Spatiotemporal variations of heavy metal historical accumulation records and their influencing mechanisms in the Yangtze River Estuary

Complex transformations of heavy metals in the mega-river-estuary continuum limit our understanding of their pollution history. This study investigated sedimentary compositions of heavy metals, major elements, total organic carbon, grain size, and radionuclides to study spatiotemporal variations in heavy metal accumulation patterns and their controlling mechanisms in four sediment cores (E1-E4) from the Yangtze River Estuary (YRE). Results show that only E3 in the distal YRE front mirrors well the heavy metal pollution history due to its continuous deposition in a stable sedimentary environment, while E1 and E2 record the influence of riverine and estuarine projects and processes apparently. E1 in the proximal YRE front registers intense human disturbance through sediment dredging and dumping activities to produce a thick layer of abnormal low ²¹⁰Pbₑₓ and minor heavy metal concentrations. E2 in the intermediate YRE front demonstrates the recently increasing influence of reduced sediment discharge by its upcore coarsening trend with decreased heavy metal concentrations. Flood and storm events left different imprints in core sediments of E2 and E3 by their coarse stratal units with fewer heavy metal concentrations. The source analysis indicates that heavy metals in estuarine sediments mainly come from natural processes but are significantly affected by human activities. A direct linkage of the heavy metal accumulation history with the socioeconomic development in recent decades is found by a comparison study of core data from the tidal river to the estuary, albeit with a remarkable spatiotemporal difference, which is jointly determined by grain size, offshore distance, hydrodynamic condition, depositional status, and sedimentation rate besides estuarine processes. This warns us to carefully interpret the heavy metal history from single or sparse core data in a mega estuary system with intense natural forces and human disturbances analogous to the YRE.