Asymmetric synthesis of diarylmethane derivatives by dynamic kinetic resolution
2015
Gooch, Lewis M. | Rossington, Steven B. | Wilkinson, James A.
Asymmetric allylation of ortho-methoxydiphenylmethane has been carried out with high yields and ee of up to 94% using the chiral ligand (−)-sparteine as an additive. Results of reactions performed under various conditions suggest that a dynamic kinetic resolution of two rapidly interconverting diastereomeric complexes is occurring.
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