Heterocycle-substituted tetrazole ligands for copper-catalysed aerobic oxidation of alcohols
2014
Liu, Yangyang | Xie, Aming | Li, Junjian | Xu, Xiao | Dong, Wei | Wang, Boliang
An efficient copper-catalysed aerobic oxidation of alcohols has been established, which employed heterocycle-substituted tetrazoles as ligands. The commercially available (S)-5-(pyrrolidin-2-yl)-1H-tetrazole proved as the best ligand for this oxidation. Under optimized conditions, the substrate scope was broadened. A plausible mechanism was also proposed.
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