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Quantification of Methane Emissions Rate Using Landgem Model and Estimating the Hydrogen Production Potential from Municipal Solid Waste Landfill Site
2023
Ramprasad, C.
In India, solid waste is deposited mostly in uncontrolled open landfills without proper segregation and handling methods. Organic wastes dumped in a landfill undergo anaerobic decomposition and emit landfill gases like methane and carbon dioxide. Landfill gases are a significant contributor to greenhouse gases and greatly impact climate change. In the interim, reducing gas emissions and controlling and recycling such gasses is important from environmental hygienic, and global perspectives. Landfill gas has tremendous potential to convert as a source of alternative fuel. The present study estimates the CH4 (Methane) and CO2 (Carbon dioxide) emissions and quantifies the renewable energy available and hydrogen production potential using the LandGEM 3.02 empirical models for the Kanuru, Vijayawada landfill. It was observed that methane emission peaked in 2042 with an emission rate according to the model was 2.51E+08 Metric tons CO2 equivalents. The gas-recovery system is an essential component in landfills for extracting energy with 75-80% efficiency; the generation rate of greenhouse gases will reduce to around 1.78E06 Mg of CO2 eq. The predicted methane emissions vary from 1.33E6-9.22E6 cu.m per year for the period of 2010-2042. It was also estimated that annual energy production from LFG emissions was from 1.8-130 GWh per year, and hydrogen production potential was 0.6-43.3 Gg per year. The study concludes that projected scientific data will assist policymakers in creating sustainable MSW management by bridging the gap between sustainable renewable energy production and protecting the environment. The basic objectives of the study include the quantification of landfill gas production using the LandGEM model for Vijayawada, assessing the electricity generation potential of the landfill methane gas emitted, methane and carbon dioxide recovery from landfills with energy conversion could reduce GHG emissions, and estimation of hydrogen generation potential from the landfill methane emissions.
Mostrar más [+] Menos [-]Chemistry, Metabolism and Neurotoxicity of Organophosphorus Insecticides: A Review
2023
Singh, Ashutosh | Singh, Abhishek | Singh, Akhilesh | Singh, Priti | Singh, Vivek | Singh, Yogender | Tuli, Hardeep Singh | Abdulabbas, Hadi Sajid | Chauhan, Abhishek
Organophosphorus compounds (OPs) are phosphoric acid derivatives represented by the formula (R2XP=O/S), R as organic groups; however, they need not contain a direct carbon-phosphorus bond. The organophosphorus compounds can be categorized into three classes, viz., organophosphates, carbamates nerve agents. The OPs having application as insecticides are generally phosphorothioates (i.e., containing P=S bond). These sulfur analogs are first bioactivated (in vivo) and converted to oxygen analogs responsible for exerting toxic action. These organophosphorus compounds are esters, fluorides, anhydrides, and amides of phosphoric, phosphorothioate, and phosphorodithioic acids. The toxicity of OPs is related to their molecular structure, metabolism in the targeted organisms, concentration, mode of decomposition, application, ingestion in organisms, etc. Exposure to OPs leads to the appearance of neurological symptoms followed by acute poisoning by targeting the target primarily, acetylcholine (AChE). However, secondary targets and other harmful effects besides nerve system problems are also reported. Organophosphates poison insects and other animals, including birds, amphibians, and mammals. These chemicals can have neural effects (Neurotoxicity), non-neuronal effects, or acute toxicity, which may also result in fatality. Their uncontrollable widespread became a significant threat to the environment; thus, corrective measures have been essential to save living beings and the environment from further damage.
Mostrar más [+] Menos [-]Multivariant Assessment of Metals Using Liverworts as an Appealing Tool in Catchment Sites of Uttarakhand, India
2023
Chaturvedi, Priyank | Singh, Shivom | Rathore, Kajal S.
This study aimed to conduct a systematic review to analyze heavy metals seasonal concentrations in Uttarakhand tourist hotspot cities (Almora, Nainital, Ranikhet, Mussoorie, and Dhanaulti). A total of 45 samples of liverwort Dumotiera hirsuta were collected from five different cities during winter (Dry deposition) and monsoon (Wet deposition) in the year 2021. The concentrations of Zn, As, Cd, and Pb due to anthropogenic pollution load in the selected locations were analyzed by active biomonitoring using Inductive Coupled Plasma Mass Spectrometry (ICP-MS). Concentration loading of zinc, arsenic, cadmium, and lead was observed to be 79%, 71%, 48%, and 33%, respectively, higher during the dry (winter) season when compared with the monsoon dataset. Multivariant data were analyzed using Principal Component Analysis (PCA) with three components explaining maximum variation in data by factor loading through varimax rotation. The rapid growth and development have connected tourists to the mountain of the western Himalayas. Thus, a monitoring program is needed in these areas for further assessment. So that necessary action can be taken to conserve the eco-sensitive zones of Uttarakhand.
Mostrar más [+] Menos [-]Biodiesel from Dunaliella salina Microalgae Using Base Catalyzed Transesterification – An Assessment through GC/MS, FTIR and NMR Studies
2023
Hariram, V. | Janarthanan, M. | Paul, R. Christu | Sivasankar, A. | Akram, M. Wasim | Sangeethkumar, E. | Ramanathan, V. | Khan, P. Sajid | Reddy, S. Manikanta
Algal biofuels are a promising renewable feedstock to produce energy that can supplement future energy demands greatly. The present study aims to utilize Dunaliella salina, a hypersaline, unicellular greenish-orange micro-algae, to produce bio-oil. F/2 nutrient media and trace metal and vitamin solution under carbon-dioxide-rich conditions were used to cultivate the microalgae. Ultrasonic extraction method at 60 Hz for 90 min isolated 650 mL of bio-oil. A single-stage based-catalyzed transesterification process with methanol and sodium hydroxide yielded 380 mL of Pure Dunaliella salina biodiesel at % an extraction efficiency of 87%. The Phytochemical screening on the cultivated Dunaliella sp. was performed to understand its feasibility to be used as a fuel for IC engines. Furthermore, the obtained biodiesel was characterized using Fourier Transform Infrared Spectrometer (FTIR), Gas Chromatography Mass Spectrometer (GCMS), and Nuclear Magnetic Resonance (NMR) spectral analysis.
Mostrar más [+] Menos [-]Assessment of SO2 Emissions from Cement Industries Utilizing Limestone with High Pyritic Sulfur Content: Case Study of Cement Plants in the Jaintia Hills District, Meghalaya, India
2023
Mandal, Arnab | Choudhury, M. K. | ., Nazimuddin | Gargava, Prashant
In properly operated Cement Plants, SO2 emissions are mostly caused by pyritic sulfur (sulfides) in the used limestones, accounting for approximately 85% of the raw mill in the plant. However, the pyritic sulfur content in limestones of the Jaintia Hills district of Meghalaya and their influence on the SO2 Emission from cement industries of Meghalaya have not been studied so far. The current study is conducted to perform an in-depth investigation of pyritic sulfur content in limestone reserves used by Meghalaya Cement Industries to assess the SO2 emission in the cement industries using high pyritic sulfur limestones and review the existing technology for the recommendation of the most suitable technology to minimize the SO2 Emissions. Random testing of collected limestone samples from various locations of Captive Mining sites in Cement Industries is performed to assess average pyritic sulfur concentration along different mining benches. Pyritic Sulfur Content (wt.%) in collected limestones varies from 0.15% to 3.5%. Polynomial Regression Analysis shows that Avg.SO2 Emission(Y) from Klin Stack can be represented as a function of pyritic sulfur content (X) (wt.%) of used limestones in the process: Y = 273.7X2 + 21.46X + 422.76. Based on the pyritic sulfur content in limestones, it is observed that “the more the Pyritic Sulfur content is, Darker the Limestone Samples are.” Hence, A Colour Scale has been prepared to visualize higher pyritic sulfur content in limestones. For longer-term sustainability, installing a Flue-Gas Desulfurization (FGD) unit at the kiln stack outlet may be included in the manufacturing process of cement plants to reduce the SO2 Emissions from Stack.
Mostrar más [+] Menos [-]Decarbonization of the Building Sector in Morocco – A Systematic Review
2023
Majaty, S. El | Touzani, A. | Kasseh, Y.
This article is a systematic review of the decarbonization of the building sector in Morocco. It explores the different approaches and technologies used to reduce greenhouse gas emissions and achieve decarbonization targets in this sector. The article examines the policies and regulations in place in Morocco to encourage decarbonization of the building sector, as well as the initiatives taken by key actors to reduce carbon emissions in their buildings. It also reviews sustainable building technologies and renewable energy systems currently used in the country. The systematic review concludes that while Morocco has put in place policies and regulations to encourage the decarbonization of the building sector, there is still much to be done to achieve the ambitious decarbonization targets set by the country. The authors of the article recommend greater investment in sustainable building technologies and renewable energies, as well as increased collaboration between public and private sector actors to accelerate the transition to low-carbon buildings.
Mostrar más [+] Menos [-]Ambient Air Quality Monitoring with Reference to Particulate Matter (PM10) in Kolhapur City
2023
Bhosale, C. S. | Mane, P. R. | Salunkhe, J. S. | Mothgare, V. M. | Sutar, S. S. | Manglekar, S. B. | Jadhav, A. S. | Raut, P. D.
Air is an important medium for all living beings and is essential for the well-being of all. Monitoring of air is important to know the quality of air. The air quality monitoring was carried out in Kolhapur City under the National Air Monitoring Program. The present study involves the assessment of PM10 as described in the National Ambient Air Quality Standards (NAAQS). The source apportionment study related to particulate matter was carried out in Kolhapur City. The study also determined the average PM10 concentration in the city as it will be useful for preparing an action plan to reduce PM10 concentration. PM10 concentration was calculated as per the standard method adopted by CPCB. Sampling was carried out for 8 hours in three shifts twice a week at each sampling site for three consecutive years. Mahadwar Road (MR) and Dabholkar Corner (DC) were selected per the surrounding residential area, population density, and traffic conjunction. The third site Shivaji University (SUK), was selected as a control site. The results indicated that the PM10 level has risen above the prescribed standards of NAAQS. The reason for the rise in PM10 may be due to fossil fuel burning, construction activity, vehicles, and unpaved roads. The Analysis of Variance (ANOVA) technique is used to check the equality of the mean concentration of PM10 at these three locations and found a significant difference between mean concentrations of PM10, suggesting increased particulate matter.
Mostrar más [+] Menos [-]Emerging Trends in Wastewater Treatment of Semiconductor Industry: A Review
2023
Sadafale, Hemant S. | Gaikwad, R.W.
The semiconductor industry produces a lot of wastewater. These wastewaters can affect the environment if they are not treated. As a result, one of the semiconductor industry’s primary concerns and duties is the treatment and disposal of wastewater from the industry. Many processes, including electrocoagulation, electro-adsorption, and coagulation-flocculation using both natural and synthetic coagulants, have been invented over the years for purifying semiconductor effluent. The long-term viability of this system is unknown although it generates solid by-products (sludge) and requires routine sludge disposal, both of which raise the operational expenses of effluent treatment. Thus, a sustainable alternative method of removing contaminants from the semiconductor industry is needed to advance toward pollution prevention and green innovation. The hydrodynamic cavitation technique has improved over time and is useful for treating water and wastewater. This article gives an insight into different wastewater technologies, so proper technology must be chosen.
Mostrar más [+] Menos [-]Production of a Database on Short-Lived Climate Pollutants (SLCP) and the Elaboration of Projection Scenarios of these Emissions Using the LEAP Software - The Case of Morocco
2023
Kasseh, Y. | Touzani, A. | Majaty, S. El
Short-lived climate pollutants (SLCPs) have significant effects on climate, human health, and the environment. In Morocco, steps are being taken to reduce SLCP emissions, but effective policymaking requires a thorough understanding of emission sources and trends. In this paper, we present a study on the production of a database on SLCP emissions in Morocco, as well as the development of scenarios to project these emissions using LEAP software. The results of this analysis allow us to better understand the emissions sources and evaluate the impact of different emission reduction policies.
Mostrar más [+] Menos [-]Intellectual Property Rights Regime in Green Technology: Way Forward to Sustainability
2023
Khan, Z. A. | Singh, Shireen
Climate change crises and environmental imbalances have been a significant concern globally in recent times. The climatic changes give rise to various issues such as global warming, depletion of the ozone layer, deterioration of natural resources, soil erosion, deforestation, and more. Many international and national agreements and policies have been created to protect the environment, from the UNFCCC to the recent Paris Agreement, aiming to control rising environmental issues. However, developed and developing countries must achieve desirable results in combating climate change. Industrial and technological developments are critical reasons for environmental pollution and degradation. Progress is necessary for planned developing countries, but growth and expansions shall also consider ecological sustainability. Technology shall be novel in adapting to the changes, considering the effects it can produce on the environment. Green technology combines technology with the environment, also called environmental technology, clean technology, or sustainable technology. It is a combination of science and technology together to mitigate climatic changes and protect the environment. Green technology is the modern sustainable solution to pressing environmental concerns. India is one of the countries globally showing rapid green technology developments. The authors of this paper have tried to highlight the dire need to modify technological developments vis-a-vis environmental sustainability to protect the environment. The research paper delves into and understands the interface between clean technology’s importance and relevance for ecological sustainability and the role of patent law, particularly in dealing with issues of the environment. The paper shall also establish a harmonious relationship between patent law and its role in ensuring environmental sustainability.
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