The current study provides an information on the combined effect of pollution with potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) in hydromorphic soils on the accumulation, growth, functional and morphological-anatomical changes of macrophyte plant, i.e., Phragmites australis Cav., as well as information about their bioindication status on the example of small rivers of the Azov basin. The territory of the lower reaches of the Kagalnik River is one of the small rivers of the Eastern Azov region was examined with different levels of PTEs contamination in soils, where the excess of the lithosphere clarkes and maximum permissible concentrations (MPC) for Mn, Cr, Zn, Pb, Cu, and Cd were found. The features of the 16 priority PAHs quantitative and qualitative composition in hydromorphic soils and P. australis were revealed. The influence of soil pollution on accumulation in P. australis, as well as changes in the morphological parameters were shown. It has been observed that morphometric changes in P. australis at sites experiencing the сontamination and salinity are reflected with the changes in the ultrastructure of plastids, mitochondria, and EPR elements of plant cells. PTEs accumulated in inactive organs and damaged cell structures. At the same time, PAHs penetrated through the biomembranes and violated their integrity, increased permeability, resulted cell disorganization, meristem, and conductive tissues of roots. The nature and extent of the structural alterations found are dependent on the type and extent of pollution in the examined regions and can be utilized as bioindicators for evaluating the degree of soil phytotoxicity characterized by the accumulation of PTE and PAHs.

Both heavy metals and radiation could affect the proliferation and dissemination of emerging antibiotic resistance pollutants. As an environmental medium rich in radioactive metals, the profile of antibiotic resistance in uranium mine remains largely unknown. A uranium mine in Guangdong province, China was selected to investigate the distribution and influencing factors of antibiotic-resistant bacteria (ARB) and antibiotic resistance genes (ARGs) including intracellular ARGs (iARGs), adsorbed-extracellular ARGs (aeARGs), and free extracellular ARGs (feARGs). The result indicated that sulfonamide and tetracycline ARB could be generally detected in mining area with the absolute concentrations of 7.70 × 10²–5.18 × 10⁵ colony forming unit/g. The abundances of aeARGs in mine soil were significantly higher than those of iARGs (p < 0.05), highlighting the critical contribution of aeARGs to ARGs spread. The feARGs in mine drainage and its receiving river were abundant (3.38 × 10⁴–1.86 × 10⁷ copies/mL). ARB, aeARGs, and iARGs may correlate with nitrogen species and heavy metals (e.g., U and Mn), and feARGs presented a significant correlation with chemical oxygen demand (p < 0.05). These findings demonstrate the occurrence of ARB and ARGs in uranium mine for the first time, thereby contributing to the assessment and control of the ecological risk of antibiotic resistance in radioactive environments.

Smelting activities are considered as the primary cause of heavy metal (HM) accumulation in soils, and the human health around the smelter has been a great concern worldwide. In this study, a total of 242 agricultural soil samples were collected around a large scale Pb/Zn smelter in China, and eight HMs (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) were analyzed to assess HMs status, ecological -health risks, and identify source. Monte Carlo simulation was utilized to evaluate the probabilistic health risks, and positive matrix factorization (PMF) was employed to identify sources. The results revealed the average contents of five heavy metals (Cd 5.28 mg/kg, Pb 203.36 mg/kg, Hg 0.39 mg/kg, Zn 293.45 mg/kg, Cu 37.14 mg/kg) are higher than their background values in Hunan province. Cd had the highest mean pollution index (PI) of 41.8 and the greatest average ecological risk index (Eᵣ) of 1256.34, indicating that Cd was the primary enriched pollutant and had a higher ecological risk than other HMs. The mean hazard index (HI) through exposure to eight HMs was 2.95E-01 and 9.74E-01 for adults and children, respectively, with 35.94% of HI values for children exceeding the risk threshold of 1. Moreover, the mean total cancer risks (TCR) were 2.75E-05 and 2.37E-04 for adults and children, respectively, with 75.48% of TCR values for children exceeding the guideline value of 1E-04. In addition, the positive matrix factorization results showed smelting activities, natural sources, agricultural activities and atmospheric deposition were the three sources in soils, with the contribution rate of 48.62%, 22.35%, and 29.03%, respectively. The uncertainty analysis of the PMF indicated that the three-factor solution is reliable. This work will provide scientific reference for the comprehensive prevention of soil HM pollution adjacent to the large smelter.

In order to study the effect of cadmium ions on the mechanical properties and micro-structure characteristics of the red clay in Guilin, we have conducted triaxial test and the scanning electron microscope tests to analyze the effects of cadmium ion concentration and the number of dry and wet cycles on the mechanical properties and micro-structure changes of the red clay. The results showed the effects of cadmium ions and dry-wet cycles destroy the structure of red clay. The cohesive force of red clay decreases with the increase of cadmium ion concentration, and the internal friction angle first increases and then decreases. With the rise in the number of dry and wet cycles, the cohesive force of cadmium-contaminated red clay first increases and then decreases, and the angle of internal friction rises gradually. Under the action of different cadmium ion concentrations, the stress-strain curve is strain hardening. With the concentration of cadmium ions increases, the strain hardening becomes more apparent; the peak value reached faster. and the axial strain corresponding to the peak value of the line decreases. With the increase in the number of wet and dry cycles, the volume of cadmium-contaminated red clay shrinks and its compactness increases; it gets the peak shear strength faster during the shearing process, and its peak value becomes larger and larger. The main reason for the phenomenon is that cadmium ions destroy the cementation between the particles. The soil particles are mainly in point contact which loosens the structure of the soil; on the other hand, the thickness of the surface diffusion layer of the clay particles increases through chemical action, The exchange of cations increases the porosity of the soil and weakens its strength. The dry-wet cycle shrinks the volume of the red clay, and the soil particles are mainly in surface contact; as the number of dry-wet cycles increases, the soil particles connection is closer, the soil porosity decreases and the strength increases.

Many communities around the country are undergoing contentious battles over the installation of artificial turf. Opponents are concerned about exposure to hazardous chemicals leaching from the crumb rubber cushioning fill made of recycled tires, the plastic carpet, and other synthetic components. Numerous studies have shown that chemicals identified in artificial turf, including polycyclic aromatic hydrocarbons (PAHs), phthalates, and per- and polyfluoroalkyl substances (PFAS), are known carcinogens, neurotoxicants, mutagens, and endocrine disruptors. However, few studies have looked directly at health outcomes of exposure to these chemicals in the context of artificial turf. Ecotoxicology studies in invertebrates exposed to crumb rubber have identified risks to organisms whose habitats have been contaminated by artificial turf. Chicken eggs injected with crumb rubber leachate also showed impaired development and endocrine disruption. The only human epidemiology studies conducted related to artificial turf have been highly limited in design, focusing on cancer incidence. In addition, government agencies have begun their own risk assessment studies to aid community decisions. Additional studies in in vitro and in vivo translational models, ecotoxicological systems, and human epidemiology are strongly needed to consider exposure from both field use and runoff, components other than crumb rubber, sensitive windows of development, and additional physiological endpoints. Identification of potential health effects from exposures due to spending time at artificial turf fields and adjacent environments that may be contaminated by runoff will aid in risk assessment and community decision making on the use of artificial turf.

Polybrominated diphenyl ethers (PBDEs) are aromatic compounds that containing bromine atoms, which possess high efficiency, good thermal stability. However, PBDEs had various known toxic effects and were characterized as persistent environmental pollutants. Exposure to a quinone-type metabolite of PBDEs (PBDEQ) is linked with excess production of intracellular reactive oxygen species (ROS) in our previous studies. Here, we observed that PBDEQ exposure led to ROS and mitochondrial dysfunction, which promoted canonical and non-canonical Nod-like receptor protein 3 (NLRP3) inflammasome activation. Further experiments demonstrated that PBDEQ exposure activated Toll-like receptors (TLRs), subsequently regulating nuclear factor kappa B (NF-κB) signaling. Moreover, lysosomal damage and K⁺ efflux were involved in PBDEQ-driven NLRP3 inflammasome activation. Our in vivo study also illustrated that PBDEQ administration induced liver inflammation in male C57BL/6J mice. Cumulatively, our current finding provided novel insights into PBDEQ-induced pro-inflammatory responses.

The impact of land use type on the content of potentially toxic elements (PTEs) in the soils of the Qinghai-Tibet Plateau (QTP) and the associated ecological and human health risks has drawn great attention. Consequently, in this study, top- and subsurface soil samples were collected from areas with four different land uses (i.e., cropland, forest, grassland, and developed area) and the total contents of Cr, Cd, Cu, Pb and Zn were determined. Geostatistical analysis, self-organizing map (SOM), and positive matrix factorization (PMF), ecological risk assessment (ERA) and human health risk assessment (HRA) were applied and used to classify and identify the contamination sources and assess the potential risk. Partial least squares path modeling (PLS-PM) was applied to clarify the relationship of land use with PTE contents and risk. The PTE contents in all topsoil samples surpassed the respective background concentrations of China and corresponding subsurface concentrations. However, the ecological risk of all soil samples remained at a moderate or considerable level across the four land use types. Developed area and cropland showed a higher ecological risk than the other two land use types. Industrial discharges (32.8%), agricultural inputs (22.6%), natural sources (23.7%), and traffic emissions (20.9%) were the primary PTE sources in the tested soils, which indicate that anthropogenic activities have significantly affected soil PTE contents to a greater extent than other sources. Industrial discharge was the most prominent source of non-carcinogenic health risk, contributing 37.7% for adults and 35.2% for children of the total risk. The results of PLS-PM revealed that land use change associated with intensive human activities such as industrial activities and agricultural practices distinctly affected the PTE contents in soils of the Qinghai-Tibet Plateau.

Biomagnification of persistent toxic substances (PTSs) in food chains is of environmental concern, but studies on biotransport of PTSs across aquatic and riparian food chains are still incomplete. In this study, biomagnification of several PTSs including methylmercury (MeHg), polybrominated diphenyl ethers (PBDEs), and 1,2-bis (2,4,6-tribromophenoxy) ethane (BTBPE) was investigated in adjacent aquatic and riparian food webs. Concentrations of MeHg and PBDEs ranged from 2.37 to 353 ng/g dry weight (dw) and not detected (Nd) to 65.1 ng/g lipid weight (lw) in riparian samples, respectively, and ranged from Nd to 705 ng/g dw and Nd to 187 ng/g lw in aquatic samples, respectively. Concentrations of MeHg were significantly correlated with δ¹³C (p < 0.01) rather than δ¹⁵N (p > 0.05) values in riparian organisms, while a significant correlation was observed between concentrations of MeHg and δ¹⁵N (p < 0.01) in aquatic organisms. Biomagnification factors (BMFs) and trophic magnification factors (TMFs) of PBDE congeners were similar in riparian and aquatic food webs, while BMFs and TMFs of MeHg were much higher in aquatic food web than those in riparian food web. The results indicate the biotransport of MeHg from aquatic insects to terrestrial birds, and δ¹³C can be a promising ecological indicator for biotransport of pollutants across ecosystems.

This study investigates the relationship between territorial human influence and decreases in NO₂ air pollution during a total COVID-19 lockdown in Metropolitan France. NO₂ data from the confinement period and the Human Influence Index (HII) were implemented to address the problem. The relative change in tropospheric NO₂ was calculated using Sentinel-5P (TROPOMI) satellite data. Hotspot-Coldspot analysis was performed to examine the change in NO₂. Moreover, the novel Human-Influenced Air Pollution Decrease Index (HIAPDI) was developed. Weather bias was investigated by implementing homogeneity analysis with χ2 test. The correlations between variables were tested with the statistical T-test. Likewise, remote observations were validated with data from in-situ monitoring stations. The study showed a strong correlation between the NO₂ decrease during April 2020 under confinement measures and HII. The greater the anthropogenic influence, the greater the reduction of NO₂ in the regions (R² = 0.62). The new HIAPDI evidenced the degree of anthropogenic impact on NO₂ change. HIAPDI was found to be a reliable measure to determine the correlation between human influence and change in air pollution (R² = 0.93). It is concluded that the anthropogenic influence is a determining factor in the phenomenon of near-surface NO₂ reduction. The implementation of HIAPDI is recommended in the analysis of other polluting gases.