3-Component palladium–indium mediated diastereoselective cascade allylation of imines with allenes and aryl iodides
2002
Cooper, I. R. (Ian R.) | Grigg, Ronald | MacLachlan, William S. | Thornton-Pett, Mark | Sridharan, Visuvanathar
A new palladium–indium diastereoselective cascade allylation of imines using allenes and aryl iodides is described; N-tosyl and N-aryl homoallyl amines were obtained in moderate to good yields and excellent diastereoselectivity was observed when enantiomerically pure N-tert-butanesulfinyl imines were employed in the cascade.
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