The use of snowmelt as an inexpensive multi-component tracer solution for active aquifer characterization is investigated, creating a valid alternative to existing artificial water isotope labelling using enriched deuterium oxide (²H₂O) and water-¹⁸O (H₂¹⁸O). The approach directly takes advantage of natural differences between groundwater and precipitation. It is shown, at laboratory-scale and small field-scale, that a direct injection of snowmelt into a porous medium allows for the tracing of water flow and, therefore, for the determination of transport parameters based on the stable isotope signatures (δ²H and δ¹⁸O) and on the sum parameter electrical conductivity (EC). The differences in the isotope signature between the snowmelt and groundwater applied in this study were significant, with ∆(δ²H) = 61.0‰ and ∆(δ¹⁸O) = 8.2‰, while the EC difference was ~0.5 mS/cm. Stable isotope breakthrough was observed to be almost congruent to sodium chloride (laboratory tracer experiment) and to uranine (field-scale push-drift-pull test), clearly supporting the assumption of conservative transport. A crosscheck of the isotope data in δ²H-δ¹⁸O plots revealed no significant biases in the tests. On the other hand, the snowmelt’s EC breakthrough suffered from a slight retardation due to ion exchange and mineral reactions.

The fractured volcanic aquifer of the Abaya Chamo basin in the southern Ethiopian Rift represents an important source for water supply. This study investigates the geochemical evolution of groundwater and the groundwater flow system in this volcanic aquifer system using hydrochemistry and environmental tracers. Water types of groundwater were found to transform from Ca-Mg-HCO₃ (western part of Lake Abaya area) to Na-HCO₃ (northwestern part), from the highland down to the Rift Valley. Silicate hydrolysis and Ca/Na ion exchange are the major geochemical processes that control groundwater chemistry along the flow path. Groundwaters are of meteoric origin. The δ¹⁸O and δD content of groundwater ranges from −4.9 to −1.1‰ and –27 to 5‰, respectively. The δ¹⁸O and δD values that lie on the summer local meteoric water line indicate that the groundwater was recharged mainly by summer rainfall. δ¹³CDIC values of cold groundwater range from −12 to −2.7‰, whereas δ¹³CDIC of thermal groundwater ranges from −8.3 to +1.6‰. The calculated δ¹³CCO₂₍g₎ using δ¹³CDIC and DIC species indicates the uptake of soil CO₂ for cold groundwater and the influx of magmatic CO₂ through deep-seated faults for thermal groundwater. In the western part of Lake Abaya area, the shallow and deep groundwater are hydraulically connected, and the uniform water type is consistent with a fast flow of large gradient. In contrast, in the northern part of Lake Abaya area, water underwent deep circulation and slow flow, so the water types—e.g. high F⁻ (up to 5.6 mg/L) and Na⁺—varied laterally and vertically.

Salinization in coastal aquifers is usually related to both seawater intrusion and water–rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl⁻, Na⁺, Ca²⁺, Mg²⁺ and SO ₄²–), as well as the isotopic content and ratios (²H, ¹⁸O, ⁸⁷Sr/⁸⁶Sr and ¹³C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

Based on analysis of groundwater hydrogeochemical and isotopic data, this study aims to identify the recharge sources and understand geochemical evolution of groundwater along the downstream section of the Shule River, northwest China, including two sub-basins. Groundwater samples from the Tashi sub-basin show markedly depleted stable isotopes compared to those in the Guazhou sub-basin. This difference suggests that groundwater in the Tashi sub-basin mainly originates from meltwater in the Qilian Mountains, while the groundwater in the Guazhou sub-basin may be recharged by seepage of the Shule River water. During the groundwater flow process in the Tashi sub-basin, minerals within the aquifer material (e.g., halite, calcite, dolomite, gypsum) dissolve in groundwater. Mineral dissolution leads to strongly linear relationships between Na⁺ and Cl⁻ and between Mg²⁺+ Ca²⁺ and SO₄ ²⁻ + HCO₃ ⁻, with stoichiometry ratios of approximately 1:1 in both cases. The ion-exchange reaction plays a dominant role in hydrogeochemical evolution of groundwater in the Guazhou sub-basin and causes a good linear relationship between (Mg²⁺+ Ca²⁺)–(SO₄ ²⁻ + HCO₃ ⁻) and (Na⁺+ K⁺)–Cl⁻ with a slope of −0.89 and also results in positive chloroalkaline indices CAI 1 and CAI 2. The scientific results have implications for groundwater management in the downstream section of Shule River. As an important irrigation district in Hexi Corridor, groundwater in the Guazhou sub-basin should be used sustainably and rationally because its recharge source is not as abundant as expected. It is recommended that the surface water should be used efficiently and routinely, while groundwater exploitation should be limited as much as possible.