Urban streams are degraded through multiple mechanisms, including severely altered flow regimes, elevated concentrations of waterborne contaminants, removal of riparian vegetation and the loss of a mosaic of heterogeneous aquatic habitats. Engineering of urban stream reaches using concrete is a widespread and extreme case of deliberate alteration of flow regimes and concomitant habitat simplification. To assess the effect of such engineering practices on stream ecosystems, we compared aquatic macroinvertebrate communities from concrete-lined engineered urban reaches, non-engineered urban reaches with natural substrates and reference reaches flowing through minimally disturbed forested subcatchments and with natural substrates, in the Sydney metropolitan region, Australia. The communities from all urban reaches were impoverished and distinctly different from more diverse communities in forested reference reaches. Despite low aquatic habitat heterogeneity, engineered urban reaches had very high abundances of Diptera and some other tolerant taxa. Diptera and/or Gastropoda were dominant in non-engineered urban reaches. Multivariate community structures were dissimilar between the urban reaches and forested reference reaches and between non-engineered and engineered urban reaches. However, the low family-level richness and SIGNAL scores in both urban reach types indicated they were severely ecological impaired, whether engineered or not. Most macroinvertebrate taxa in the regional pool that were hardy enough to inhabit urban reaches with natural substrates were also present in nearby concreted reaches. The results add weight to the growing evidence that in urban landscapes, regional-scale changes in water quality and flow regimes limit the establishment of diverse macroinvertebrate communities, which cannot be addressed through the provision of increased reach-scale habitat heterogeneity.

In this study, the removal of diclofenac (DCF) from aqueous phase by birnessite, a layered manganese oxide, was investigated by batch experiments. The results indicated that 90% of DCF was removed by birnessite within 4 h in different initial concentrations of DCF, and the kinetic experiment data were well fitted with pseudo-first-order kinetic model (R² > 0.98). The removal of DCF by birnessite was pH-dependent, and low pH was beneficial to the reaction. The presence of Fe²⁺ and Mn²⁺ strongly inhibited the removal of DCF. However, Ca²⁺, Mg²⁺, Zn²⁺, Cu²⁺, and humic acid (HA) promoted the reaction and following the order: Cu²⁺ > Zn²⁺ > HA > Mg²⁺ ≈ Ca²⁺. In addition, some typical anions, such as NO₃⁻, PO₄³⁻, and SO₄²⁻, had slight effects on the reaction. Electrochemical results demonstrated that the adsorption of DCF on birnessite was reaction rate-limiting step. Graphical Abstract ᅟ

Where surface-functionalized engineered nanoparticles (NP) occur in drinking water catchments, understanding their transport within and between environmental compartments such as surface water and groundwater is crucial for risk assessment of drinking water resources. The transport of NP is mainly controlled by (i) their surface properties, (ii) water chemistry, and (iii) surface properties of the stationary phase. Therefore, functionalization of NP surfaces by organic coatings may change their fate in the environment. In laboratory columns, we compared the mobility of CeO₂ NP coated by the synthetic polymer polyacrylic acid (PAA) with CeO₂ NP coated by natural organic matter (NOM) and humic acid (HA), respectively. The effect of ionic strength on transport in sand columns was investigated using deionized (DI) water and natural surface water with 2.2 mM Ca²⁺ (soft) and 4.5 mM Ca²⁺ (hard), respectively. Furthermore, the relevance of these findings was validated in a near-natural bank filtration experiment using HA-CeO₂ NP. PAA-CeO₂ NP were mobile under all tested water conditions, showing a breakthrough of 60% irrespective of the Ca²⁺ concentration. In contrast, NOM-CeO₂ NP showed a lower mobility with a breakthrough of 27% in DI and < 10% in soft surface water. In hard surface water, NOM-CeO₂ NP were completely retained in the first 2 cm of the column. The transport of HA-CeO₂ NP in laboratory columns in soft surface water was lower compared to NOM-CeO₂ NP with a strong accumulation of CeO₂ NP in the first few centimeters of the column. Natural coatings were generally less stabilizing and more susceptible to increasing Ca²⁺ concentrations than the synthetic coating. The outdoor column experiment confirmed the low mobility of HA-CeO₂ NP under more complex environmental conditions. From our experiments, we conclude that the synthetic polymer is more efficient in facilitating NP transport than natural coatings and hence, CeO₂ NP mobility may vary significantly depending on the surface coating.

Diflubenzuron (DFB) is a larvicide widely used to control Aedes aegypti populations as an alternative to organophosphates (OPs), with a specific mechanism of action for insects by inhibiting their chitin synthesis. However, DFB is used extensively in urban and rural environments, having the aquatic environment as the major receptor. Thus, the present study aimed to investigate the toxicity of DFB-based formulation and compare it with the toxicity of the OP temephos (TMP)-based formulation, a larvicide still used to control A. aegypti, on freshwater fishes Oreochromis niloticus and Hyphessobrycon eques. Organisms were submitted to acute (48 h) and prolonged (7 days) exposures, in the presence and absence of organic sediment, seeking interactions between chemical and sediment. Histopathological analyses were performed on O. niloticus gills and liver. According to 48-h median lethal concentration (LC₅₀), DFB- and TMP-based formulations were classified as harmful and toxic to fish, respectively, following the Globally Harmonized System of Classification (GHS). After prolonged exposure to sublethal concentrations, DFB-based formulation decreased H. eques body weight at concentrations 272-fold lower than its LC₅₀. Ultrastructural responses of O. niloticus indicated edemas and aneurisms on gills, and hepatocyte hypertrophy and vascular congestion of the liver. TMP-based formulation also induced pyknotic nuclei, which may lead to irreversible necrosis. The addition of organic sediment did not alter the larvicide toxicity, suggesting that larvicides remained available to the organisms. Altogether, these results suggest that as an insect-specific pesticide, DFB still induces mortality and tissue damage in fishes; thus, both larvicides pose risks to fishes.

Formation of trihalomethanes (THMs) through excessive chlorination in the supplied water and its carcinogenic nature is a public health concern in many parts of the world, including a couple of neighboring countries in Asia. However, the issue was not yet addressed either in the public health policy or in academia in Bangladesh. Therefore, the objectives of this study are to determine the THM concentration in supplied water, its multiple pathways to the human body, and an estimation of resultant carcinogenic risk to urban dwellers in six different regions of Dhaka city. Thirty-one supplied water samples were collected from 31 different water points located in Purana Paltan, Naya Paltan, Kallyanpur, Shyamoli, Malibagh-Rampura, and Panthapath regions in premonsoon time. Total chlorine and chlorine dioxide (ClO₂) and trihalomethane (THM) concentration were determined using UV-VIS spectrophotometer; total organic carbon (TOC), total inorganic carbon, and total carbon concentration were measured using TOC analyzer, and chloroform concentration was determined by applying gas chromatography-mass spectroscopy (GC-MS-MS) in the supplied water samples. Research findings indicate that THM concentration exceeded the USEPA acceptable limit (80 ppb) in all regions except Panthapath. Study results showed that carcinogenic risk via ingestion was higher than the USEPA acceptable limit of 10⁻⁶. Carcinogenic risk via dermal absorption and inhalation exposure was lower according to USPEA acceptable limit. To conclude, this study represents the current knowledge about THM concentration in supplied pipeline water and adverse health risk, which signifies that regulatory measures should be taken to reduce the THM concentration.

During phytoremediation of polycyclic aromatic hydrocarbons (PAHs) and heavy metals, the phytoremediation plants are often stressed by pollutants, which would reduce the efficiency of phytoremediation. The addition of organic acids from root exudates could alleviate the stress. In this study, three organic acids (citric acid, succinic acid, glutaric acid) were added to investigate the effects of organic acids on the stress response of Scirpus triqueter L. at two pyrene–lead concentrations. The activities of reactive oxygen species, malondialdehyde, plasma membrane H⁺-ATPase, and vacuolar H⁺-ATPase and PPase activity, as well as the activities of antioxidant enzymes (SOD, POD, and CAT) in Scirpus triqueter L. were determined. The addition of organic acids could effectively reduce the activities of reactive oxygen species, malondialdehyde, plasma membrane H⁺-ATPase, and vacuolar H⁺-ATPase and PPase activities. Under higher pollution, the damage of plant plasma membrane is more serious, but the addition of citric acid can alleviate this situation and even more effective than the relief under low pollution. The effect of citric acid was more significant than that of succinic acid and glutaric acid. These results demonstrated that organic acids could attenuate the stress of pyrene and lead to Scirpus triqueter L.

Rapid detection of oil released from underground storage tanks and estimation of its flow rate allows for the prevention of further contamination or the limitation of the spread of contaminants. In this research, we developed a method for oil release detection by sensing volumetric water contents (VWC) in a hydraulic control system. Oil release detection tests were conducted at bench and pilot scales. In the bench-scale test, oil and water were released directly on top of the oil release detection system. In the pilot-scale test, the release detection system was installed in the soil and the oil was spilled on the soil surface. The new oil release monitoring system was capable of detecting the oil release using the VWC decrease (0.42 → 0.11 m³/m³). The infiltration of water did not affect the value of VWC. Sequential injection or mixture of oil and water also showed a decrease in VWC (0.42 → 0.12 m³/m³). The rate of VWC decrease was directly proportional (− 0.003 ml/min) to the rate of oil infiltration. A conceptual model was suggested to delineate the mechanism of oil release detection and to estimate the rate of oil infiltration. The detectability of the oil release in soil was also verified in the pilot-scale test (0.45 → 0.12 m³/m³). The rate of oil infiltration could be estimated using the slope of the measured VWC. The amount of time for oil infiltration through the soil and dispersion during the migration should be considered to analyze the VWC curve properly. These results showed that the oil release detection system can be used to monitor oil release and to determine the rate of oil infiltration by installation in the soil near an underground storage tank.

In this work, the novel direct synthesis method of dimethylacetamide-based graphene oxide (GO) was performed through electrochemical exfoliation assisted by commercially available single-tail sodium dodecyl sulphate (SDS) surfactant. Then, the synthesised GO (SDS–GO) was incorporated into polyvinylidene fluoride (PVDF) solution to produce a nanofiltration (NF) membrane through the phase immersion method. The addition of GO into the preparation of membrane solution alters the membrane morphology and improves the hydrophilicity. TiO₂ was also used as an additive for the NF membrane fabrication to further increase the membrane hydrophilicity. The fabricated PVDF/SDS–GO/TiO₂ and PVDF/SDS–GO NF membranes were compared with pure PVDF membrane. Then, the fabricated NF membranes were tested for methylene blue (MB) rejection with 10 ppm MB concentration. On the basis of the dead-end cell measurement operated at the pressure of 2 bar, the PVDF/SDS–GO/TiO₂ presents high MB rejection (92.76%) and the highest dye flux (7.770 L/m² h). This dye flux value was sevenfold higher than that of pure PVDF membrane (1.146 L/m² h) which was due to the utilisation of both GO and TiO₂ that improved the membrane hydrophilicity as indicated by the lowest contact angle (64.0 ± 0.11°). High porosity (57.46%) also resulted in the highest water permeability (4.187 L/m² h bar) of the PVDF/SDS–GO/TiO₂ NF membrane.

Water resource engineers extensively use regional flood frequency analysis to compute the discharge at ungauged sites with limited flow records in the river basins. Frequency and magnitude are the two important factors required to be analyzed for an effective assessment of flood disaster risk management. Globally, many linear clustering techniques are employed to categorize the watershed which are ineffective when dealing with noise and outliers. The present study overcomes this by proposing a relatively new nonlinear clustering algorithm based on hierarchical estimation of densities (NLCAHD) for the Cauvery basin, where the Homogeneity test (H) is enforced to identify the group of stations with same populations. Discordancy measure is carried out for screening the data in order to eliminate the conflicting sites from the group. The whole basin is classified into six homogeneous clusters, while the goodness of fit measure tests the data to distinguish the preferred distribution for the purpose of calculating the growth curves. A comparative study is made with the other linear algorithms such as K-means and C-means, which reveals the better performance of the proposed nonlinear model for identifying the homogeneous regions, in arriving at precise estimates of flood quantiles for various return periods up to 160 years.

Despite the controversy, the ecological risk of microplastics research has increased sharply from only one in 1966 to 495 in 2018, according to Web of Science with microplastics as keyword. To date, an upward trend of global microplastics mass emission was confirmed by many environmental scientists. The ocean is the ultimate destination of land-based microplastics sources; therefore, most of efforts were concentrated on microplastics in aquatic environment. In this brief article, the global release of microplastics and flux into the ocean in the recent decade were estimated roughly. The plastics fragmentation in the marine environment only accounted for 22% of total microplastics release (assuming defined emission rate per capita and fragmentation rate of plastics). Future research is needed for microplastics generation and retention in the terrestrial system, especially indoor environments. The accumulated microplastics over the environmental self-purification capacity certainly increases stress for the marine, freshwater and terrestrial ecosystem.