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Heavy Metal Removal from Contaminated Soil Using Soil Washing Techniques
2023
Resmi, G. | G. Thampi, Santosh | Chandrakaran, S.
Heavy metals are discharged into the soil around us from various anthropogenic sources and also by the use of fertilizers, pesticides, pharmaceuticals, etc. In most cases, industrialization can be pointed to as the reason behind soil pollution. Contamination of soil leads to large-scale environmental degradation and health impacts. Many investigators have studied techniques for removing heavy metals from soil. Soil washing is an emerging area that can be implemented for this purpose. Studies were carried out in the controlled conditions of a laboratory environment to determine the suitability of soil-washing techniques for removing lead from polluted land. The results showing the influence of various parameters in soil washing, such as duration of washing, molar strength of the solution used, the weight ratio of soil to wash solution, etc., are presented in this paper. Batch studies were conducted to investigate the performance of chelating agents such as Na2EDTA, HCl, HNO3 and CaCl2 with regard to the removal of lead from artificially contaminated locally available soil. Based on the batch studies, it is observed that the strength of the washing solution, the proportion of soil and solution, the period of agitation, etc. influence the removal of contaminants. Based on the studies, it is concluded that, while recommending soil washing using chelating agents for remediating lead-contaminated soils, it is essential to identify the influencing parameters and determine the optimum conditions so that higher removal can be achieved without any adverse effect.
Show more [+] Less [-]Evaluation of Biomass Solid Waste as Raw Material for Preparation of Asphalt Mixture
2023
Tao, He | Liu, Hongming | Yang, Jie | Sun, Tao
At present, the resource utilization of solid waste in China is facing prominent problems such as high production intensity, insufficient utilization, and low added value of products. The preparation of biomass composites from biomass solid waste and plastic solid waste reduces not only environmental pollution and energy consumption but also promotes the high-value utilization of solid waste. So, the characterization and preparation experiments of samples with two different biomass are carried out. The wheat straw fiber and corn straw fiber were added into the bio-asphalt mixture with the content of 0.1%, 0.2%, 0.3%, and 0.4%, respectively, with the content of 9% and 12% bio-heavy oil. The physical properties and rheological properties of asphalt were analyzed and evaluated by three indexes and a dynamic shear rheological test. Through the rutting test and immersion Marshall test, high-temperature performance and biological asphalt mixture’s water stability were evaluated. The results show that straw fiber can improve bio-asphalt mixture’s road performance, especially the performance of high-temperature rutting. When the fiber content of bio-asphalt with 9% bio-heavy oil content is 0.3%, the physical properties and rheological properties of bio-asphalt are the best. Corn straw fiber’s influence on bio-asphalt mixture was better than that of wheat straw fiber.
Show more [+] Less [-]The Influence of Geographical Factors on Polyploidy in Angiosperms with Cartographic Evidence from the Northwestern Himalayas: A Review
2023
Tiwana, Anupreet Singh | Thummalakunta, Siva Prathap | Gupta, Saurabh | Singh, Vijay | Kataria, Ramesh Chand
The review paper comprised the impact of geographical and environmental factors on polyploidy and vice versa. The review covers different effects of geographical factors, like spatial isolation, altitude, and local climate on polyploidy, and the behavior of polyploid(s) in abiotic factors, such as temperature and light with a few examples of northwest Himalayas. The paper concludes that polyploid plants behave differently in environmental conditions, as polyploids are more prominent in higher altitudes, colder environments, and nutrient-rich soil than diploid progenitors, but have a mixed distribution in different geographical conditions. Further, polyploidy is more common among perennials than annuals, while niche differentiation depends more on the local environment. The virtual case study results from North and North Western India have been shown with the help of ArcGIS online software. The scrutiny of spatial distribution on maps highlights the fact that polyploidy is still a complex research puzzle with interesting perspectives.
Show more [+] Less [-]Pattern Characterization of Meteorological Drought Using Multivariate Drought Index Over Mirzapur in Middle Gangetic Plains of India
2023
Gond, Shivani | Gupta, Nitesh | Dikshit, P. K. S. | Bihari Dwivedi, Shyam
Droughts and floods have been occurring at a higher frequency in recent decades. The rapid transition between them magnifies the socio-economic consequences of these catastrophes relative to the effects of the individual occurrences of the extreme event. This study examines the temporal variability of meteorological drought and wet event characteristics occurring over Mirzapur (Uttar Pradesh), India. The Standardized Precipitation Evapotranspiration Index (SPEI) is applied to monthly water balance at scales 3, 6, 9, and 12 months to estimate the meteorological drought and wet events from 1971 to 2018. Drought and wet event characteristics such as the number of drought/wet events, severity, duration, and intensity are estimated using run theory over SPEI output. While characterizing the pattern of trends over the historical time period, variable-sized cluster analysis (VSCA) allows the detection of multiple change points as opposed to the Mann-Kendall (MK) test, which produces a monotonic trend for the entire time period. The VSCA technique accounts for drought variability and depicts the pattern’s evolution across the period under consideration. Station-scale drought data from Mirzapur, Uttar Pradesh (UP), India, were used in the procedure. VSCA allows for the detection of many change points while describing the pattern of drought trend throughout a historical period, as opposed to the usual Mann-Kendall (MK) test, which provides a monotonic trend for the whole time. As a result, VSCA demonstrated the MK test compatibility.
Show more [+] Less [-]Impacts of microplastics and heavy metals on the earthworm Eisenia fetida and on soil organic carbon, nitrogen, and phosphorus
2023
Mai, Huong | Thien, Nguyen Danh | Dung, Nguyen Thuy | Valentin, Christian
Microplastics (MPs) are increasingly being studied because they have become ubiquitous in aquatic and terrestrial environments. However, little is known about the negative effects of co-contamination by polypropylene microplastic (PP MPs) and heavy metal mixtures on terrestrial environment and biota. This study assessed the adverse effects of co-exposure to PP MPs and heavy metal mixture (Cu2+, Cr6+, and Zn2+) on soil quality and the earthworm Eisenia fetida. Soil samples were collected in the Dong Cao catchment, near Hanoi, Vietnam, and analyzed for changes in extracellular enzyme activity and carbon, nitrogen, and phosphorus availability in the soil. We determined the survival rate of earthworms Eisenia fetida that had ingested MPs and two doses of heavy metals (the environmental level — 1 × — and its double — 2 ×). Earthworm ingestion rates were not significantly impacted by the exposure conditions, but the mortality rate for the 2 × exposure conditions was 100%. Metal-associated PP MPs stimulated the activities of β-glucosidase, β-N-acetyl glucosaminidase, and phosphatase enzymes in soil. Principle component analysis showed that these enzymes were positively correlated with Cu2+ and Cr6+ concentrations, but negatively correlated with microbial activity. Zn2+ showed no correlation with soil extracellular enzyme activity or soil microbial activity. Our results showed that co-exposure of earthworms to MPs and heavy metals had no impact on soil nitrogen and phosphorus but caused a decrease in total soil carbon content, with a possible associated risk of increased CO2 emissions.
Show more [+] Less [-]Air pollution and agricultural labor supply: Evidence from China
2023
Ye, Hai-Jian | Huang, Zuhui | Chen, Shuai
Categorization of Mining Materials for Restoration Projects by Means of Pollution Indices and Bioassays
2023
Ferri-Moreno, Inmaculada | Barquero-Peralbo, Jose Ignacio | Andreu-Sánchez, Oscar | Higueras, Pablo | Roca-Pérez, Luis | García-Lorenzo, Mari Luz | Esbrí, Jose María
Sulfide mining wastes may lead to severe environmental and human health risks. This study aims to use geochemical and ecotoxicological indicators for the assessment of the ecological risks of potentially toxic elements (PTEs) in the San Quintín mining group to categorize wastes prior to mining restoration. Ecotoxicity was evaluated using crustacean (Dahpnia magna, Thamnocephalus platyurus) and algae (Raphidocelis subcapitata) bioassays. The geochemical and mineralogical results suggested that the mining residues underwent intense weathering processes, with active processes of acidity generation and metal mobility. Total PTEs concentrations indicated that the mining materials were extremely polluted, with Pb, Zn and Cd geoaccumulation index (Igeo) values higher than 5 in more than 90% of the samples. The pollution load index (PLI) showed average values of 18.1, which classifies them as very highly polluted. The toxicity tests showed a higher toxicity for plants than crustaceans, being the highest values of toxicity related to toxic elements (Pb, Cd and Zn), electrical conductivity and to pH. This paper presents for the first time the combination of indices in the categorization of mining waste prior to its restoration. The combination of them has made it possible to categorize the waste and adapt the restoration and remediation procedures.
Show more [+] Less [-]Wild and ruderal plants as bioindicators of global urban pollution by air, water and soil in Riyadh and Abha, Saudi Arabia
2023
Picó García, Yolanda | Campo Velásquez, Julián | Barceló i Cullerés, Damià
Recently, environment pollution around the globe has increased because of anthropogenic activities. As part of the biota, plants can assimilate the compounds present in air, water and soil and respond to changes in surround conditions, for that, they can be used as bioindicators of global pollution. However, urban plants' ability to monitor organic pollutants in air, soil, and water have not been profoundly studied yet. Anthropogenic contamination produced by five different types of pollutants [polycyclic aromatic hydrocarbons (PAHs), pharmaceuticals and personal care products (PPCPs), perfluoroalkyl substances (PFASs), pesticides and organophosphorus flame retardants (OPFRs)] has been studied in Riyadh and Abha areas (Saudi Arabia). In addition to the points in both cities, a control point located in the Asir National Park (close to Abha), which is little affected by human activity, was used. The 5 groups of contaminants were found with different but high detection frequencies from 85 % to 100 % in wild and ruderal plants. PAHs were detected in all the analyzed samples at the highest average sum of concentrations (ΣPAHs) 1486 ng·g−1 dry weight (d.w.). Statistically significant differences were obtained between Riyadh, Abha and the point located in the national park (p < 0.05). ΣPAHS in Riyadh >> ΣPAHs in Abha > ΣPAHs in the National Park. Values of the average sum of concentrations for the other groups of contaminants ΣPPCPs, ΣPFASs, Σpesticides and ΣOPFRs were 420.5, 171, 48 and 47 ng g−1 d.w., respectively. High values of PPCPs are due to the presence of salicylic acid. Differences in the average sum of each type of contaminant concentrations between cities were not statistically significant. The results of this assessment of wild and ruderal plants as bioindicators for 5 types of organic contaminants suggest that they can be used to monitor anthropogenic contaminants in the terrestrial environment.
Show more [+] Less [-]Toward a better understanding of the environmental impacts of expanding farmer-led irrigation in Sub-Saharan Africa: An exploratory assessment of irrigation-induced risk of nutrient water pollution in Ethiopia
2023
Xie, Hua | Dile, Yihun T. | Ringler, Claudia | Srinivasa, R. | Worqlul, Abeyou Wale
Irrigation, and especially farmer-led irrigation, is considered to be a promising option for enhancing agricultural productivity in Sub-Saharan Africa. However, there is a lack of thorough understanding of the impacts of irrigation development on environment. Past discussions are mainly limited to the water depletion and hydrological regime change effect of irrigation. This paper presents a study to narrow the knowledge gap by assessing nutrient water pollution risk induced by the expansion of farmer-led irrigation in Ethiopia. Using household survey data collected from four woredas in Ethiopia where irrigated crop production currently concentrates, we first evaluate the impact of irrigation on cropping intensity and annual consumption level of fertilizers and then use the findings of the household survey data analysis to support conceptualization of a modeling framework for assessing agricultural nutrient water pollution risk from farmer-led irrigation development in Ethiopia at national scale. We project that overall farmer-led irrigation development in Ethiopia will lead to a gentle increase in national total of agricultural nutrient loadings. This result helps justify the endeavor of promoting farmer-led irrigation in Ethiopia. On the other hand, the projected nutrient flow and nutrient loading growth rate related to the farmer-led irrigation expansion are highly heterogeneous spatially, and risk of local water quality deterioration exists. There is still need to make investment to ensure the environmental sustainability of farmer-led irrigation development.
Show more [+] Less [-]Microplastics: What Can We Learn from Clastic Sediments?
2023
Waldschläger, Kryss | Brückner, Muriel Z.M. | Almroth, Bethanie Carney | Hackney, Christopher R. | Adyel, Tanveer M. | Alimi, Olubukola S. | Belontz, Sara L. | Cowger, Win | Doyle, Darragh | Gray, Andrew | Kane, Ian | Kooi, Merel | Kramer, Matthias | Lechthaler, Simone | Michie, Laura | Nordam, Tor | Pohl, Florian | Russell, Catherine | Thit, Amalie | Umar, Wajid | Valero, Daniel | Varrani, Arianna | Warrier, Anish K. | Woodall, Lucy C. | Wu, Nan
Microplastics research has gained momentum in the 21st century but lags behind the long-standing research on clastic sediment. An interdisciplinary review paper was conducted, comparing microplastics with natural sediments in terms of particle properties, transport processes, sampling techniques, and ecotoxicology. The paper identifies seven research goals to enhance our understanding of microplastics in freshwater environments while learning from sediment research. This extended abstract presents the core message of the review paper, emphasizing the need to improve descriptions of microplastic particles, understand their transport processes, develop standardized sampling methods, and study their ecotoxicological effects. The research goals outline specific tasks to achieve these objectives and emphasize the importance of comparing microplastics to sediments to gain insights into their toxicity. Addressing these research goals will contribute to a comprehensive understanding of microplastics and their impact on freshwater ecosystems. For detailed insights, the original paper should be consulted.
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