Nickel-catalyzed regio- and stereoselective hydrophosphinylation of internal ynamides with H-phosphinates
2018
Kinbara, Atsushi | Kasai, Haruka | Sato, Kaede | Watanabe, Yuri | Yamagishi, Takehiro
A method for the catalytic hydrophosphinylation of internal ynamides with H-phosphinates has been developed for the first time. The protocol employing the catalyst generated from NiBr2 and PPh3 could be applied to several types of ynamides and H-phosphinates, affording (E)-β-aminovinylphosphinates in a highly regio- and stereoselective manner.
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