Our field survey showed that thequality of shallow groundwater around the KatsuraRiver in the Kyoto Basin was strongly affected by theinfiltration of river water. Furthermore, that thedeterioration of the groundwater in the southern areato the west of the Katsura River may be related to theincrease in groundwater extraction. To clarify themechanism of groundwater deterioration, we havedeveloped a stochastic method to simulate groundwaterflow. The results showed that there was a largereduction in the groundwater level where groundwaterextraction was intense and recharge flowed from theKatsura River to the high extraction areas in thesouthern region. Another simulation showed that if thegroundwater extraction was 10% of the present removalrate, there would be little recharge from the KatsuraRiver into the groundwater and the quality of thegroundwater would be improved. Thus, we conclude thatthe cause of groundwater deterioration is probably dueto the induced recharge of deteriorated river waterfrom the Katsura River.

A new technique based on traditional concepts has beendeveloped for rapid, on-site analysis of mercury inenvironmental media. In this method, mercury isanalyzed by integration of thermal decomposition,amalgamation, and atomic absorption spectrometry(TDA-AAS). Sample preparation and analysis areessentially integrated into a single instrumentalsystem; solid samples can be analyzed directly,without chemical pre-treatment, in an analysis time ofapproximately 5 minutes per sample. A wide range ofstandard reference material has been analyzed byTDA-AAS. Agreement with the certified values at the95% confidence interval for all matrices testedvalidates this technique. Subsequent to validation,TDA-AAS has been used in a series of field studies inconjunction with remediation of mercury-contaminatedsoil at natural gas utility sites. Reasonableagreement has been demonstrated between TDA-AASon-site results and laboratory results usingconventional mercury analysis techniques. Independentlaboratory confirmation of the field data is notrequired as TDA-AAS demonstrates lab-quality resultson-site. This field technique has been shown tosurpass traditional laboratory methods in terms ofboth precision and detection limits. A method for theUnited States Environmental Protection Agency (USEPA), Method 7473, has been developed and validatedbased on TDA-AAS methodology (US EPA, 1998).

Soil erosion has both on-farm and off-farm impacts. Reduction ofsoil depth can impair the land's productivity, and the transportof sediments can degrade streams, lakes, and estuaries. Since1933, soil conservation policies have existed in the UnitedStates. Originally they focused on the on-farm benefits ofkeeping soil on the land and increasing net farm income.Beginning in the 1980s, however, policy goals increasinglyincluded reductions in off-site impacts of erosion. As aconsequence of conservation efforts associated with explicitU.S. government policies, total soil erosion between 1982 and1992 was reduced by 32% and the sheet and rill erosion ratefell from an average of 4.1 tons per acre per year in 1982 to 3.1 tons per acre in 1992. Wind erosion rate fell from anaverage of 3.3 tons per acre per year to 2.4 tons per acre peryear over the same period. Still, soil erosion is imposingsubstantial social costs. These costs are estimated to be about$37.6 billion annually. To further reduce soil erosion andthereby mitigate its social costs, there are a number of policyoptions available to induce farmers to adopt conservationpractices including education and technical assistance,financial assistance, research and development, land retirement,and regulation and taxes.

Twenty-eight volatile organic compounds have been measured in a 3-month monitoring campaign. The sampling point is locatedin the urban centre of La Coruña, a medium-size town in theNorthwest of Spain. Only a petrol refinery can be consideredas an important point VOCs source in its surrounding area.The municipal landfill collapsed in September 1996, and rebuilding works caused strong odour episodes at the urbancentre. We tried to check how this problem affected urban airquality. Samples were taken with Tenax-TA tubes and analysedby thermal desorption-GC-MS. From the results obtained, traffic emissions were recognised as the main VOCs source inthe sampling zone. On November 9th a contaminationepisode took place. Aromatic and aliphatic compounds levelswere probably affected by emissions from fuel treatmentprocesses in a nearby petrol refinery. No influence onquantified VOCs concentrations from the remaking landfillworks was observed. Several compounds (organosulphurs, estersand alcohols) were recognised as the cause of odour problems.

Roads play a major role intransporting sediment associated nonpoint sourcepollutants to urban stream networks via storm drains. In urban areas the relationship of erodible soil toroads may be of critical importance in controllingmetal contributions to roads. Two 50-m transects(Park and School) were investigated perpendicular toroads in Manoa basin, Oahu, Hawaii. Concentrations ofnine elements were compared to background control soillocations and to five supplemental samples from nearbyrecreational parks. Sediment from curbside areas ofroads (road deposited sediment) was collected as thestarting point of each transect, and subsequently soilwas sampled from two depths (0–2.5 cm and 7.5–10.0 cm)along the transects. Total and 0.5 M HCl extractableconcentrations were determined for aluminum (Al),calcium (Ca), chromium (Cr), copper (Cu), iron (Fe),manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn)using either inductively coupled plasma-atomicemission spectroscopy (ICP-AES) or flame atomicemission spectroscopy (FAAS). Ca, Cu, Pb and Znexhibited anthropogenic enhancement, with Pb and Znhaving the greatest enrichment in road sedimentfollowed by locations nearest the road. Copperdisplayed a narrower band of contamination than eitherPb or Zn, and this may reflect larger aerosolassociations and more rapid fall velocities. Lead andZn exhibited substantial decay in concentration at 50 m compared to the road sediment, but enrichment wasstill apparent. The positioning of a band of soilbetween the road-curb area and the sidewalk for thePark transect facilitated deposition and storage oftrace metals, and with subsequent erosion by splash orconcentrated flow this area can account for continuedtransport of contaminated sediment to adjacent roadsurfaces. On the other hand the School transect hadno soil directly beside the road, and the nearestsample from the road (5 m) displayed enrichment butsubstantially lower than the Park transect. Thesepreliminary data suggest that remobilization of soilstored metals in close proximity to roads cansignificantly prolong the environmental contaminationof urban road systems and eventually stream sediments.

Subsurface tile drainage systems with drainspacings of 15 m in 0.4 ha and 25 m in 3.2 ha wereinstalled at the farmers' field in 1986 and 1987,respectively, to study their effect on the reclamationof the coastal saline sodic clay soils. The system'sperformance in terms of the changing physical andchemical properties of the soil and rice yield wascontinuously monitored for a decade. Field datasuggested the possibility of adopting wider drainspacings and thus, drainage system with 35 and 55 mspacings was laid in 1997 in a 4 ha area. On theseinstallations the losses of NH₄ ⁺-N throughsub-surface drainage effluent were estimated. Thearea under 25 m drain spacing was the control with nocrops, fertilization and irrigation. Analysis ofwater samples collected daily for 10 days startingfrom 40 DAT from the drain laterals revealed thatthere were no trace of NH₄ ⁺-N in theeffluent from 15 and 25 m drain spacings. However,the effluent from 35 and 55 m spacings contained anaverage of 6.704 mg L⁻¹ and 4.205 mg L⁻¹ of NH₄ ⁺-N, respectively, before irrigation and2.438 and 1.650 mg L⁻¹ after irrigation. Themagnitudes of the losses of NH₄ ⁺-N duringthe crop season were 6.43 kg ha⁻¹ in 35 m spacingwith a drainage rate of 5.6 mm d⁻¹ and 2.14 kgha⁻¹ in 55 m spacing with a drainage rate of 3.5 mm d⁻¹. The rice yield was 6.5 Mg ha⁻¹ in15 m drain spacing where no ammonium losses throughsubsurface drainage effluent occurred. The rice yieldsunder 35 and 55 m drain spacings were 1.9 and 1.8 Mgha⁻¹, respectively. The poor yield was due tosignificant loss of ammonium form of nitrogen throughthe drainage effluent and lesser availability of totalnitrogen to the plants. The plant uptake of nitrogen in the unreclaimed area with 55 m spacing was half ofthat in the reclaimed area with 15 m spacing.

The effect of soil treatment with brominal (a herbicide) and theinsecticide selecron (the equivalent field rates and five-fold) on population counts of bacteria, actinomycetes and celluloyticfungi in soil was tested throughout 10 weeks incubation at28 °C. Also, tested their effect on four soil enzymes:cellulase, acid phosphatase, alkaline phosphatase andarylsulphatase. Bacterial and actinomycetes populations in soiltreated with the two pesticides were promoted at fieldapplication rates and inhibited at higher levels. The twopesticides significantly decreased the total number ofcellulolytic fungi and most fungal species after most incubationperiods either by one or the two used levels but the effect ofselecron was more pronounced.Cellulase activity in soil treated with brominal and selecronwas inhibited after most incubation periods. The effect of soiltreatment with the two pesticides on acid phosphatase waspromotive at field application rates after some incubationperiods but the enzyme activity was delayed at the higherapplication doses. Alkaline phosphatase activity in treated soilwas accelerated with both pesticides even at the higherapplication rates, suggesting a direct role of alkaline soil pHin increasing resistance of alkaline phosphatase to pesticides.The effect of soil treatment with pesticides on arylsulphataseactivity fluctuated between promotion and inhibition, butinhibition was predominant.

The cement industry has been one of the major sources of air pollution in the past and the Turkish Air Quality Protection Regulation has issued limits also to trace elementemissions to minimise the polluting effects of this industrialsector. In the present study, dust samples were obtained isokinetically from 18 main stacks of 10 cement plants locatedin different geographical areas of Turkey. The samples were analysed for trace elements Hg, Cd, Cr, Pb, Ni, Se, Te, TI, V, Sb, Ba, Zn, Co, Sr, Cu, Bi, Mo, Be, and As. The results are presented both as concentration in the dust samples as well as emissions per unit production, and concentration inthe stack gas. The trace element emissions of the main stacksagree to great extent with the values given in the literature. On the other hand, the trace element emissions of the plants considered are well below the limits set in the Turkish Air Quality Protection Regulation.

The effects of urea, (NH₄)₂SO₄, KNO₃, and NH₄NO₃ on nitrous oxide (N₂O) emission from soil at field capacity and submerged condition were studied during 120 days in the laboratory. Soils in both moisture regimes gave higher emissions in the beginning, which were reduced later. Total emission of N₂O was higher at submergence as compared to field capacity regardless of fertilizer type. At field capacity soil fertilized with ureaemitted the highest amount of N₂O (1903 μg N₂O-N kg⁻¹ soil) during 120 days while at submerged condition, soil with NH₄NO₃ gave the highest emission (4843 μg N₂O-N kg⁻¹ soil). In another study, the efficacy of seven nitrification inhibitors in reducing the emission of N₂O-N from soil fertilized with urea was tested in the laboratory. Nitrapyrin, 2-amino-4-chloro-6-methylpyrimidine (AM), and dicyandiamide (DCD) reduced the emission to 12, 24, and 63% that of urea, respectively, whereas sodium thiosulphate, sulphur, acetylene,and thiourea had no effect on emission of N₂O. In submerged conditions none of the inhibitors reduced the emission.

Former and present landfill techniques at the Filbornaplant in Helsingborg, South Sweden are compared withrespect to impacts on the environment. This includes thepotential for nutrient recovery and heavy metalimmobilisation in the waste residue. The results showthat optimised landfill bioreactor-cells have a higherturn-over rate for organic matter compared to the formerlandfills, whereas the retention capacity for heavymetals in both systems was surprisingly high. Full scaleleachate data, as well as a laboratory leachingexperiments confirmed the role of bioreactor cells asanaerobic filters enabling a separation of nutrients froma mixed waste, while the toxic metals are retained. Theconclusion of this article is that by simple measures, thebiological processes can be optimised, resulting inhigher turn-over rates for organic matter and thusaccelerated waste stabilisation.