A simple colorimetric and ratiometric fluoride ion probe with large color change
2020
Shi, Heng | Chen, Hongjin | Li, Xiangguo | Xing, Jieni | Zhang, Gang | Zhang, Rui | Liu, Jian
Two colorimetric and ratiometric fluoride ion probes SHJ-1 and SHJ-2 based on the acylhydrazone skeleton have been developed. Among the eight anions (F⁻, Cl⁻, Br⁻, I⁻, ClO₄⁻, H₂PO₄⁻, HSO₄⁻, CH₃COO⁻), the present probes showed high selectivity and sensitivity toward fluoride ion detection with obvious color change. Notably, the probe SHJ-1 exhibited a red shift of 145 nm upon fluoride sensing, which is the largest value among fluoride ion probes based on acylhydrazone derivates to date. ¹HNMR titration study and theoretical calculations suggested that the strong binding of the probe SHJ-1 to fluoride as well as the further deprotonation may facilitate the intramolecular charge transfer transition. These two probes are 1 : 1 complexed with fluoride ions, and the detection limits were calculated to be 1.24 μM for SHJ-1 and 15.73 μM for SHJ-2.
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