Palladium-Catalyzed Difluoromethylation of Aryl Chlorides and Bromides with TMSCF₂H
2019
Ferguson, Devin M. | Malapit, Christian A. | Bour, James R. | Sanford, Melanie S.
A palladium-catalyzed cross-coupling of aryl chlorides/bromides with TMSCF₂H is described. Two different catalysts, Pd(dba)₂/BrettPhos and Pd(PᵗBu₃)₂, are demonstrated and provide a variety of difluoromethylated arenes in good yields.
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