Rhodium-Catalyzed Synthesis of Isoquinolines and Indenes from Benzylidenehydrazones and Internal Alkynes
2014
Huang, Xiao-Cheng | Yang, Xu-Heng | Song, Ren-Jie | Li, Jin-Heng
A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N–N bond and the C═N bonds and is dependent on the substituents of the benzylidenehydrazone.
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