In this work, an experimental study was done in an autoclave reactor to evaluate the gasification characteristics of food waste in supercritical water. The effects of reaction temperature (550–700 °C), residence time (0–30 min), feedstock concentration (5 wt%-9 wt.%), catalyst type (K₂CO₃, Na₂CO₃, and Raney-Ni), and catalyst loading (Catalyst/dry feedstock 0.5–2) on gas production and liquid products were investigated. The results indicated that higher reaction temperature and longer residence time positively promoted food waste gasification. The organic compound species in liquid products decreased quickly to form gas products with the increased temperature, and the aromatic compounds were the key organic matter for the complete gasification of food waste. The addition of catalysts could significantly convert more liquid intermediates into gaseous products, and improve the gasification performance of food waste. The catalytic performance of catalysts can be ranked as K₂CO₃> Raney-Ni > Na₂CO₃. H₂ yield and carbon gasification efficiency increased with the increase of K₂CO₃ loading, reaching the highest values of 38.29 mol kg⁻¹ and 95.84% with the addition of 14 wt% K₂CO₃, respectively. This work indicated that food waste could be well treated and utilized as an energy resource to produce H₂ by SCWG technology.

Sustainable use and management of nutrients is an important issue for food, energy and water systems. The close connections between the three systems, reflected by the “nexus” concept, warrant an integrated approach to nutrients management across the nexus. In this paper, dynamic modelling of nutrient flows in a local food-energy-water system is presented and applied to a simplified case study. The model was used to simulate several scenarios affecting nitrogen flows and stocks to assess the impact of a) the level of local wheat production, b) the selection of energy generation technology, and c) the management of available nutrient resources (digestate and straws). The simulation results showed that varying the proportion of locally produced wheat significantly affects the surface runoff and the nitrogen content in a local water body, with the latter increasing by nearly 70% in 50 years if about half of the wheat consumed is produced locally as opposed to being 100% imported. The introduction of anaerobic digestion as an energy generation option helps to supply more electricity, reduce the imported fertiliser, and also significantly reduce the landfilled nitrogen nutrient by up to 60 times, due to the reuse of the anaerobic digestate. On the other hand, a balanced consideration should be given between using the straw as fertiliser and as feedstock for energy generation. This work offers a first analysis of the food-energy-water nexus with a focus on nutrient flows and stocks. The modelling approach has the potential to inform holistic decision making with respect to nutrient usage, efficiency and the related environmental impact in the design of a local system for meeting the demand for food, energy and water.

Separation of water-soluble lignins from lignocellulosic biomass provides a new and still poorly exploited feedstock to increase the sustainability of biorefineries. We applied derivatization followed by a reductive cleavage (DFRC) method, 2D-HSQC-NMR, and ³¹PNMR after ³¹P-labeling, to investigate molecular composition in water-soluble lignins obtained by alkaline oxidation from three biomass materials for energy (miscanthus, giant reed and an industrially pre-treated giant reed). Chromatographic identification of lignin products cleaved by DFRC showed a large predominance of guaiacyl (G) units in all biomasses and a lesser abundance of syringyl (S) and p-coumaryl (P) monomers. Our S/G ratios disagree with those reported in literature by other lignin separation methods. Carboxyl functions (ferulic and pcoumaric acids) were revealed by heterocorrelated ¹H–¹³C HSQC-NMR, and confirmed by ³¹P-NMR spectra of ³¹ P-labeled lignin molecules. An understanding of molecular composition of water-soluble lignins from biomass sources for energy is essential for lignin most efficient exploitation in either industrial or agricultural applications.

In China, waste sorting practice is not strictly followed, plastics, especially food packaging, are commonly mixed in food waste. Supercritical water gasification (SCWG) of unsorted food waste was conducted in this study, using model unsorted food waste by mixture of pure food waste and plastic. Different operating parameters including reaction temperature, residence time, and feedstock concentration were investigated. Moreover, the effect of three representative food additives namely NaCl, NaHCO₃ and Na₂CO₃ were tested in this work. Finally, comparative analysis about SCWG of unsorted food waste, pure food waste, and plastic was studied. It was found that higher reaction temperature, longer residence time and lower feedstock concentration were advantageous for SCWG of unsorted food waste. Within the range of operating parameters in this study, when the feedstock concentration was 5 wt%, the highest H₂ yield (7.69 mol/kg), H₂ selectivity (82.11%), total gas yield (17.05 mol/kg), and efficiencies of SCWG (cold gas efficiency, gasification efficiency, carbon gasification efficiency, and hydrogen gasification efficiency) were obtained at 480 °C for 75 min. Also, the addition of food additives with Na⁺ promoted the SCWG of unsorted food waste. The Na₂CO₃ showed the best catalytic performance on enhancement of H₂ and syngas production. This research demonstrated the positive effect of waste sorting on the SCWG of food waste, and provided novel results and information that help to overcome the problems in the process of food waste treatment and accelerate the industrial application of SCWG technology in the future.

A data-driven model is used to analyse the global effects of biodiesel on the energy–water–food (EWF) nexus, and to understand the complex environmental correlation. Several criteria to measure the sustainability of biodiesel and four main limiting factors for biodiesel production are discussed in this paper. The limiting factors includes water stress, food stress, feedstock quantity and crude oil price. The 155-country model covers crude oil prices ranging from USD10/bbl to USD160/bbl, biodiesel refinery costs ranging from -USD0.30/L to USD0.30/L and 45 multi-generation biodiesel feedstocks. The model is capable of ascertaining changes arising from biodiesel adoption in terms of light-duty diesel engine emissions (NO, CO, UHC and smoke opacity), water stress index (WSI), dietary energy supply (DES), Herfindahl–Hirschman index (HHI) and short-term energy security. With the addition of potential biodiesel production, the renewable energy sector of global primary energy profile can increase by 0.43%, with maximum increment up to 10.97% for Malaysia. At current crude oil price of USD75/bbl and refinery cost of USD0.1/L, only Benin, Ireland and Togo can produce biodiesel profitably. The model also shows that water requirement varies non-linearly with multi-feedstock biodiesel production as blending ratio increases. Out of the 155 countries, biodiesel production is limited by feedstock quantity for 82 countries, 47 are limited by crude oil price, 20 by water stress and 6 by food stress. The results provide insights for governments to set up environmental policy guidelines, in implementing biodiesel technology as a cleaner alternative to diesel.

Multifunctional crops can simultaneously contribute to multiple societal objectives. As a result, they represent an attractive means for improving rural livelihoods. Moringa oleifera is an example of a multifunctional crop that produces nutritious leaves with uses as food, fodder, and a biostimulant to enhance crop growth. It yields seeds containing a water purifying coagulant and oil with cosmetic uses and possible biofuel feedstock. Despite Moringa oleifera's (and other multifunctional crops') various Food-Energy-Water uses, optimizing the benefits of its multiple uses and livelihood improvements remains challenging. There is a need for holistic approaches capable of assessing the multifunctionality of agriculture and livelihood impacts. Therefore, this paper critically evaluates Moringa oleifera's Food-Energy-Water-Livelihood nexus applications to gain insight into the tradeoffs and synergies among its various applications using a systems thinking approach. A systems approach is proposed as a holistic thinking framework that can help navigate the complexity of a crop's multifunctionality. The “Success to the Successful” systems archetype was adopted to capture the competition between the need for leaf yields and seed yields. In areas where there is energy and water insecurity, Moringa oleifera seed production is recommended for its potential to coproduce oil, the water purifying coagulant, and a residue that can be applied as a fertilizer. In areas where food insecurity is an issue, focusing on leaf production would be beneficial due to its significance in augmenting food for human consumption, animal feed, and its use as a biostimulant to increase crop yields. A causal loop diagram was found to effectively map the interconnections among the various uses of Moringa oleifera and associated livelihood improvements. This framework provides stakeholders with a conceptual decision-making tool that can help maximize positive livelihood outcomes. This approach can also be applied for improved management of other multifunctional crops.

In view of a water-energy-food (WEF) nexus strategy, the present work assessed the bioenergy production potential of Halimione portulacoides used for the phytoremediation of nutrient-rich simulated wastewater from saltwater-based integrated multi-trophic aquaculture (IMTA). Specimens of this halophyte plant were grown in hydroponics under four different nutrient treatments with distinct nitrogen (N) and phosphorous (P) concentrations. Ultimate and proximate analysis, calorific value and thermogravimetric analysis coupled to mass spectrometry were used to assess the bioenergy potential of the non-edible biomass of the plants, namely the canes (C) and roots (R), and of commercial pellets (CP), which were used as benchmark. R and, especially, CP had higher carbon but lower oxygen content and larger volatiles but lower ashes than C. The higher heating values (HHV) of C (16–17 MJ kg⁻¹) and R (17–18 MJ kg⁻¹) were the same order as those of conventional energy crops and CP (20 MJ kg⁻¹). Although mass loss and associated gaseous emissions during temperature programmed pyrolysis occurred mainly between 250 and 650 °C for all biomasses, they took place at slightly higher temperatures for C > CP > R. In any case, the integrated gaseous emissions during the pyrolysis of C, R, and CP were very similar and included H₂, CH₄, CO, and CO₂ (syngas main constituents). Biomass production of C was affected by the nutrients load of the applied treatments, but this was not the case for R. Also, the nutrients treatments had no detectable effects on the biomasses’ ultimate or proximate analysis, HHV, thermal decomposition or resultant gaseous emissions. Thermal properties and behaviour of C and R were very similar to those of CP, showing their potential for bioenergy production and revealing that a WEF nexus strategy can be implemented in IMTA by energetic valorization of non-edible biomass of H. portulacoides used for water phytoremediation.

Yam peel (YP), cassava peel (CP), cocoyam peel (CoP) and plantain peel (PP) are common food wastes of the Niger Delta region. Anaerobic digestion (AD) of these wastes with water hyacinth (WH) presents a viable way of both providing renewable energy and cleaning up the environment. AD tests were carried out on the food wastes and WH to determine their biogas potentials. The experiments were carried out under mesophilic conditions at (37 ± 1 °C) over a period of 20 days and the tests were replicated to give an indication of repeatability. The results showed that YP+WH, CP+WH, CoP+WH and PP+WH had specific biogas yields of 0.42, 0.29, 0.39 and 0.38 m³/kg volatile solid (VS), respectively. The yields represented 76, 48, 70 and 69% of their respective theoretical values. Co-digesting the food wastes with WH in a VS ratio of 2:1 reduced the biogas yields of YP, CP, CoP and PP by 16, 22, 7 and 7%, respectively. The drop in gas production was due to indigestible complex molecules in the WH co-substrate. The results indicate that common food wastes in the Niger Delta can be used as feedstock for AD, but co-digesting with WH reduces the biogas yield.

The goals of ensuring energy, water, food, and climate security can often conflict. Microalgae (algae) are being pursued as a feedstock for both food and fuels—primarily due to algae's high areal yield and ability to grow on non-arable land, thus avoiding common bioenergy-food tradeoffs. However, algal cultivation requires significant energy inputs that may limit potential emission reductions. We examine the tradeoffs associated with producing fuel and food from algae at the energy–food–water–climate nexus. We use the GCAM integrated assessment model to demonstrate that algal food production can promote reductions in land-use change emissions through the offset of conventional agriculture. However, fuel production, either via co-production of algal food and fuel or complete biomass conversion to fuel, is necessary to ensure long-term emission reductions, due to the high energy costs of cultivation. Cultivation of salt–water algae for food products may lead to substantial freshwater savings; but, nutrients for algae cultivation will need to be sourced from waste streams to ensure sustainability. By reducing the land demand of food production, while simultaneously enhancing food and energy security, algae can further enable the development of terrestrial bioenergy technologies including those utilizing carbon capture and storage. Our results demonstrate that large-scale algae research and commercialization efforts should focus on developing both food and energy products to achieve environmental goals.

This study presents a comprehensive decision model for the integrative design of a biorefinery for bioethanol production and its supply chain (BPSC) under the water-energy-food-land (WEFL) nexus framework. A new optimization model was developed using a mixed integer linear programming to simultaneously identify the optimal process configuration of a bioethanol production plant and the optimal bioethanol supply network. The objective function of the model is to minimize the total annual cost for establishing and operating the BPSC to meet society’s needs (energy, water and food) under the limited resources and land availabilities, and technology capacity. The proposed model can provide the optimal solutions for design and operation of the BPSC: i) the types, and quantities of feedstocks; ii) types, number, and location of facilities and; iii) regional flows. The capability of the proposed model was validated through the case study of Jeju Island, Korea, with two scenarios: BPSC by cost (COPT) and nexus (NOPT) optimization. As a result, it was identified that the BPSC in NOPT requires higher energy supply cost (8.55 B$) than the COPT (6.44 B$). However, the BPSC in NOPT can satisfy the society demands with relatively smaller consumption of occupied land (2%), fresh water (30%) and primary energy consumption (64%) than that of the COPT, respectively.