Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions
2005
Jones, Gavin D. | McFarland, Chris | Anderson, Thomas J. | Vicic, David A.
The use of tpy′ (tpy′ = 4,4′,4″-tri-tert-butyl-terpyridine) as a ligand for nickel allows for the isolation of a Ni(i)–alkyl complex and a Ni(ii)–alkyl halide complex, both of which can be used as mechanistic probes of key steps in alkyl cross-coupling reactions.
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