Nickel-Catalyzed Cyanation of Phenol Derivatives with Zn(CN)₂ Involving C–O Bond Cleavage
2018
Gan, Yi | Wang, Gaonan | Xie, Xin | Liu, Yuanhong
An efficient nickel-catalyzed cyanation of aryl sulfonates, fluorosulfonates, and sulfamates with Zn(CN)₂ was developed, which provides a facile access to the nitrile products in generally good to excellent yields. The reaction is accomplished by using Niᴵᴵ complex as the precatalyst and DMAP as the additive. The method also displays wide functional group compatibility; for example, keto, methoxy, N,N-dimethylamino, cyano, ester, and pyridyl groups are well-tolerated during the reaction process.
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