1-Deoxy-D-xylulose synthesized from the (S)-cyanohydrin of acrolein
2001
Fechter, M.H. | Gaisberger, R. | Griengl, H.
The biocatalytic transformation of acrolein into (S)-2-hydroxybut-3-enenitrile using the (S)-hydroxynitrile lyase from Hevea brasiliensis followed by Grignard C-elongation, asymmetric epoxidation and nucleophilic ring-opening afforded 1-deoxy-D-xylulose (1) in 47% overall yield.
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