Pretreatment of Lignocellulosic Biomass with 1-Ethyl-3-methylimidazolium Acetate for Its Eventual Valorization by Anaerobic Digestion
2021
Jose D. Marin-Batista | Angel F. Mohedano | Angeles de la Rubia
This study assessed the breakdown of lignocellulosic biomass (LB) with the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]) as a pretreatment to increase the methane yield. The pretreatment was conducted for wheat straw (WS), barley straw (BS), and grape stem (GS) at 120 °:C for 120 min, using several LB to [Emim][Ac] ratios (1:1, 1:3, and 1:5 w/w). Pretreatment significantly disrupted the lignocellulose matrix of each biomass into soluble sugars. GS showed the highest sugar yield, which was followed by WS, while BS was slightly hydrolyzed (175.3 ±: 2.3, 158.2 ±: 5.2, and 51.1 ±: 3.1 mg glucose g&ndash:1 biomass, respectively). Likewise, the pretreatment significantly reduced the cellulose crystallinity index (CrI) of the resulting solid fractions of GS and WS by 15% and 9%, respectively, but slightly affected the CrI of BS (5%). Thus, BMP tests were only carried out for raw and hydrothermally and [Emim][Ac] (1:5) pretreated GS and WS. The untreated GS and WS showed similar methane yields to those achieved for the solid fraction obtained after pretreatment with an LB to [Emim][Ac] ratio of 1:5 (219 ±: 10 and 368 ±: 1 mL CH4 g&ndash:1 VS, respectively). The methane production of the solid plus liquid fraction obtained after IL pretreatment increased by 1.61- and 1.34-fold compared to the raw GS and WS, respectively.
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