1,2,3-Triazoles: Gas Phase Properties
2013
Wang, Kai | Zhen, Mu | Wang, Qiaoyi | Shi, Xiaodong | Lee, J. K.
1,2,3-Triazoles have come to the forefront as compounds of import in a vast number of applications. The fundamental properties of these species, however, remain largely unknown. Herein, the gas phase properties of 4-phenyl-1,2,3-triazole, benzotriazole, and a series of 1-phenylbenzotriazoles are described. Proton affinity and acidity values are computed and measured. Furthermore, ion–molecule reactions and H/D exchange studies are used to ascertain tautomer prevalence for the 4-phenyl species.
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