Use of non-degradable plastics in food packaging is alarming for the environment as they are often thrown away after short consumption. Though papers are replacing plastics in different sectors, their low water resistance limits their use in food packaging. in the past, water-resistant papers have been fabricated, but the natural degradability of the paper has been compensated. This study proposes water-resistant yet biodegradable papers from naturally abundant wastes, such as banana plant (BP) and water hyacinth (WH) and validates their properties for practical packaging uses. The resources were completely used, avoiding generation of any in-process biomass residue. This study for the first time reports the impact of ethyl cellulose (EC) coating (∼10 μm) on paper surfaces. The morphology and chemical analysis of the coated papers confirmed the consistent formation of EC layer on paper surfaces. The presence of EC significantly reduced the vapour transmission (22–30%) and moisture content (6–11%) of the papers. Water drops were stable on the coated surfaces at least for 20 min and then were wiped off leaving a dry surface. EC coating considerably increased the tensile index, i.e., 13–17% for BP and 20–35% for WH, though elongation and modulus properties remained almost unchanged. All the papers showed ultraviolet (UV)-resistance, while the coated papers were more transparent in the visible light region. Overall results confirmed the potential of the proposed EC-coated papers as a promising alternative to single-use plastics in food packaging.

Natural biopolymers have become key players in the preparation of biodegradable food packaging. However, biopolymers are typically highly hydrophilic, which imposes limitations in terms of barrier properties that are associated with water interactions. Here, we enhance the barrier properties of biobased packaging using multilayer designs, in which each layer displays a complementary barrier function. Oxygen, water vapor, and UV barriers were achieved using a stepwise assembly of cellulose nanofibers, biobased wax, and lignin particles supported by chitin nanofibers. We first engineered several designs containing CNFs and carnauba wax. Among them, we obtained low water vapor permeabilities in an assembly containing three layers, i.e., CNF/wax/CNF, in which wax was present as a continuous layer. We then incorporated a layer of lignin nanoparticles nucleated on chitin nanofibrils (LPChNF) to introduce a complete barrier against UV light, while maintaining film translucency. Our multilayer design which comprised CNF/wax/LPChNF enabled high oxygen (OTR of 3 ± 1 cm³/m²·day) and water vapor (WVTR of 6 ± 1 g/m²·day) barriers at 50% relative humidity. It was also effective against oil penetration. Oxygen permeability was controlled by the presence of tight networks of cellulose and chitin nanofibers, while water vapor diffusion through the assembly was regulated by the continuous wax layer. Lastly, we showcased our fully renewable packaging material for preservation of the texture of a commercial cracker (dry food). Our material showed functionality similar to that of the original packaging, which was composed of synthetic polymers.

Although polyvinyl alcohol (PVA) is a promising biodegradable packaging material, it presents some disadvantages for food packaging such as poor ultraviolet (UV) and water vapor barrier properties, low mechanical strength, poor water resistance, and lack of antimicrobial properties. To overcome these limitations, novel PVA/cellulose nanocrystals (CNC)/titanium dioxide (TiO₂) nanocomposites were developed, characterized, and demonstrated for potential food packaging applications. The mechanical strength, water vapor barrier, and UV barrier properties of PVA/CNC/TiO₂ 5 % film (5 wt% TiO₂ in the PVA/CNC matrix with 5 wt% of CNCs) increased by 55.8 %, 45.2 %, and 70,056.8 %, respectively, compared to those of a PVA film. In the antibacterial simulation test, PVA/CNC/TiO₂ 5 % film could limit the growth of microorganisms for 14 days. In packaging tests with fresh garlic, PVA/CNC/TiO₂ films effectively prevented weight loss and spoilage by external influences, indicating the potential of the PVA/CNC/TiO₂ nanocomposites for food-packaging applications.

Recycling of food-by-products is very important subject. Many trials have been done to reuse by-product, however, almost trials have not been to install the commercial process due to their treatment costs and their qualities. To convert biodegradable stuff is one of their trail fields. However, their products have disadvantage of high cost and low properties against water-resistance. To minimize costs and to improve waterproof property, we used zein-containing corn gluten meal and succeeded in making solid materials by injection molding. We turned the materials into pellets with an extruder, and then molded the pellets into seedling culture pots with an injection molder. This study project was carried out jointly with Showa Sangyo Co., The Japan Steel Works and National Food Research Institute. In this project we were able to successfully reduce costs and to obtain solid molded products for practical use by adopting the injection molding method, which has many advantages in productivity (low costs, high moldability, flexibility to make various shapes of molds). At present, we are working to assess the biodegradable molded material actually applied and to improve materials for different purposes.

A novel composite foam was prepared from native cassava starch and water hyacinth (WH) by baking in a hot mold. The effects of WH powder content (0, 3, 5, 7 or 10 wt%, dry starch basis) on the properties of the starch foam were investigated. A starch foam formulation with 5 wt% WH powder exhibited the highest flexural stress at maximum load (3.42 MPa), the highest flexural strain (extension) at maximum load (3.52%), the highest modulus (232.00 MPa), the lowest moisture content (6.77%) and the most uniform cell size distribution (0.44 ± 0.09 mm). Moreover, mechanical properties of starch foam with 5 wt% WH powder were better than the same properties of some commercial foams. After being coated with beeswax, the starch foams retained their shape after immersion in distilled water and their water solubility was significantly reduced. Results indicated that a starch foam/5 wt% WH composite with beeswax coating was a biodegradable foam that could possibly replace commercial non-degradable foam.

Nowadays consumers are aware of environmental problems. As an alternative to petrochemical polymers for food packaging, researchers have been focused on biopolymeric materials as raw material. The aim of this study was to evaluate mechanical properties (toughness, burst strength and distance to burst), water adsorption, light-barrier properties and transparency of composite films based on cellulose, glycerol and polyvinyl alcohol. Scanning electron microscopy, spectral analysis (FT-IR and UV–VIS-NIR) and differential scanning calorimetry were performed to explain the morphology, structural and thermal properties of the films. Results showed that polyvinyl alcohol enhances the toughness of films up to 44.30 MJ/m3. However, toughness decreases when glycerol concentration is increased (from 23.41 to 10.55 MJ/m3). Water adsorption increased with increasing polyvinyl alcohol concentration up to 222%. Polyvinyl alcohol increased the film thickness. The films showed higher burst strength (up to 12014 g) than other biodegradable films. The films obtained have optimal values of transparency like those values of synthetic polymers. Glycerol produced a UV protective effect in the films, an important effect for food packaging to prevent lipid oxidative deterioration. Results showed that it is feasible to obtain cellulose-glycerol-polyvinyl alcohol composite films with improved properties.

Microaeration has been used conventionally for the desulphurization of biogas, and recently it was shown to be an alternative pretreatment to enhance hydrolysis of the anaerobic digestion (AD) process. Previous studies on microaeration pretreatment were limited to the study of substrates with complex organic matter, while little has been reported on its effect on substrates with higher biodegradability such as brown water and food waste. Due to the lack of consistent microaeration intensities, previous studies were not comparable and thus inconclusive in proving the effectiveness of microaeration to the overall AD process. In this study, the role of microaeration pretreatment in the anaerobic co-digestion of brown water and food waste was evaluated in batch-tests. After a 4-day pretreatment with 37.5mL-O2/LR-d added to the liquid phase of the reactor, the methane production of substrates were monitored in anaerobic conditions over the next 40days. The added oxygen was consumed fully by facultative microorganisms and a reducing environment for organic matter degradation was maintained. Other than higher COD solubilization, microaeration pretreatment led to greater VFA accumulation and the conversion of other short chain fatty acids to acetate. This could be due to enhanced activities of hydrolytic and acidogenic bacteria and the degradation of slowly biodegradable compounds under microaerobic conditions. This study also found that the nature of inoculum influenced the effects of microaeration as a 21% and 10% increase in methane yield was observed when pretreatment was applied to inoculated substrates, and substrates without inoculum, respectively.

A new biodegradable polyhydroxybutyrate diethanol amine (PHB-DEA) polymer was used as adsorbent for the sensitive and selective separation, preconcentration and determination of Pb(II), Cd(II) and Zn(II) by using atomic absorption spectrometry. Diethyl dithiocarbamate was used as chelating reagent. Analytical parameters such as pH, eluent type and its volume, flow rates of sample solution, ligand amount, sample volume were optimized. Effects of some cations, anions and transition metal ions were also investigated. Enrichment factor and relative standard deviation were found to be 100 and 3%, respectively. The limits of detection based on three times standard deviation of blanks (N=21) were found 1.05μgL−1 for Pb(II), 0.42μgL−1 for Cd(II) and 0.13μgL−1 for Zn(II). Limits of quantification (10s, N=21) were found 3.47μgL−1 for Pb(II), 1.39μgL−1 for Cd(II) and 0.43μgL−1 for Zn(II). Accuracy evaluation of the method was confirmed with analyses of certified reference materials (NIST SRM 1515 Apple leaves, IAEA 336 Lichen, GBW 07605 Tea). Optimized method was applied to tap water and food samples after microwave digestion method. Cadmium and lead values in some samples were found higher than legal limits.

Green chemistry or in other words “green world” is referred to a sustainable environment using biocompatible, biodegradable, renewable, economical, and simple materials, and methods. Without any exaggeration, the exceptional chemical and physical properties of ZnO bionanocomposites beside various utilizations, make it vital materials in research and green chemistry field. Biocompatible ZnO nanoparticles with fascinating antimicrobial, physicochemical, as well as photocatalytic performance could be applied as a prominent candidate to reinforce diverse biopolymer matrixes, for instance, chitosan, starch, cellulose, gelatin, alginate, poly(hydroxyalkanoates), carrageenan, and so on. With a combination of advantageous properties of these materials, they could be illustrated specific utilizations in different areas. In this regard, the following context focuses on highlighting the recent achievements of this category of material on three important and widely used scopes: eco-friendly food packaging, biomedical specially wound dressings, and water remediation technologies.