Bu4NI-Catalyzed Dehydrogenative Coupling of Diaryl Phosphinic Acids with C(sp3)–H Bonds of Arenes
2018
Xiong, Biquan | Wang, Gang | Zhou, Congshan | Liu, Yu | Zhang, Panliang | Tang, Kewen
An efficient phosphorylation of C(sp³)–H bonds of arenes with diaryl phosphinic acids via Bu₄NI-catalyzed dehydrogenative coupling has been developed. This transformation proceeds efficiently under transition-metal-free reaction conditions and represents a straightforward method to prepare valuable organophosphorus compounds from readily available arenes and diaryl phosphinic acids.
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