Recycling of spent alkaline Zn-Mn batteries directly: Combination with TiO2 to construct a novel Z-scheme photocatalytic system
2020
Zhao, Zhong | Shen, Boxiong | Hu, Zhenzhong | Zhang, Jianwei | He, Chuan | Yao, Yan | Guo, Sheng-Qi | Dong, Fan
Recycling of spent alkaline Zn-Mn batteries (S-AZMB) has always been a focus of attention in environmental and energy fields. However, the current research mostly concentrated in the recovery of purified materials, and ignores the direct reuse of S-AZMB. Herein, we propose a new concept for the first time that unpurified S-AZMB can be used as raw materials for preparation of Z-scheme photocatalytic system in combination with TiO₂. A series of characterizations and experiments confirm that the combination with S-AZMB not only extends the response of TiO₂ to visible light, but also significantly enhances the separation ability of photogenerated electron-hole pairs. In the toluene removal experiment, the degradation kinetic rate of Z-scheme TiO₂@S-AZMB photocatalyst reaches 21.0 and 10.5 times than that of TiO₂ and S-AZMB, respectively. More notably, this S-AZMB based Z-scheme photocatalyst can maintain structural and photocatalytic performance stability in cyclic catalytic reactions. We believe that this work not only expands the research concept of recycling S-AZMB, but also provides a new idea for designing highly efficient Z-scheme photocatalysts.
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