Cp*Co(III)/MPAA-Catalyzed Enantioselective Amidation of Ferrocenes Directed by Thioamides under Mild Conditions
2019
Liu, Yan-Hua | Li, Peng-Xiang | Yao, Qi-Jun | Zhang, Zhuo-Zhuo | Huang, Dan-Ying | Le, Minh Dong | Song, Hong | Liu, Lei | Shi, Bing-Feng
Cp*Cobalt(III)-catalyzed enantioselective C–H amidation of ferrocenes using monoprotected amino acids (MPAAs) as chiral ligands was developed. The reaction was performed under mild conditions in high yields (up to 97%) with moderate enantioselectivity (up to 77.5:22.5 er), providing a promising strategy to create planar chirality via base-metal-catalyzed enantioselective C–H activation.
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