Complexation of asymmetric diborenes with magnesium bromide
2018
Lu, Wei | Kinjo, Rei
The synthesis of neutral Mg complexes of asymmetric diborenes is reported. X-ray diffraction analysis reveals that the Mg center is unsymmetrically coordinated to the B₂ units of diborenes. Theoretical calculations manifest the donation of electrons from the π-type orbitals of diborenes to an empty orbital of Mg.
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