Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives
2010
Laot, Yann | Petit, Laurent | Zard, Samir Z.
A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen.
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