Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu₉MgS₂B₂₀O₄₁
2019
Chi, Yang | Xu, Jing | Xue, Huai-Guo | Zhang, Yueping | Chen, Xiaolong | Whangbo, Myung-Hwan | Guo, Sheng-Ping | Deng, Shuiquan
We prepared a new rare-earth compound, Eu₉MgS₂B₂₀O₄₁ (EMSBO), and characterized its structural and physical properties. EMSBO consists of triple-Kagomé-layer slabs separated by nonmagnetic ions and groups. Within each slab, intervalence charge transfer has been found to occur between the Eu²⁺ and Eu³⁺ Kagomé layers, a new channel for quantum fluctuation of magnetic moments. The measured magnetic susceptibilities and the specific heat capacity exhibit very similar features characteristic of quantum spin liquid behaviors observed in other materials.
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