Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds
2003
Stabenow, Frank | Saak, Wolfang | Weidenbruch, Manfred
Treatment of lead(ii) bromide with phenylmagnesium bromide at low temperature furnishes yellow crystals of the ionic compound [BrMg(THF)₅]⁺ [:Pb(PbPh₃)₃]⁻ which, upon X-ray crystallographic analysis, reveals three stretched Pb–Pb bonds and Pb–Pb–Pb angles of about 93°.
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