Synthesis of the ω6 (5Z,8Z)-Tetradecadienoic and (7Z,10Z)-Hexadecadienoic Polyene Fatty Acids
2015
Golovanov, A. B. | Ganina, K. D. | Groza, N. V. | Eremin, S. V. | Myagkova, G. I.
An approach using acetylenes was used and optimized to synthesize rare natural ω6 polyene fatty acids. The key synthetic step was cross-coupling of a propargyl derivative with a terminal acetylene in the presence of equimolar amounts of Cu(I).
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