Conformational analysis of N-aryl-N-(2-azulenyl)acetamides
2018
Ito, Ai | Amaki, Takamasa | Ishii, Ayako | Fukuda, Kazuo | Yamasaki, Ryu | Okamoto, Iwao
Aromatic amides bearing 2-azulenyl group on the amide nitrogen were synthesized and their structures were investigated. The π-electron density of the N-aryl group was found to influence the cis-trans conformational preferences of these compounds in solution. X-ray crystallography revealed that the plane of the 2-azulenyl ring has a strong tendency to lie coplanar with the amide plane when the azulene group is located on the same side as the amide oxygen atom.
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