Reaktionen von SbCl5 mit Acetoaeetanilid / Reactions of SbCl5 with Acetoacetanilide
2014
Dietrich, W. | Eisinger, H. K. | Latscha, H. P.
Antimony(V) Chloride, Acetoacetanilide At room temperature acetoacetanilide and antimony(V) chloride form a 1:1-(1) and a 1:2-adduct (2). These adducts react to the heterocycles C₁₀H₁₀Cl₄NO₂Sb (3) and C₁₀H₉Cl₅NO₂Sb (4). 3 exists in solution in two stereoisomers. The Free Energy of Activation for the transformation of the isomers is estimated.
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