Mercury (Hg), selenium (Se) and nitrogen (δ15N) stable isotope were assessed in a tropical food web of Rio de Janeiro’s north coast. Isotopic data on muscle suggest a difference related to this parameter along the food web; where top-predators (cetacean and voracious fish) displayed heavier δ15N over the entire food web. Both top-predators presented similar δ15N values. Cetacean displayed higher Hg and lower Se than voracious fish. Five trophic positions (TP) were found in relation to primary consumer as baseline, ranging from 2.0 to 4.0. Positive relationships were found between trace-element and δ15N. The slope of regression equations (0.11 for Se and 0.21 for Hg) and food web magnification factors (2.4 for Se and 5.4 for Hg) showed that Hg presented higher rate of increase over the food web. Simultaneous measurements of trace-elements and ecological tracers emphasize the importance of TP into the trophic structure and distribution of Hg and Se throughout the food web.

Microplastics are present in marine habitats worldwide and laboratory studies show this material can be ingested, yet data on abundance in natural populations is limited. This study documents microplastics in 10 species of fish from the English Channel. 504 Fish were examined and plastics found in the gastrointestinal tracts of 36.5%. All five pelagic species and all five demersal species had ingested plastic. Of the 184 fish that had ingested plastic the average number of pieces per fish was 1.90±0.10. A total of 351 pieces of plastic were identified using FT-IR Spectroscopy; polyamide (35.6%) and the semi-synthetic cellulosic material, rayon (57.8%) were most common. There was no significant difference between the abundance of plastic ingested by pelagic and demersal fish. Hence, microplastic ingestion appears to be common, in relatively small quantities, across a range of fish species irrespective of feeding habitat. Further work is needed to establish the potential consequences.

The possibility of current-driven propagation of contaminants released along a major fairway polluting the Marine Protected Areas (MPAs) in the Gulf of Finland, the Baltic Sea, is examined using a 3D circulation model, a Lagrangian transport model and statistics. Not surprisingly, the number of hits to the MPA decreases almost linearly with its distance from the fairway. In addition, the potential pollution released during a ship accident with the pollutants carried by currents may affect MPAs at very large distances. Typically, a fairway section approximately 125km long (covering about 1/3 of the approximate 400-km-long gulf) may serve as a source of pollution for each MPA. The largest MPA (in the Eastern Gulf of Finland) may receive pollution from an approximately 210-km-long section (covering about 1/2 of the entire length of the gulf). This information may be useful in assisting maritime management.

In this study, the activity concentrations of 210Po and 210Pb were determined in mussels (Mytilus galloprovincialis) collected from Didim and Izmir Bay (Turkish coast of Aegean Sea) during the period of April 2006–March 2007. The concentrations activity of 210Po were determined spectroscopically through its 5.30MeV alpha particle emission, using 209Po as an internal tracer. The 210Pb activity concentrations were determined from the ingrowth of 210Po, assuming zero initial 210Po activity. The results of 210Po and 210Pb activity concentrations were found to vary between 34±9 and 1855±98Bqkg−1 dry weight and ND (lower than limit of detection) – 64±6Bqkg−1 dry weight, respectively. 210Po/210Pb ratio ranged between 1.00 and 106.87. The highest 210Po activities were found in mussels collected from Didim.

Marine fish farms could cause environmental disturbances on the sediment due to uneaten food and fish faeces that impact the marine benthos. Polychaete assemblages are considered good indicators of environmental perturbations. The present study aimed to establish groups of polychaetes as potential indicators of fish farm pollution. This study was carried out in ten fish farms along the Spanish coast. Changes in polychaete assemblage were analyzed with meta-analysis and multivariate techniques. Abundance, richness and diversity showed significant decreases under fish farm conditions. Distribution patterns of polychaetes responded to combinations of physicochemical variables. The main ones are sulfide concentration, silt and clays percentage, and stable nitrogen isotope ratio. The results showed that some families are tolerant, Capitellidae, Dorvilleidae, Glyceridae, Nereididae, Oweniidae and Spionidae; while others are sensitive to fish farm pollution, Magelonidae, Maldanidae, Nephtyidae, Onuphidae, Paralacydoniidae, Paraonide, Sabellidae and also Cirratulidae in spite of being reported as a tolerant family.

There has been a widespread world-wide use of flathead mullet, Mugilcephalus, in fish biomonitor studies within the coastal zone. This review summarises this research field, focusing on heavy metals, and considers the implications of the accumulated data. Differences in sampling methodology, tissues analysed and units of reported data provide challenges in assessing and benchmarking these biomonitor studies. The benthic feeding strategy of M.cephalus invariably increases exposure risk relative to middle or upper water column feeders, nevertheless contaminant accumulation via direct and indirect pathways was regulated sufficiently such that toxicants were below food guidelines in most coastal regions (32 of the 49 examined). Human health issues can arise if fish are consumed from heavily industrialised regions. Recommendations are provided for future biomonitoring studies, based on the results for M. cephalus but relevant for fish species more broadly, to provide more comparable data so that managers can benchmark against local conditions.

Large scale environmental remediation projects applied to sea water always involve large amount of capital investments. Rigorous effectiveness evaluations of such projects are, therefore, necessary and essential for policy review and future planning. This study aims at investigating effectiveness of environmental remediation using three different Seemingly Unrelated Regression (SUR) time series models with intervention effects, including Model (1) assuming no correlation within and across variables, Model (2) assuming no correlation across variable but allowing correlations within variable across different sites, and Model (3) allowing all possible correlations among variables (i.e., an unrestricted model). The results suggested that the unrestricted SUR model is the most reliable one, consistently having smallest variations of the estimated model parameters. We discussed our results with reference to marine water quality management in Hong Kong while bringing managerial issues into consideration.

Water turbidity and suspended sediment concentration (SSC) are commonly used as part of marine monitoring and water quality plans. Current management plans utilise threshold SSC values derived from mean-annual turbidity concentrations. Little published work documents typical ranges of turbidity for reefs within open coastal waters. Here, time-series turbidity measurements from 61 sites in the Great Barrier Reef (GBR) and Moreton Bay, Australia, are presented as turbidity exceedance curves and derivatives. This contributes to the understanding of turbidity and SSC in the context of environmental management in open-coastal reef environments. Exceedance results indicate strong spatial and temporal variability in water turbidity across inter/intraregional scales. The highest turbidity across 61 sites, at 50% exceedance (T50) is 15.3 NTU and at 90% exceedance (T90) 4.1 NTU. Mean/median turbidity comparisons show strong differences between the two, consistent with a strongly skewed turbidity regime. Results may contribute towards promoting refinement of water quality management protocols.

The surface sediments from Laizhou Bay (LB) and the coastal sea around Zhangzi Island (ZI) were analyzed for acid-volatile sulfide (AVS) and simultaneously extracted metals (SEMs) to assess the sediment quality. These two areas, especially LB, are important mariculture bases in China and are significantly affected by the Yellow River. The concentrations of AVS ([AVS]) and SEM ([SEM]) varied in the ranges 0.71–11.03 and 0.10–0.74μmolg−1 dry weight, respectively. [AVS] was generally low in the river outlet area and increased in the seaward direction in LB. [AVS] was significantly and positively correlated with TOC. [SEM] was significantly and positively correlated with TOC, the water content of sediment and the fine sediment fraction and it was significantly and negatively correlated with coarse sediment fraction. The obtained results suggest that the surface sediments of LB and ZI were of high quality and not likely to cause negative effects on their ecosystems.

The fluorescence EEM technique, PARAFAC modeling, and hydrocarbon composition were used to characterize oil components and to examine the chemical evolution and degradation pathways of Macondo crude oil under controlled laboratory conditions. Three major fluorescent oil components were identified, with Ex/Em maxima at 226/328, 262/315, and 244/366nm, respectively. An average degradation half-life of ∼20d was determined for the oil components based on fluorescence EEM and hydrocarbon composition measurements, showing a dynamic chemical evolution and transformation of the oil during degradation. Dispersants appeared to change the chemical characteristics of oil, to shift the fluorescence EEM spectra, and to enhance the degradation of low-molecular-weight hydrocarbons. Photochemical degradation played a dominant role in the transformation of oil components, likely an effective degradation pathway of oil in the water column. Results from laboratory experiments should facilitate the interpretation of field-data and provide insights for understanding the fate and transport of oil components in the Gulf of Mexico.