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Chemical Pretreatment of Rice and Wheat Straws to Reduce the Recalcitrant Structure: Comparative and Kinetic Studies with Different Chemicals for Biogas Production Texto completo
2023
Nikita Kanaujia, Shalu Rawat and Jiwan Singh
In this study, a comprehensive comparison of two different chemical pretreatments of wheat straw (WS) and rice straw (RS) was made. The pretreatment was performed using piranha solution and p-toluenesulfonic acid (PTSA) to dissolve the biomass’s complex lignin and hemicellulose matrix to enhance its methane production. Energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopes (SEM), and X-ray diffraction (XRD) analysis, were used to analyze the characteristics of untreated and pretreated feedstock. WS and RS treated with piranha solution showed maximum methane yield (1234 mL and 1196 mL, respectively). The piranha pretreatment increased the methane yield of wheat straw by 2.37 folds and rice straws by 2.31 folds. The maximum VFA concentration was observed in WS on the 14th day in the piranha-treated sample, 1553.33 ± 2.8 mg.L-1, while in RS on the 21st day in the untreated sample, 676 ± 5.77 mg.L-1. SEM analysis of piranha-treated WS indicated a reduction in recalcitrant structure. Deformation of C-O, C=C, C-C-O, and C-H bonds in cellulose, hemicellulosic, and lignin as a result of chemical pretreatment in WS and RS was also indicated by FTIR analysis. The modified Gompertz model (MGM) and logistic function model (LFM) appropriately defined the degradation process and explained cumulative biogas’ kinetic. Pretreatment with piranha solution reduces the complexity of WS and RS, thus increasing methane production by reducing the retention time.
Mostrar más [+] Menos [-]Effect of Elevated Ozone on Soybean (Glycine max L.) Cultivar: Role of Orange Juice and Synthetic Ascorbic Acid Texto completo
2023
Indra Jeet Chaudhary, Bhavna Nigam and Dheeraj Rathore
Ozone is a hazardous gas for the environment and negatively affects plant and human health. These days, phytoextracts are commonly used as a source of bioactive compounds for reducing the detrimental environmental effects on plants. In the presented study, soybean cultivar JS-335 was used to assess the protective role of synthetic ascorbic acid (SAA) and orange juice (25% orange juice, enriched ascorbic acid) under ozone stress conditions. The results showed that under ozone stress, soybean cultivar JS-335 reduced growth and biomass and negatively affected the biochemical properties of plants due to these changes, finally causing yield losses. Foliar-applied OJ >and SAA improved plant growth and development and increased crop yield. It was discovered that a 25% OJ coupled with ascorbic acid and other essential nutrients and biomolecules was almost as effective as a 100 ppm SAA in reducing the harmful effects of ozone stress on soybean plants. As a result, it was determined that OJ, a less expensive source of ascorbic acid, can improve ozone resistance in plants in ozone-prone areas.
Mostrar más [+] Menos [-]Occurrence of Heavy Metals in Soil and Selected Edible Plants in the Vicinity of Major Lead-Zinc Mining Sites in Ebonyi State, Nigeria Texto completo
2023
E.B. Ogbuene, O.G. Aloh, C.T. Eze, O.O. Eze, T.E. Ugochukwu, A.M. Oroke, C.E. Izueke-Okolo, A.V. Ozorme, C.J. Ibekwe and C.A. Eze
The occurrence of heavy metals in soil and selected edible plants (Manihot esculenta, Dioscorea rotundata, Ipomoea batatas, Telfairia occidentalis, and Chromolaena odorata) in the vicinity of major Lead-Zinc mining sites in Ebonyi State, Nigeria was investigated. The concentrations of the detected heavy metals in soil from the study sites ranged from 0.38-77830.99 (mg.kg-1). The limit values for all detected metals in soil from the mining sites were exceeded in most instances. The results showed that the plant species accumulated heavy metals near the mining sites to varying levels in their shoots and roots. The limit values for all detected heavy metals in the edible plants were not exceeded except in a few instances. The plant species demonstrated varying effectiveness for phytoextraction, indicating their appropriateness in the phytoremediation of heavy metal-contaminated soil. Therefore, examining the environmental consequences of uncontrolled mining activity in the vicinity of the mining sites with a scientific approach has helped to increase our knowledge of the pollution problem in the mining sites, reveal the ferocity of the situation, and contribute to the techniques presently in use for monitoring chemical pollution in a mining-impacted ecosystem.
Mostrar más [+] Menos [-]Landslide Potential Analysis Using Unmanned Aerial Vehicle in South Leato Village, Gorontalo City, Indonesia Texto completo
2023
S. S. Eraku, A. P. Permana and M. N. Baruadi
Spatial data technology using unmanned aerial vehicle (UAV) is one of the aerial imaging technologies used to produce detailed data. However, its utilization for mapping, especially disaster mapping needs an in-depth study. The research site is located within 00-”00’29°51’31°00” N and 12327’5°-123”00’3°” E that covers an area of 2,531 Ha, which consists of 1,745 Ha land and 786 Ha water areas. Administratively, the research site is in South Leato Village of Dumbo Raya sub-district of Gorontalo city with a total area of 41,9 Ha. This study is aimed at assessing the landslide by creating a landslide zonation map and finding out the landslide potential area by using the UAV. This research employs field surveys by using drones and Geographic Information System (GIS) analysis. It is found that the parameters that influence landslides are lithology, rainfall, slope inclination, lineament density, and land use. The landslide vulnerability analysis reveals three levels of vulnerability in this site; low, medium, and high vulnerability, in which, 19 Ha is classified as low vulnerability area, 9.5 Ha is classified as medium vulnerable, and 13.5 Ha is classified as highly vulnerable area.
Mostrar más [+] Menos [-]Preparation and Characterization of Slow-Release Zinc and Iron Fertilizer Encapsulated by Palm Stearin Texto completo
2023
Maizatiey Farizza Mohd Nasir, Md. Kamal Uddin(), Mohd Salleh Kamarudin, Muhammad Fadhil Syukri Ismail, Arina Shairah Bt Abdul Sukor and A. Abubakar
Using granular form application in the pisciponic system, this study investigates the effects of supplementation in the pisciponic system on plant growth performance. This study was conducted at the Aquaculture Experimental Station in Puchong, Selangor. The experiment was set up in a greenhouse with a plastic liner at the bottom. The coated fertilizers were immersed in 500 mL of distilled water in the beakers. The immersion times were analyzed for each 3, 6, 12, 18, 24, 30, 36, 42, 48, 54, 60, 66, and 72 hours. Insoluble solids and water were then filtered using filter paper and dried in the oven, followed by the drying process to obtain a constant weight before being put in the desiccators. During the release test, the distilled water was taken at every 48-hour interval, and the concentration of nutrients was determined from the atomic absorption spectrometer. The findings indicate that the weights of release fertilizers, specifically Zn and Fe, significantly decreased over time. At the lowest concentration, the coated zinc and iron weights decreased as time increased. Referring to the curve results, the Zn fertilizer started drastically decreasing its weight at hour 24, which decreased approximately to 0.002 for every subsequent hour. Meanwhile, Fe fertilizer decreased drastically at hour 66, where the weight dropped from 0.10467 to 0.039. However, the final weights for both fertilizers at hour 72 were about the same.
Mostrar más [+] Menos [-]Petroleum-Based Plastics Versus Bio-Based Plastics: A Review Texto completo
2023
Shikha Kumari, Alka Rao, Manjeet Kaur and Geeta Dhania
Plastic needs have expanded along with population growth, industrialization, and urbanization. Plastic is unrivaled due to its useful properties and is used to prepare numerous important goods daily. This paper encloses the different kinds and applications of petroleum-based plastic and the drawbacks related to their use, i.e., its nonbiodegradability which leads to their stay in the environment for a very long time. Additionally, there are not enough effective disposal techniques for the large volume of plastic waste produced; thus, plastic garbage builds up in the environment and endangers it. Limiting the usage of plastic is necessary to protect the environment. This can be done with the help of bioplastic, which is an excellent substitute for plastic. The different kinds of bioplastic and their biodegradability in different mediums, viz., soil compost and aquatic systems, are addressed in this paper. Along this, the different areas of application of bioplastic have been explored. The present study also addresses the underlying mechanism of plastic polymerization and biodegradation and the current status of bioplastics in the global market.
Mostrar más [+] Menos [-]Types and Distribution of Macroinvertebrates Stressed by Heavy Metals in Mangrove Forests Texto completo
2023
W. Budijastuti, R. Ambarwati, N. Ducha, F. Rachmadiarti, L. Lisdiana and K. Sahani
Heavy metals can decrease the number of species in nature. This research aims to determine the relationship between the type of macroinvertebrates stressed by heavy metals in the Wonorejo Mangrove Area, Surabaya, East Java. This type of research is observational. The determination of stations was done using the purposive random sampling method. Tests for Pb and Cd content were carried out using the AAS method. Nutrient content testing was carried out using the AAS and Kjeldahl methods. Data analysis was presented descriptively, and multivariate analysis was done using Principal Component Analysis (PCA). Based on the present research, it can be concluded that there are variations in the type and distribution of macroinvertebrates stressed by heavy metals in the mangrove area of Surabaya. Station 1 is dominated by Ocypode ryderi, Station 2 by Assiminea sp., Station 3 by Scylla paramamosain, and Station 4 by Cerithidea sp. with the high presence of metals (Cd, Pb), and soil and water nutrients (Org-C, N) at Stations 1, 3, and 4. The Station 2 has only Pb. Assiminea sp. (Phylum Mollusca) can be the best candidate for metal bioindicators because it appears in all locations where soil and water have been contaminated with Pb and Cd metals without affecting their life.
Mostrar más [+] Menos [-]Hydrogeochemical Characteristics and Suitability of Groundwater for Drinking and Irrigation from Shallow Aquifers of PG1 Watershed in Chandrapur District of Maharashtra Texto completo
2023
S. S. Deshpande and Y. A. Murkute
An endeavor has been made to understand the hydrogeochemical characteristics of groundwater from shallow aquifers of the PG1 watershed (latitudes 19°38’30” to 19°50’30” N and longitudes 79°04’00” to 79°11’00” E). The appropriateness of groundwater has also been checked for various purposes. The groundwater from the study area is alkaline and slightly saline. The Ca2+ ˃ Mg2+ ˃ Na+ ˃ K+ and HCO3- ˃ SO42- ˃ Cl- ˃ NO3- was the ascendancy of cations and anions. The earth metals (Ca + Mg) exceeded the alkali metals (Na + K). The positive correlation interpreted from the interrelationship of Na+ vs Cl- exhibited a silicate weathering process for the liberation of ions in groundwater at the rock-water interface. In addition to the non-lithological source, anthropogenic inputs were inferred, indicating the agricultural fertilizers and domestic wastewater. All the groundwater samples from the study area are suitable for drinking and domestic use. The groundwater from the study area is also suitable for irrigation with negligible exceptions.
Mostrar más [+] Menos [-]Microbial Consortia Preparation for Amylase, Protease, Gelatinase and Lipase Production from Isolates Obtained from Organic Kitchen Waste Texto completo
2023
Snehal Masurkar and Girish R. Pathade
Households, restaurants, canteens, and hotel wastes constitute kitchen waste. Every day our growing cities generate more and more waste, which is overloading our municipal systems. The main aim of the present work was to prepare a microbial consortium that can effectively and rapidly bring about the degradation of kitchen wastes that can be used in agricultural soils. More than 100 different bacterial isolates were obtained from various kitchen waste dumping areas. The bacterial isolates were studied to produce enzymes like amylase, gelatinase, lipase, and protease on respective media plates. The best 20 isolates were subjected to enzyme quantification. The isolates showing maximum production for all four enzymes were selected for consortia preparation. The consortia of isolates were prepared by permutation combinations. Amongst all consortia prepared consortium No. 7 showed maximum enzymatic potential. The bacterial isolates in the best consortium (No. 7) were further characterized and identified as KW104 Serratia marcescens, KW37 Micrococcus luteus, KW128 Brevindimonas mediterranea, KW91 Bacillus tequilensis, and KW97 Exiguobacterium mexicanum. This consortium showed rapid degradation of waste as compared to others in 15 days duration of time showing good potential for compost formation when applied to plant growth.
Mostrar más [+] Menos [-]Measurement of Black Carbon Absorption Coefficients Using an Aethalometer and Their Association with Visibility Texto completo
2023
Khadeejeh M. Hamasha
Black carbon (BC) is a pollutant aerosol affecting climate and human health. Light absorption coefficients of black carbon (Babs) were measured using an aethalometer model AE33 at wavelengths 370, 470,520,660,880, and 950 nm. Babs for the seven wavelengths at seven sites in Jordan fluctuated with time and peaked at rush hours. The daily average values for all sites were inversely proportional to the wavelength. The average daily visibility values in the seven Jordan sites varied between 72 km and 211km. In the Irbid site, the daily average visibility values for 7-13 Nov. 2021 varied between 43 km and 107 km. BC varied from hour to hour and from day to day. The daily average values of BC in Irbid for the period of 7 -13 Nov. 2021 varied between 2.24 μg.m-3 and 4.66 μg.m-3. BC peaked at the rush hour and had the lowest values on Friday. About 90% of the measured BC was from fossil fuel sources and 10% from biomass-burning sources.
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