM) Full text
2019
jalali, S. H. | vafaeinejad, A. R. | aghamohammadi, H. | Esmaeili Bidhendi, M.
The purpose of this study is to use both agent-based modeling as a new method in modeling dynamic phenomena and GIS to show the effects of carbon monoxide (CO) on individuals in the city of Tehran. After collecting the latest information about the severity of carbon monoxide pollutants on different days, one of the days with a very high severity of this pollutant has been selected for investigation and the interpolation map of its data has been developed via IDW method in ArcGIS software environment, which is then re-classified with the NetLogo software environment used to run the agent-based model. At this stage, the agents are randomly produced in four different age groups in the environment and begin moving with the onset of the running process in the environment. Also, the symptoms, caused by the pollution effects on the agents, appear in form of changes in color and are based on carboxyhemoglobin (COHb) levels (percentage) of each. The results indicate that among the considered older age groups, the members of the age group above 65, have had been mostly affected by pollution and the effect of pollution on the agents of the age group of 13 to 30 years old has been less than the other groups.
Show more [+] Less [-]A Novel and an Efficient 3-D High Nitrogen Doped Graphene Oxide Adsorbent for the Removal of Congo Red from Aqueous Solutions Full text
2019
Zeraatkar Moghaddam, A. | Ghiamati, E. | Pakar, R. | Sabouri, M. R. | Ganjali, M. R.
The current study both synthesizes and uses four compounds of graphene oxide (GO), nitrogen doped graphene oxide (ND-GO), high nitrogen doped graphene oxide (HND-GO), and three dimensional high nitrogen doped graphene oxide (3D-HND-GO) in order to remove a model anionic dye, Congo red (CR) from wastewaters. It also compares their carbon nano-structure, with regard to removal efficiency and finds out that 3D-HND-G yields higher efficiency in removal of CR, especially at lower pHs. This is due to its better dispersibility and greater surface area. Also, batch adsorption technique has been utilized and all involved parameters that affect the removal efficiency, e.g. initial pH, adsorbent dosage, initial CR concentration, and contact time are examined. The study applies Central Composite Design (CCD) to figure out their efficacies, with the results showing the following optimum conditions for removal of 100 ppm of CR: 4 mg/mL of the adsorbent, pH = 3, and 25 min of contact time. Furthermore, it studies the adsorption activity of the synthesized adsorbent, including kinetics, isotherm, and desorption comprehensibly. The adsorption isotherm is well-fitted through the Langmuir model, exhibiting high CR adsorption capacity. Also, CR adsorption kinetics shows that it has obeyed a pseudo-second-order kinetic model, indicating that adsorption has made the rate-limiting step. In addition, the proposed adsorbent has successfully been applied to reduce the concentration of CR as hazardous dye materials in the water and wastewater samples.
Show more [+] Less [-]Strategic Planning, Based on Environmental Spatial Assessment, Using SWOT and GIS to Locate Sustainable Industrial Areas (Case Study: Tehran Province) Full text
2019
Hoveidi, H. | Nasehi, S. | Imanpour, Namin | Nohegar, A.
Unbalanced distribution of population in a country like Iran as well as accelerating urbanization and environmental degradation, both arising from incorrect location of industrial areas, are two problems that require appropriate industrial development policies to get resolved. Considering the expansion of industrial areas along with their role in contamination of the environment, it is necessary to develop strategies to improve environmental performance. The purpose of this study is to provide strategies for establishment of industrial areas, based on environmental spatial assessment, using SWOT technique and GIS. In this method, once the spatial data are mapped and analyzed with GIS software, leading to determination of effective factors for location of industrial areas and their, the maps of such effective factors can be prepared. After weighing effective layers on location, based on the AHP model, the GIS software capabilities have been used to merge and overlap the maps and the industrial areas location map are prepared. The map has been classified in five classes (very poor, poor, moderate, good, and very good) and finally, based on the final map and SWOT analysis, optimal strategies have been developed to reduce environmental degradations. The location analysis with integrated GIS and SWOT method is effective for providing optimal strategies. More accurate results of this study show that the study area is located in "defensive" position and the authorized areas to locate the industrial areas in the "very good" class are over 240,191.9 hectares large, being mostly in the south and southwest of Tehran.
Show more [+] Less [-]Modeling and Optimization of the Coagulation–Flocculation Process in Turbidity Removal from Aqueous Solutions Using Rice Starch Full text
2019
Usefi, S. | Asadi-Ghalhari, M.
Natural coagulants have received much attention for turbidity removal, thanks to their environmental friendliness. The present study investigates potential application of rice starch for removal of turbidity from aqueous solutions. It considers the effects of four main factors, namely settling time (40-140 min), pH (2-8), slow stirring speed (20-60 rpm), and rice starch dosage (0-200 mg/L), each at five levels, by means of central composite design. Results show that a quadratic model can adequately describe turbidity removal in case of non-autoclaved rice starch with statistics of R2= 0.95, R2adj.= 0.91, R2pred.= 0.77, AP = 23.75, and CV = 4.77. It has also been found that the performance of non-autoclaved rice starch is superior to the autoclaved variety, in terms of removal efficiency and floc size. In the optimal point, predicted by the model, a removal efficiency equal to 98.4% can be attained, using non-autoclaved rice starch, which is higher than that of the autoclaved rice starch (71.29%). The significant effective parameters have proven to be settling time along with pH. Overall, rice starch can be considered a promising high potential coagulant for removal of turbidity from water or wastewater.
Show more [+] Less [-]Monitoring of Zn and Cr in Downstream Water from Uzunçayır Dam in Turkey Full text
2019
Topal, M. | Arslan Topal, E. I.
In this study, the concentrations of Zn and Cr in downstream waters from Uzunçayır Dam (Tunceli, Turkey) were monitored during spring (March, April, May) and summer (June, July, August) season. Zinc and Cr concentrations in surface water samples were detected using the ICP-MS device. According to the data obtained the lowest Zn and Cr concentrations in the spring season were 65.43±3.2 μg/L in March at 10th day for Zn and 0.28±0.02 μg/L in March at 10th and 20th day for Cr, the highest Zn and Cr concentrations were determined to be 83.12±4.1 μg/L in May at day 30 for Zn and 0.48±0.02 μg/L in May at day 30 for Cr. The lowest Zn and Cr concentrations in summer season were 55.48±2.7 μg/L at 30th day in August for Zn and 0.54±0.03 μg/L at 10th day in June for Cr. The highest Zn and Cr concentration in summer season were found as 69.48±3.5 μg/L in June at day 10 for Zn and 1.23±0.06 μg/L in August at day 30 for Cr. The Zn and Cr concentrations in the downstream of Uzunçayır Dam were found to be smaller than the Zn and Cr concentrations given by the Surface Water Quality Regulation (SWQR). As a result, it was determined that there was no harm in using water from the Uzunçayır Dam as irrigation water or drinking water in terms of Zn and Cr concentrations.
Show more [+] Less [-]Two-Dimensional Solute Transport with Exponential Initial Concentration Distribution and Varying Flow Velocity Full text
2019
Thakur, C. K. | Chaudhary, M. | van der Zee, S.E.A.T.M. | Singh, M. K.
The transport mechanism of contaminated groundwater has been a problematic issue for many decades, mainly due to the bad impact of the contaminants on the quality of the groundwater system. In this paper, the exact solution of two-dimensional advection-dispersion equation (ADE) is derived for a semi-infinite porous media with spatially dependent initial and uniform/flux boundary conditions. The flow velocity is considered temporally dependent in homogeneous media however, both spatially and temporally dependent is considered in heterogeneous porous media. First-order degradation term is taken into account to obtain a solution using Laplace Transformation Technique (LTT) for both the medium. The solute concentration distribution and breakthrough are depicted graphically. The effect of different transport parameters is studied through proposed analytical investigation. Advection-dispersion theory of contaminant mass transport in porous media is employed. Numerical solution is also obtained using Crank Nicholson method and compared with analytical result. Furthermore, accuracy of the result is discussed with root mean square error (RMSE) for both the medium. This study has developed a transport and prediction 2-D model that allows the early remediation and removal of possible pollutant in both the porous structures. The result may also be used as a preliminary predictive tool for groundwater resource and management.
Show more [+] Less [-]Impact of Hindon River Water on Selected Riparian Flora (Azadirachta Indica and Acacia Nilotica) with special Reference to Heavy Metals Full text
2019
Ruhela, M. | Bhutiani, R. | Ahamad, F. | Khanna, D.R.
The present study aims to identify the impact of polluted aquatic body i.e. River Hindon on two selected riparian flora i.e. Azadirachta indica and Acacia nilotica. During the course of study the average concentration of different metals in river water was found as Iron (Fe) 11.27ppm±3.50, Manganese (Mn) 4.00ppm±1.26, Cadmium (Cd) 0.08ppm±0.07, Nickel (Ni) 0.63ppm±0.17 and Zinc (Zn) 1.46ppm±0.38 respectively. The average concentration of heavy metals in A. indica of sampling site was found as Iron (Fe) 24.76ppm±6.25, Manganese (Mn) 5.04ppm±1.38, Cadmium (Cd) 0.05ppm±0.05, Nickel (Ni) 0.34ppm±0.20 and Zinc (Zn) 53.92ppm±19.29 respectively while in control site plant average concentration was found as Iron (Fe) 17.18ppm±3.96, Manganese (Mn) 3.63ppm±1.63, Cadmium (Cd) 0.02ppm±0.03, Nickel (Ni) 0.16ppm±0.06 and Zinc (Zn) 31.26ppm±12.11 respectively and average concentration in A. nilotica of sampling sites was found as Iron (Fe) 45.78ppm±10.67, Manganese (Mn) 42.08ppm±11.98, Cadmium (Cd) 0.59ppm±0.51, Nickel (Ni) 40.83ppm±12.16 and Zinc (Zn) 144.10ppm±49.94 respectively while average concentration in control site plant was found as Iron (Fe) 27.76ppm±9.49, Manganese (Mn) 22.75ppm±7.09, Cadmium (Cd) 0.42ppm±0.27, Nickel (Ni) 23.53ppm±8.02 and Zinc (Zn) 96.61ppm±24.78 respectively. One way ANOVA shows statistically significant difference between sampling site plant and control site plant for all the studied metals except Cr in A. nilotica F (3, 42) = 0.589, P= 0.626. A big difference was found in the concentration of metals between sampling site plants and control site plant. In case of metal uptake A. nilotica was found more efficient as comparison to A. indica.
Show more [+] Less [-]A Review on Impact of E-waste on Soil Microbial Community and Ecosystem Function Full text
2019
Salam, M.D. | Varma, A.
The ever increasing pile-up of electronic waste in dumping sites, especially in developing countries such as China, Pakistan, India and several African countries, might have caused a significant alteration in the microbial community of the contaminated sites. This change in the microbial population may have significant impact to the soil ecology function. The major pollutants of electronic waste are heavy metals like cadmium, lead, nickel, mercury, hexavalent chromium, arsenic and persistent organic pollutants like polychlorinated biphenyls and polybrominated diphenyl ethers. In general, the toxic pollutants reduce the normal soil microbial biota but give rise to increase in the heavy metal resistant and organic pollutants remediating microbes. With the development of culture- independent approach as a tool for studying microbial diversity, the microbial community structures in toxic waste contaminated sites have been revealed gradually. Studies on the microbial community structure of electronic waste contaminated sites show that there are significant differences between the contaminated and the non-contaminated sites. Soil pH in the e-waste contaminated sites of various regions has been reported in a wide range varying from pH 4 to pH 12. However, the predominant phyla so far identified in the electronic waste contaminated sites, based on studies through culture independent approach, are Firmicutes, Proteobacteria, Actinobacteria, Acidobacteria, Chloroflexi, Crenarchaeota and Bacteroidetes accounting for more than 80% of the total sequence reads on an average. The genera like Pseudomonas, Bacillus, Clostridium, Rhodococcus, Achromobacter and many unclassified bacteria are the common types in the contaminated sites.
Show more [+] Less [-]Introduction and Application of New GIS_AQI Model: Integrated Pollution Control in Tehran Full text
2019
Pardakhti, A. | Ebrahimi Qadi, M.
The city of Tehran undergoes an increasing growth in population as well as industrial activities, both of which increase the concentration of air pollutants. The current research tries to turn a limited and focused system of air contamination measurement and control to an unlimited and extensive one that examines the concentration of each of the contaminants in any area of Tehran. Accordingly, information from twenty air-pollution measurement stations at certain points of the city helps measuring the concentrations of contaminants like SO2, NO2, CO, O3, PM2.5, and PM10 throughout a year on a daily basis. The index of AQI has also been used as the air quality index to determine the level of pollution in the city. Using ARC-GIS software, the AQI or the air quality index has been zoned and a comprehensive map, designed. Moreover, in order to illustrate this map, a map of the zoning has been drawn up for this purpose on December, 26, 2016, considered an unhealthy day in Tehran, the results of which show that only 27.8% of the city is unhealthy and the rest of the city does not fall in unhealthy area. However, due to the lack of a comprehensive map for determining the AQI in different parts of the city, the whole city closes down, leading in an economic loss of about $ 1 million a day for the city.
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