The concentration of human activities in the near-shore ecosystems from the northern Antarctic Peninsula area can cause an increasing bioavailability of pollutants for the vulnerable Antarctic biota. Penguin chicks can reflect this potential impact in the rookeries during the breeding season. They also can reflect biomagnification phenomena since they are on the top of the Antarctic food chain. The concentrations of Al, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Cd and Pb were measured by ICP-MS in samples of liver, kidney, muscle, bone, feather and stomach content of gentoo, chinstrap and Adélie penguin chicks (n=15 individuals) collected opportunistically in the Islands of King George and Deception (South Shetland Islands, Antarctica). The detected levels of some trace elements were not as low as it could be expected in the isolated Antarctic region. Penguin chicks can be useful indicators of trace elements abundance in the study areas.Carcasses of Antarctic penguin chicks were used to evaluate the bioavailability of trace elements in the Islands of King George and Deception.

We investigated the effects of river floods on the macrobenthic community of the intertidal flat in the Ohta River Estuary, Japan, from 2005 to 2010. Sediment erosion by flood events ranged from about 2–3cm to 12cm, and the salinity dropped to 0‰ even during low-intensity flood events. Cluster analysis of the macrobenthic population showed that the community structure was controlled by the physical disturbance, decreased salinity, or both. The opportunistic polychaete Capitella sp. was the most dominant species in all clusters, and populations of the long-lived polychaete Ceratonereis erythraeensis increased in years with stable flow and almost disappeared in years with intense flooding. The bivalve Musculista senhousia was also an important opportunistic species that formed mats in summer of the stable years and influenced the structure of the macrobenthic community. Our results demonstrate the substantial effects of flood events on the macrobenthic community structure.

Neuston samples were collected at 21 stations during an ∼700 nautical mile (∼1300km) expedition in July 2012 in the Laurentian Great Lakes of the United States using a 333μm mesh manta trawl and analyzed for plastic debris. Although the average abundance was approximately 43,000 microplastic particles/km2, station 20, downstream from two major cities, contained over 466,000particles/km2, greater than all other stations combined. SEM analysis determined nearly 20% of particles less than 1mm, which were initially identified as microplastic by visual observation, were aluminum silicate from coal ash. Many microplastic particles were multi-colored spheres, which were compared to, and are suspected to be, microbeads from consumer products containing microplastic particles of similar size, shape, texture and composition. The presence of microplastics and coal ash in these surface samples, which were most abundant where lake currents converge, are likely from nearby urban effluent and coal burning power plants.

Sediment contamination poses a potential risk for both ecosystems and human health. Risk assessment is troublesome as sediments contain complex mixtures of toxicants, and traditional chemical analyses can neither provide information about potential hazards to organisms nor identify and measure all present contaminants. This work combines the use of the PLHC-1 cell line and the recombinant yeast assay (RYA) to assess the environmental quality of estuarine and coastal sediments. The application of multiple endpoints (cytotoxicity, generation of oxidative stress, presence of CYP1A inducing agents, micronucleus formation and estrogenicity) revealed that the organic extracts of those sediments affected by industrial activities or collected near harbours and untreated urban discharges showed significant cytotoxicity, micronuclei and CYP1A induction. The study highlights the usefulness of the applied bioassays to identify those sediments that could pose risk to aquatic organisms and that require further action to improve their environmental quality.

Heavy metal (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) concentrations in surface sediments from the Changhua River Estuary and adjacent shelf, western Hainan Island, were conducted to evaluate the level of contamination. Numerical Sediment Quality Guidelines (TEL and PEL) were applied to assess adverse biological effects of these metals, suggesting that occasional biological effect may occur due to As, Cr, Cu, Ni, and Pb. Enrichment factors shown that the significant As and Pb contaminations in the study area. Multivariate analysis indicated that the sources of Cd, Cr, Cu, Hg, Ni and Zn resulted primarily from natural weathering processes, whereas As and Pb were mainly attributed to anthropogenic sources. The results of this study would provide a useful aid for sustainable marine management in the region.

The goal of this study was to determine the potential for Enterohemorrhagic Escherichia coli O157:H7 (EHEC) contamination in tropical marine waters. Samples were collected from urban, suburban, and rural sites around the islands of Puerto Rico and The Republic of Trinidad and Tobago. Quantification of E. coli and EHEC was evaluated using MI plates and qPCR. EHEC was detected in six sites in Puerto Rico: West of La Parguera Town, Boquilla, Oro Creek, Fishers Association, Joyuda Lagoon, and Boqueron Wetland Creek and in two rural sites in Trinidad: Balandra Bay and Quinam Bay. Plate count enumeration of E. coli was not a reliable indicator for the presence of EHEC. The sites where EHEC was detected on both islands are used for recreational bathing, water sports and recreational/commercial fisheries and therefore pose a public potential health risk.

Test facilities such as lab basins and wave tanks are essential when evaluating the use of chemical dispersants to treat oil spills at sea. However, these test facilities have boundaries (walls) that provide an ideal environment for surface (interfacial) film formation on seawater. Surface films may form from surfactants naturally present in crude oil as well as dispersant drift/overspray when applied to an oil spill. The objective of this study was to examine the impact of surface film formation on oil spreading rates in a small scale lab basin and on dispersant effectiveness conducted in a large scale wave tank. The process of crude oil spreading on the surface of the basin seawater was influenced in the presence of a surface film as shown using a 1st order kinetic model. In addition, interfacial film formation can greatly influence chemically dispersed crude oil in a large scale dynamic wave tank.

The concept of Ecological Potential was explored using the macrobenthic communities of the Mondego estuary (Portugal). Different scenarios (loss of a primary producer and intertidal habitat, and habitat modification due to hydromorphological changes and continued press perturbation) were tested to predict changes in the biology if hydromorphological pressures could be reversed, assuming that differences with and without the pressure could indicate the potential.Results showed noticeable changes in the system biology in each scenario. The approach followed, indicates that when data sets exist, differences in the measurement of ecological status with and without the hydromorphological change could be a way forward to determine the potential. In the particular case of the Mondego estuary, the South arm (physically unaltered water body) proved to be richer than the North (HMWB). For the Ecological Potential determination, the South arm could thus be used to derive and adjust future reference conditions for the North.

We studied the role of small, highly stratified, sulfate and nutrient enriched estuaries, as a source or sink of inorganic nitrogen species, using the Qishon estuary at the Mediterranean coast of Israel, as a case study. Measurements of nutrient concentrations, δ15N and δ18O of nitrate+nitrite, δ13CDIC and δ18OH2O were performed during 2008–2009 along the upper-fresh and lower-saline water masses, as well as sediment porewater depth-profiles. Such estuaries are characterized by relatively low removal flux of NO3- (via sedimentary denitrification) and enhanced (×3) upward flux of NH4+ (via sulfate reduction), attributed to the penetration of seawater of low NO3- and high dissolved oxygen and sulfate concentrations. The role of such small estuaries in releasing dissolved inorganic nitrogen, especially in sensitive oligotrophic areas as the Levantine basin and in the long-term, as a result of enhanced seawater penetration due to the expected sea level rise, has important environmental policy implications.

Risk zones that could be subject to the impacts of oil spills were identified at a national scale across the 23 coastal provinces of Thailand based on the average percentage risk of critical variables, including frequency of oil spill incidents, number of ports, number of local boats, number of foreign boats, and presence of important resources (i.e., protection area, conservation area, marine park, mangrove, aquaculture, coral reef, seagrass, seagull, seabird, sea turtle, dugong, dolphin, whale, guitar fish, and shark). Risks at the local scale were determined based on the frequency of simulated oil slicks hitting the coast and/or important resources. Four zones with varied risk magnitudes (low, moderate, high, and very high) were mapped to guide the preparation of effective plans to minimize oil spill incidents and impacts in coastal waters. Risk maps with sufficient information could be used to improve regulations related to shipping and vessel navigation in local and regional seas.