Raised-bed plasticulture, an intensive production system used around the world for growing high-value crops (e.g., fresh market vegetables), faces a water-food nexus that is actually a food-water-energy-land-economic nexus. Plasticulture represents a multibillion dollar facet of the United States crop production value annually and must become more efficient to be able to produce more on less land, reduce water demands, decrease impacts on surrounding environments, and be economically-competitive. Taller and narrower futuristic beds were designed with the goal of making plasticulture more sustainable by reducing input requirements and associated wastes (e.g., water, nutrients, pesticides, costs, plastics, energy), facilitating usage of modern technologies (e.g., drip-based fumigation), improving adaptability to a changing climate (e.g., flood protection), and increasing yield per unit area.Compact low-input beds were analyzed against conventional beds for the plasticulture production of tomato (Solanum lycopersicum), an economically-important crop, using a systems approach involving field measurements, vadose-zone modeling (HYDRUS), and production analysis. Three compact bed geometries, 61cm (width)× 25cm (height), 45cm× 30cm, 41cm× 30cm, were designed and evaluated against a conventional 76cm× 20cm bed. A two-season field study was conducted for tomato in the ecologically-sensitive and productive Everglades region of Florida. Compact beds did not statistically impact yield and were found to reduce: 1) production costs by $150–$450/ha; 2) leaching losses by up to 5% (1cm/ha water, 0.33kg/ha total nitrogen, 0.05kg/ha total phosphorus); 3) fumigant by up to 47% (48kg/ha); 4) plasticulture's carbon footprint by up to 10% (1711kg CO2-eq/ha) and plastic waste stream by up to 13% (27kg/ha); 5) flood risks and disease pressure by increasing field's soil water storage capacity by up to 33% (≈1cm); and 6) field runoff by 0.48–1.40cm (51–76%) based on HYDRUS model simulations of 10-year, 2-h storm events in other major tomato production regions of California and Virginia.Re-designing the bed geometries in plasticulture production systems to be more compact is an example of win-win production optimization not only for traditional farms in rural areas but also for urban and peri-urban farms which are located closer to city centers. Compact beds could enable more plants per unit area, thus requiring less land area for the same production. Needing less area facilitates urban and peri-urban farming where land values can be high. Urban and peri-urban farming has several benefits, including reductions in transportation energy as production is closer to market and the ability for city wastewater to be reused for irrigation instead of freshwater withdrawals. Compact beds allow plasticulture to have smaller water, chemical, energy, carbon, waste, and economic footprints without impacting production. Improving agricultural systems in this way could enhance economic and environmental viability, which is essential for a sustainable food-water-energy-land-economic nexus.

Treatment of fresh fruits and vegetables with electrolyzed water (EW) has been shown to kill or reduce foodborne pathogens. We evaluated the efficacy of EW in killing Escherichia coli O157:H7 on iceberg lettuce, cabbage, lemons, and tomatoes by using washing and/or chilling treatments simulating those followed in some food service kitchens. Greatest reduction levels on lettuce were achieved by sequentially washing with 14-A (amperage) acidic EW (AcEW) for 15 or 30 s followed by chilling in 16-A AcEW for 15 min. This procedure reduced the pathogen by 2.8 and 3.0 log CFU per leaf, respectively, whereas washing and chilling with tap water reduced the pathogen by 1.9 and 2.4 log CFU per leaf. Washing cabbage leaves for 15 or 30 s with tap water or 14-A AcEW reduced the pathogen by 2.0 and 3.0 log CFU per leaf and 2.5 to 3.0 log CFU per leaf, respectively. The pathogen was reduced by 4.7 log CFU per lemon by washing with 14-A AcEW and 4.1 and 4.5 log CFU per lemon by washing with tap water for 15 or 30 s. A reduction of 5.3 log CFU per lemon was achieved by washing with 14-A alkaline EW for 15 s prior to washing with 14-A AcEW for 15 s. Washing tomatoes with tap water or 14-A AcEW for 15 s reduced the pathogen by 6.4 and 7.9 log CFU per tomato, respectively. Application of AcEW using procedures mimicking food service operations should help minimize cross-contamination and reduce the risk of E. coli O157:H7 being present on produce at the time of consumption.

A green and innovative eutectic solvent based extraction method was proposed for the determination of trace level vanadium in water and food samples by graphite furnace atomic absorption spectrometry. In this extraction technique magnetic stirrer was used for preparation of eutectic solvent by mixing of zinc chloride and acetamide at different molar ratios. Extraction capability of eutectic solvent was increased by adding a non ionic surfactant (Triton X-114) to enhanced phase transfer ratio, to significantly increase the recovery of hydrophobic complex of vanadium with ammonium pyrrolidine dithiocarbamate. A multivariate technique was applied to evaluate the important extraction parameters, which plays important role for optimum recovery of the targeted analyte by proposed extraction method. Multivariate techniques such as (factorial design and central composite design) were applied to screening out the most significant extraction parameters and optimized them. Under optimized extraction conditions, limit of detection and enhancement factor were found to be 0.01 µg L⁻¹ and 64.6, respectively. The relative standard deviation for the determination of trace level vanadium at 0.32 µg L⁻¹ concentration, was achieved to be <3.0% (n = 10). Validity and accuracy of the proposed extraction method was checked by analysis of certified reference materials of Canadian lake water and tomato leaves with % age recovery >98%. The eutectic solvent extraction method was successfully applied for the determination of the trace level vanadium in real water samples of different sources and acid digested food samples, collected from different locations of Tokat city, Turkey.