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Determination of Heavy Metal Remediation to Soil from Community Buildings’ Rooftop
2022
Yasin İlhanlı | Erman Ulker
Considering the importance of water in the world, the amount of usable water is not sufficient throughout the world, the existing available fresh water resources are not enough, therefore, water shortages may be encountered in the following years. Keeping the quality of water as it is demanded gains more importance than before. Particularly, heavy metals begin to interfere with groundwater resources, and the quantity of pollution growing due to industrialization, and urbanization. In the present study, the quantitative analysis of heavy metals in harvested rainwater from the rooftop of public buildings in Bornova, Izmir is investigated. The results show that a minimum of 5 μg of copper, 4 μg of zinc, 2.69 μg of lead, 0.095 μg of cadmium, 0.55 μg of chromium, 89,7 μg of iron, 0.96 μg of arsenic, 0.0119 μg of mercury and 3.88 μg of nickel should be tossed away for obtaining a liter of potable water. In conclusion, first flush diverters are recommended to convert these non-point pollutants to point source. Thus, municipalities can take necessary measures to protect the environment such as using phytoremediation and hyperaccumulator plants in sewages.
Show more [+] Less [-]Bioremediation of Heavy Metals by Use of Bacteria
2022
Orcan Demircan | Abdul Razaque Memon
Heavy metal pollution generally occurs due to socio-economic, industrial, and anthropogenic activities, which may cause an environmentally hazardous and serious severe threat to the survival of the organisms (genotoxic, carcinogenic, and clastogenic effects on it). Many physical and chemical remediation approaches have been proposed to deal with this pollution, but these are very time-consuming and costly. While bioremediation stands out as an inexpensive and efficient approach, the use of bacteria is thought to be a potential and productive organism to prevent this pollution. This review has evaluated the bacterial potential to clean up heavy metals from the environment and elucidated the mechanisms responsible for bioremediation.
Show more [+] Less [-]Heavy Metal Concentrations in Razor Clam (Solen marginatus, Pulteney, 1799) and Sediments from Izmir Bay, Aegean Sea, Turkey
2019
Elif Çağrı Taş | Uğur Sunlu
This study was carried out to determine the concentrations of some heavy metals (Cd, Cu, Pb, Zn, Cr and Fe) in Solen marginatus (Pulteney, 1799) and sediments in the middle region of Izmir Bay. Metal concentrations in S. marginatus vary in the one-year period between summer 2005 and summer 2006. The order of accumulation of metal concentrates in soft tissue of razor clam was determined as Cd < Pb < Cr< Cu < Zn < Fe. Metal accumulations in the soft tissue of S. marginatus were compared with Provisional Tolerable Weakly Intakes (PTWI) and Provisional Tolerable Daily Intakes (PTDI) for human consumption. The results show that the maximum concentrations of metals were markedly below the limits of the FAO (Food and Agriculture Organization), WHO (World Health Organization) and TFC (Turkish Food Codex) for human consumption. The order of the metal concentrations detected in the sediment samples was Cd < Pb < Cu< Cr < Zn < Fe. In this study, the maximum heavy metal values determined in the sediment are below the criteria values of the stated for international sediment quality guidelines in the NOAA (The National Oceanic and Atmospheric Administration), OMEE (The Ministry of Environment and Energy of Ontario), ANZECC (The Australia and New Zealand Environmental on Conservation Council), CCME (The Canadian Council of Ministers of Environment). There was a statistically significant but weak correlation between concentrations of Cu and Cr in sediment and S. marginatus. The significant correlations have shown that Solen species can be used as a bioindicator species, such as mussels due to their ability to accumulate heavy metals.
Show more [+] Less [-]Impact of Brewery Waste Sludge on Sorghum (Sorghum bicolor L. Moench) Productivity and Soil Fertility in Harari Regional State, Eastern Ethiopia
2017
Nano Alemu Daba | Abduletif Ahmed | Muktar Mohammed
The study was conducted on farmers' field in sofi district of Harari Regional State during 2013/2014 main cropping season, eastern Ethiopia, to investigate the impact of brewery sludge on sorghum production and soil fertility. The treatments comprised seven levels of brewery sludges (0, 2.5, 5.0, 7.5, 10.0, 12.5 and 15.0 t ha-1) and NP inorganic fertilizer at recommended rate, arranged in randomized complete block design with four replications. Application of brewery sludge at 15 t ha-1 significantly increased the yield and biomass yield of sorghum by 79 and 85% over control and by 57 and 67% over NP application, respectively. There was no effect of brewery sludge application on heavy metals concentrations in soil after crop harvest, compared to international standard tolerable level. Co and Se levels were high in the control as well as in the soils treated with brewery sludge indicating the already high concentration of these heavy metals in the soils of the area. Plots, which received higher brewery sludge application, resulted in decreased or less percentage of grain nitrogen content showing the independence of grain protein content on lower brewery sludge level. The nitrogen uptake by sorghum grain, straw and the total was maximum (52.68, 44.25 and 79.03 kg ha-1, respectively) with the application of brewery waste sludge at 10 and 15 t ha-1 which were significantly higher than the other brewery sludge and NP mineral fertilizer applications.
Show more [+] Less [-]Polycyclic Aromatic Hydrocarbon and Metal Concentrations in Imported Canned Maize
2014
Embbey K Ossai | Chukwujindu Maxwell Iwegbue | Elizabeth E. Ajogungbe | Godswill O Tesi
Concentrations and profile of polycyclic aromatic hydrocarbons(PAHs) and metals (Cd, Pb, Ni, Cr, Fe and Mn) were determined in selected brands of canned maize in the Nigeria market with a view to providing information on the hazards associated with the consumption of these products. The measurement of the concentrations of PAHs was carried out by using a gas chromatography equipped with flame ionization detector (GC-FID) after extraction by ultra-sonication with acetone/dichloromethane and clean-up. The 16 PAH concentrations varied between 45.1 and 335.7 µg/kg. The concentrations of the indicators for occurrence and effects of PAHs in food varied from 3.6 to 114.5 µg/kg for BaP, 6.4 to 168.2 µg/kg for PAH2, 11.8 to 232.7 µg/kg for PAH4 and 19.4 to 327.3 µg/kg for PAH8. The concentrations of metals were determined by using atomic absorption spectrometry after acid digestion. The concentrations of metals in these samples ranged from
Show more [+] Less [-]The Effect of Leonardite on Chromium Toxicity and Growth of Cordes Rose
2022
Ayşen Akay | Mohammed Yashar Omar
High concentrations of chromium in the soil have a toxic effect on the living organisms in the soil ecosystem. If chromium, which is not an absolute essential element, accumulates in plants, it causes structural changes, causing a decrease in plant growth and also high toxicity due to its accumulation in biomass. Use of plants to remove chromium (Cr) from contaminated soils, it is an environmentally efficient, cost-effective, modern, applicable technique. The different species of plant and ornamental plants are used in this technique. In this study, the Kordes shrub rose used in landscaping in our province, Cr phytoremediation capacity was evaluated by growing at contaminated soil with Cr. In the study, the different doses of Cr (0, 50, 100, 500, 1000 mg kg-1) have been applied in Cr+3 and Cr+6 forms. In addition, two doses (0% and 3%) of leonardite were added to the pots to determine the effect on the developmental status of the plants and Cr uptake. In the study, plant height, number of branches, number of flowers, flower diameter, stem diameter, flower yield values and total wet and dry weight values at the end of the experiment were determined. At the end of the experiment, it was observed that generally developmental status of the plants was adversely affected at high Cr doses. Especially at 500 and 1000 mg kg-1 application doses was observed that the plants could not withstand Cr toxicity in a short time. It has been observed that plants treated with leonardite were healthier than those without. According to the data obtained at the end of the study, it was determined that the resistance of plant to high doses of Cr was low, but it showed better growth at 50 and 100 mg kg-1 doses.
Show more [+] Less [-]Monitoring of Heavy Metal Pollution in Water and Sediments at the Mid-Black Sea Region by Using Passive Sampling Method Diffusive Gradients in Thin Films
2021
Arife Şimşek | Şule Sancak | Gülfem Bakan
Determining the potential bioavailability of heavy metals, evaluating according to adapted regulations is essential to efficiently conserve our coastal and estuarine waters. In this study, it is aimed to determine the industrial pollution and various other pollution sources that the Black Sea Basin is exposed to by using DGT (Diffusive Gradients in Thin Films) method and grab (manuel) sampling method in water and sediment and to evaluate the existing pollution according to quality standards. In Samsun, seasonal samples were collected from five different sampling stations, namely Akkiraz Stream, Hıdırellez Stream, Organized Industrial Zone (OIZ) Channel, Şabanoğlu Stream and Selyeri Stream, which are selected from Tekkeköy region where industry is intensively active. In order to determine the heavy metal content in both water and sediment samples, the DGT method was chosen for passive sampling and the grab sampling method was used for active sampling, and the efficiency of the methods was evaluated. According to the results of the study, the heavy metal concentration in grab sampling for water samples in descending order Al> Fe> Zn> Pb> Ni> Cu; In the samples taken with DGT, they are listed as Al> Fe> Zn> Cu> Ni> Pb. There were significant relationships between the total metal concentrations of sediment (Csed) and water (Csu) in grab sampling and metal concentrations sediment (Csed-DGT) and water (Csu-DGT) measured by DGT. It was found that the sensitivity and performance of sampling with DGT was 2-10 times higher compared to grab sampling. The high resolution in situ DGT technique for the assessment and management of the potential release risk of heavy metals at the water-sediment interface is a complementary method that contributes to the standard grab sampling method.
Show more [+] Less [-]Assessment of Metal Levels in Biotic and Abiotic Materials from Giresun Forests
2020
Mustafa Türkmen | Aysun Türkmen | Ayhan Kara
The study investigated the metal levels in biotic and abiotic materials from Giresun forests. While soil and water samples were selected as abiotic materials, leaves and moss were selected as biotic materials in forest. These selected materials were sampled from six stations. All samples were analyzed three times for arsenic, iron, chromium, copper, manganese, nickel, lead and zinc by ICP-OES. A logarithmic transformation was done on the data to improve normality. One way ANOVA and Duncan’s multiple range tests were performed to test the differences among metal levels of stations. The differences among metal levels in stations were statistically significant (p
Show more [+] Less [-]Determination of Molybdenum Contents and Relation of Some Heavy Metals in the Soil of Meadow-Pasture Terraces Between Kırıkhan-Reyhanlı
2019
Mehmet Yalçın | Kerim Mesut Çimrin
This study was aimed to determine the molybdenum content of meadow - pasture soil between Kırıkhan and Reyhanlı in Hatay province and to determine the relations of the molybdenum content with some heavy metals in the soil. For this purpose, two different depths (0-20 and 20-40 cm) representing grassland pasture lands and 80 soil samples from 40 different points were taken. Cadmium (Cd), Cobalt (Co), Nickel (Ni), Lead (Pb), Copper (Cu), Iron (Fe), and Molybdenum (Mo) contents were determined in the soil samples. The contents of the available Cd, Co, Pb, Cu, Fe, Ni and Mo of the soil were determined by reading the 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA extracts in the ICP instrument. The results of the research shows that the Cd contents of the soils are between 0.01-0.32 ppm; Co contents are from 0.01 to 4.97 ppm; Ni contents 0.00 to 20.00 ppm; Pb contents 3.00-67.00 ppm; Cu contents 0.26-7.48 ppm; The Fe contents are between 4.00 and 61.00 and the Mo contents are between 0.001 and 0.064 ppm. It was determined that there are significant positive relationships between Co, Ni, Pb, Cu and Fe contents of Mo in the soil. It was also determined that there are significant positive significant relationships between Cd and Co; Co with Ni, Pb, Fe and Pb and Cu, Fe and Cu and Fe. No heavy metal pollution was found when the heavy metal contents of the regional soils were compared with the limit values.
Show more [+] Less [-]Examining Heavy Metal Transfer from Soil to Bread
2024
Mustafa Yılmaz
For Turkish society, bread has been an indispensable part of the kitchen and daily life throughout history. Due to its high consumption in Turkish society, it plays an important role in terms of both health and nutritional habits. Contamination from the soil where wheat is planted to the bread making process is of great importance for health. In this study, the amounts of heavy metals such as aluminum, copper, nickel, chromium, manganese, iron, lead and cadmium in the soil of an agricultural land, in flour obtained from wheat grown there and in bread made from this flour were investigated using ICP-MS. The average levels of Al, Cr, Cu, Mn, Ni, Cd, Fe, Pb and As in soil samples were 120.46, 12.23, 44.9, 93.46, 10.83, 2.06, 196.87, 1.96 and 0.21 mg/kg, respectively. In flour samples, these levels were 17.20, 2.03, 28.93, 26.3, 3.37, 0.09, 30.93, 1.37 and 0.03 mg/kg, respectively. In bread samples, 11.27, 0.77, 8.27, 18.63, 0.4, 0.02, 12.76, 0.04 and 0.001 mg/kg, respectively. The results obtained show that high metal levels in the soil are also found in bread. This indicates that heavy metal levels in bread may pose health risks in long-term consumption. Especially levels of aluminum, nickel, chromium and cadmium metals can cause serious health problems. Therefore, it is important to reduce heavy metal contamination in agriculture and production processes and to conduct regular inspections. Compliance with maximum limits set by health authorities and regulatory agencies is also critical for public health.
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