Giant Zn14 Molecular Building Block in Hydrogen-Bonded Network with Permanent Porosity for Gas Uptake
2014
Mondal, Suvendu Sekhar | Bhunia, Asamanjoy | Kelling, Alexandra | Schilde, Uwe | Janiak, Christoph | Holdt, Hans-Jürgen
In situ imidazolate-4,5-diamide-2-olate linker generation leads to the formation of a [Zn₁₄(L2)₁₂(O)(OH)₂(H₂O)₄] molecular building block (MBB) with a Zn₆ octahedron inscribed in a Zn₈ cube. The MBBs connect by amide–amide hydrogen bonds to a 3D robust supramolecular network which can be activated for N₂, CO₂, CH₄, and H₂ gas sorption.
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