Catalytic, metal-free alkylheteroarylation of alkenes via distal heteroaryl ipso-migration
2018
He, Yonghui | Wang, Yaqi | Gao, Jun | Zeng, Liang | Li, Shusheng | Wang, Wei | Zheng, Xiaohui | Zhang, Shengyong | Gu, Lijun | Li, Ganpeng
A new direct alkylheteroarylation of alkenes with simple alkylnitriles via distal heteroaryl ipso-migration has been accomplished under metal-free conditions, in which inexpensive alkylnitriles served as radical precursors, which together with ease of operation makes this process a very practical protocol.
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