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Risk assessment of the presence of polycyclic aromatic hydrocarbons (PAHs) in coastal areas of Thailand affected by the 2004 tsunami Texto completo
2013
Pongpiachan, S. | Tipmanee, D. | Deelaman, W. | Muprasit, J. | Feldens, P. | Schwarzer, K.
The total concentrations of twelve, likely carcinogenic, polycyclic aromatic hydrocarbons (PAHs) (i.e., phenanthrene (Phe), anthracene (An), fluoranthene (Fluo), pyrene (Pyr), benz[a]anthracene (B[a]A), chrysene (Chry), benzo[b]fluoranthene (B[b]F), benzo[k]fluoranthene (B[k]F), benzo[a]pyrene (B[a]P), indeno[1,2,3-cd]pyrene (Ind), dibenz[a,h]anthracene (D[a,h]A), and benzo[g,h,i]perylene (B[g,h]P) in backwash deposits of the 2004 Khao Lak tsunami were carefully investigated and compared with the concentrations of world marine sediments (WMS). In general, ∑12PAHs in this study (i.e., 69.43±70.67ngg−1) were considerably lower than those values observed in marine sediments from Boston (54,253ngg−1), coastal sediments from Barcelona Harbour (15,069ngg−1), and riverine sediment from Guangzhou Channel (12,525ngg−1), but were greater than values from coastal sediments in Rosas Bay (12ngg−1), Santa Ponsa Bay (26ngg−1) and Le Planier (34ngg−1). The total toxic benzo[a]pyrene equivalent (TEQCarc) values calculated for Khao Lak coastal sediments (KCS), Khao Lak terrestrial soils (KTS), and Songkhla Lake sediments (SLS) were 10.3±12.2ngg−1, 16.0±47.7ngg−1, and 5.67±5.39ngg−1, respectively. Concentrations of PAHs at all study sites resulted in risk levels that fell into the “acceptable” range of the US EPA model and were much lower than those of other WMS. The cancer risk levels of PAH content in KCS ranged from 7.44×10−8 to 2.90×10−7, with an average of 1.64×10−7±8.01×10−8; this value is 119 times lower than that of WMS. In addition, soil cleanup target levels (SCTLs) for both non-carcinogens (i.e., Phe, An, Fluo and Pyr) and carcinogens (i.e., B[a]A, Chry, B[b]F, B[k]F, B[a]P, Ind, D[a,h]A and B[g,h,i]P) in the KTS samples were estimated for all target groups, with an average value of 115,902±197,229ngg−1.
Mostrar más [+] Menos [-]Toxicological impact assessment of heavy metal contamination on macrobenthic communities in southern coastal sediments of Korea Texto completo
2013
Lim, Dhong-il | Choi, Jin-Woo | Shin, Hyeon Ho | Jeong, Do Hyun | Jung, Hoi Soo
In the heavily industrialized Masan Bay of southern coast, Korea, the potential harmful effects of heavy metals (Cd, Co, Cu, Ni, Pb, Sn, Zn, and Hg) were evaluated in terms of the pollution load index (PLI) and ecological risk assessment index (ERI) methods, and the results obtained were considered alongside the health of the macrobenthic fauna communities. The results revealed that the bay sediments, especially in the inner bay and the outfall area of a sewage treatment plant, are exposed to moderate to serious levels of metal pollution. Hg and Cd contributed the most to the potential toxicity response indices in sediments recently deposited in the bay. The potential ecological risk assessment of heavy metals in the bay was highlighted by the use of the benthic biological pollution index (BPI), suggesting that the ERI is a useful toxicity response index, which can quantify the overall ecological risk level to a target environment.
Mostrar más [+] Menos [-]Trace element content of seagrasses in the Leschenault Estuary, Western Australia Texto completo
2013
Kilminster, Kieryn
Estuarine environments are particularly vulnerable to human impacts. In this study, trace elements in Ruppia megacarpa, Halophila ovalis, sediment and porewater were analysed to assess the potential contamination of the Leschenault Estuary, Western Australia, from a primarily agricultural drain. Sediment concentrations of Cd, Cu, Mn, and Ni and were highest nearest the drain while Al, As, Cr, Fe and Zn and were highest further from the drain. H. ovalis showed greater accumulation of Fe, Al, and As than R. megacarpa. Concentrations of Fe, Al, As, and Ni were generally higher in below-ground plant parts than above, suggesting uptake of these trace elements via the sediment-route pathway. This study suggested that the drain was a source of Cu and Mn, with these elements entering the estuary through water inflows. As and Fe, were highest furthest from the drain suggesting input of trace elements from sources other than the drain under study.
Mostrar más [+] Menos [-]Does boat traffic cause displacement of fish in estuaries? Texto completo
2013
Becker, Alistair | Whitfield, Alan K. | Cowley, Paul D. | Järnegren, Johanna | Næsje, Tor F.
Estuaries are increasingly under threat from a variety of human impacts. Recreational and commercial boat traffic in urban areas may represent a significant disturbance to fish populations and have particularly adverse effects in spatially restricted systems such as estuaries. We examined the effects of passing boats on the abundance of different sized fish within the main navigation channel of an estuary using high resolution sonar (DIDSON). Both the smallest (100–300mm) and largest (>501mm) size classes had no change in their abundance following the passage of boats. However, a decrease in abundance of mid-sized fish (301–500mm) occurred following the passage of boats. This displacement may be attributed to a number of factors including noise, bubbles and the rapidly approaching object of the boat itself. In highly urbanised estuarine systems, regular displacement by boat traffic has the potential to have major negative population level effects on fish assemblages.
Mostrar más [+] Menos [-]Major and minor element geochemistry of deep-sea sediments in the Azores Platform and southern seamount region Texto completo
2013
Palma, Carla | Oliveira, Anabela | Valença, Manuela | Cascalho, João | Pereira, Eduarda | Lillebø, Ana I. | Duarte, Armando C. | Pinto de Abreu, Manuel
Major and minor element geochemistry of deep-sea sediments in the Azores Platform and southern seamount region Texto completo
2013
Palma, Carla | Oliveira, Anabela | Valença, Manuela | Cascalho, João | Pereira, Eduarda | Lillebø, Ana I. | Duarte, Armando C. | Pinto de Abreu, Manuel
The Azores Platform and the Irving and Great Meteor seamounts south of the archipelago (38°N–29°N) have rarely been studied geochemically, a fact which is surprising given that they represent the south-eastern limit of region V outlined in the Convention for the Protection of the Marine Environment of the North-East Atlantic (OSPAR Convention). The main aim of the present work was therefore to characterise the spatial variability of major and minor elements in deep-sea sediment cores from these two regions. XRD and geochemical analyses revealed that whereas the Azores Platform sediments are composed of a mixture of biogenic and detrital volcanic material, those at the seamounts are characterised by carbonated biogenic remains. The latter sediments were found to contain very low amounts of volcanic or hydrothermal detrital material, being almost entirely comprised of CaCO3 (more than 80%).
Mostrar más [+] Menos [-]Major and minor element geochemistry of deep-sea sediments in the Azores Platform and southern seamount region Texto completo
2013
Palma, Carla | Oliveira, Anabela | Valença, Manuela | Cascalho, João | Pereira, Eduarda | Lillebø, Ana I. | Duarte, Armando C. | Pinto de Abreu, Manuel
The Azores Platform and the Irving and Great Meteor seamounts south of the archipelago (38°N-29°N) have rarely been studied geochemically, a fact which is surprising given that they represent the south-eastern limit of region V outlined in the Convention for the Protection of the Marine Environment of the North-East Atlantic (OSPAR Convention). The main aim of the present work was therefore to characterise the spatial variability of major and minor elements in deep-sea sediment cores from these two regions. XRD and geochemical analyses revealed that whereas the Azores Platform sediments are composed of a mixture of biogenic and detrital volcanic material, those at the seamounts are characterised by carbonated biogenic remains. The latter sediments were found to contain very low amounts of volcanic or hydrothermal detrital material, being almost entirely comprised of CaCO3(more than 80%). | published
Mostrar más [+] Menos [-]Growth and survival of Halimione portulacoides stem cuttings in heavy metal contaminated soils Texto completo
2013
Andrades-Moreno, L. | Cambrollé, J. | Figueroa, M.E. | Mateos-Naranjo, E.
The halophytic shrub Halimione portulacoides demonstrates a high tolerance to heavy metal contamination and a capacity for accumulating metals within its tissues. On the Iberian Peninsula, this species has colonized habitats with high levels of metal pollution. The aim of this study is to analyze the response of H. portulacoides stem cuttings to this pollution. Growth, photosynthesis and metal uptake were examined in H. portulacoides through an experiment in which stem cuttings were replanted in metal-contaminated soil. This condition decreased growth and lowered both photosynthetic rate and stomatal conductance. Reduced photosynthetic performance was largely due to the reduced concentration of photosynthetic pigments. Despite these responses, there was some important evidence suggesting the phytoremediatory potential of Halimione stem cuttings. The results of our study indicate that this salt-marsh shrub may represent a biotool of value in the restoration of polluted areas.
Mostrar más [+] Menos [-]Impact evaluation of the industrial activities in the Bay of Bakar (Adriatic Sea, Croatia): Recent benthic foraminifera and heavy metals Texto completo
2013
Popadić, Adriana | Vidović, Jelena | Ćosović, Vlasta | Medaković, Davorin | Dolenec, Matej | Felja, Igor
The Bay of Bakar is one of the most heavily polluted bays at the Eastern Adriatic. Three major industrial companies potentially endanger the bay. The concentration of major, minor and trace elements in surface sediments from thirteen stations was discussed in relation to the sediment type and foraminiferal assemblages. The distribution of major elements in the bay is influenced by geological nature of surroundings. Heavy metal distribution depends on pollution sources and on amount of mud fraction: fine-grained sediments are enriched by them in comparison with coarse-grained ones. Different sediment quality criteria complicate the pollution assessment in the bay. Heavy metal concentrations generally fall into allowed depositional values for marine environments; only area in front of the coke plant and the City of Bakar harbor is heavily polluted. Stress-tolerant foraminiferal species dominate at stations with higher concentrations of heavy metals and coarse-grained sediments consist of larger number of epifaunal taxa.
Mostrar más [+] Menos [-]Fate of antibiotics during wastewater treatment and antibiotic distribution in the effluent-receiving waters of the Yellow Sea, northern China Texto completo
2013
Zhang, Hanmin | Liu, Pengxiao | Feng, Yujie | Yang, Fenglin
Antibiotics including three β-lactams, two fluoroquinolones and two macrolides, which were the top seven most prescribed antibiotics in Dalian, China, were selected to investigate their occurrence in six municipal wastewater treatment plants (WWTPs) and their distribution in the effluent-receiving waters of the Yellow Sea. Four WWTPs employing different treatment technologies were selected to explore the mechanism of antibiotics elimination during wastewater treatment. Results showed that fluoroquinolones and macrolides were dominant species in both WWTPs effluents and the surveyed coastal waters. Biodegradation was the main pathway for β-lactams removal, however, primary treatment performed better than biological treatment for fluoroquinolones removal. Concentrations of macrolides increased dramatically after the biological treatment, which was probably due to the release of macrolides enclosed in feces particles. In the surveyed coastal waters, reduction of antibiotic concentration with distance was observed. Potential environmental risk caused by the occurrence of these antibiotics should be evaluated in future work.
Mostrar más [+] Menos [-]Trace metals associated with deep-sea tailings placement at the Batu Hijau copper–gold mine, Sumbawa, Indonesia Texto completo
2013
Angel, Brad M. | Simpson, Stuart L. | Jarolimek, Chad V. | Jung, Rob | Waworuntu, Jorina | Batterham, Grant
The Batu Hijau copper–gold mine on the island of Sumbawa, Indonesia operates a deep-sea tailings placement (DSTP) facility to dispose of the tailings within the offshore Senunu Canyon. The concentrations of trace metals in tailings, waters, and sediments from locations in the vicinity of the DSTP were determined during surveys in 2004 and 2009. In coastal and deep seawater samples from Alas Strait and the South Coast of Sumbawa, the dissolved concentrations of Ag, As, Cd, Cr, Hg, Pb and Zn were in the sub μg/L range. Dissolved copper concentrations ranged from 0.05 to 0.65μg/L for all depths at these sites. Dissolved copper concentrations were the highest in the bottom-water from within the tailings plume inside Senunu Canyon, with up to 6.5μg Cu/L measured in close proximity to the tailings discharge. In general, the concentrations of dissolved and particulate metals were similar in 2004 and 2009.
Mostrar más [+] Menos [-]DNA strand breaks (comet assay) in blood lymphocytes from wild bottlenose dolphins Texto completo
2013
Lee, Richard F. | Bulski, Karrie | Adams, Jeffrey D. | Peden-Adams, Margie | Bossart, Gregory D. | King, Lydia | Fair, Patricia A.
The comet assay was carried out on blood lymphocytes from a large number of wild dolphins (71 from Indian River Lagoon, FL, USA; 51 from Charleston Harbor, SC, USA) and provides a baseline study of DNA strand breaks in wild dolphin populations. There were no significant differences in the comet assay (%DNAintail) results between the different age and sex categories. Significant difference in DNA strand breaks were found between Charleston Harbor dolphins (median – 17.4%DNAintail) and Indian River Lagoon dolphins (median – 14.0%DNAintail). A strong correlation found between T-cell proliferation and DNA strand breaks in dolphin lymphocytes suggests that dolphins with a high numbers of DNA strand breaks have a decreased ability to respond to infection. Higher concentrations of genotoxic agents in Charleston Harbor compared with Indian River lagoon may have been one of the causes of higher DNA strand breaks in these dolphins.
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