Nitrogen-doped biochar loaded with FeS (FeS@NBCBM) was synthesized by two-step ball milling processes. Characterization results revealed that N-doping process successfully introduced pyridinic, pyrrolic, and graphitic N structures, and FeS was subsequently embedded in N-doped biochar (NBCBM). The resultant FeS@NBCBM presented predominant adsorption capacity for Cr(VI) (194.69 mg/g) and tetracycline (TC, 371.29 mg/g) compared with BC (27.28 and 37.89 mg/g) and NBCBM (71.26 and 81.26 mg/g). In addition, the Cr(VI)/TC elimination process by FeS@NBCBM was basically stable with multiple co-existing ions with slight decrease on adsorption performance after three desorption-regeneration cycles. Most importantly, FeS@NBCBM was found to achieve Cr(VI) elimination not only by electrostatic attraction, ion exchange and complexation, but also by electrons-triggered reduction provided by different species of N, Fe²⁺ as well as S(Ⅱ). Meantime, pore filling, hydrogen bonding, and π-π stacking interactions were demonstrated to contribute to TC adsorption. These results suggested the co-modification of N-doping and FeS loading by ball milling as an innovative decorating method for biochar to adsorptive purification of Cr(VI) and TC-contaminated water.

This study investigated whether lead (Pb), at concentrations allowed for soil, affects the community of insects that live in the aerial part of plants. We evaluated the effect of Pb concentrations on accumulated species richness, composition, and abundance of different functional groups of insects. Kale plants were grown in soil experimentally contaminated with four concentrations of lead nitrate: 0 (control), 144 (T1), 360 (T2), and 600 (T3) mg/kg of soil. The experiment was conducted in an open greenhouse for the natural colonization of insects. Insects were collected twice using trap bags attached to the plant leaf and by direct removal. The concentration of Pb in the stem and leaf samples increased with the increased soil contamination, even showing values above the limit allowed by the legislation for this plant species. Control plants showed a higher richness of accumulated insect species. In addition, the treatments had an effect on the community composition, in which Diaeretiella rapae (primary parasitoid) was found as an indicator of the control + T1 treatments and the top species Pachyneuron sp. (parasitoid of predators) was associated with the control. The abundance of chewing and sucking herbivores, their respective parasitoids, predators, and parasitoids of predators were negatively affected. Hyperparasitoid abundance was not affected, but their accumulated species richness was. This study was innovative in demonstrating that soil contamination by different concentrations of a heavy metal (Pb) can negatively affect the community of plant-associated insects, even at concentrations allowed for soil, reflecting possible damage to the ecosystem.

The objective of this work was to evaluate the adsorption capacity of alkylated modified porous biochar prepared by esterification and etherification (PSAC-2) for low concentrate volatile organic compounds (VOCs, toluene and ethyl acetate) in high humidity environment by experiments and theoretical calculations. Results showed that PSAC-2 has a large specific surface area and weak surface polarity, at 80% relative humidity, its capacities for toluene and ethyl acetate adsorption could be maintained at 92% and 87% of the initial capacities (169.9 mg/g and 96.77 mg/g). The adsorption behaviors of toluene, ethyl acetate, and water vapor were studied by adsorption isotherms, and isosteric heat was obtained. The desorption activation energy was obtained by temperature programmed desorption experiment. The outcomes manifested that the PSAC-2 can achieve strong adsorption performance for weakly polar molecules. Through density functional theory (DFT) simulations, owing to the interaction of hydrogen bonds, oxygen-containing groups became a significant factor influencing the adsorption of VOCs in humid environments. These results could provide an important reference for VOCs control in a high humidity environment.

The control of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from the flue gas in hazardous waste incinerators (HWIs) is an intractable problem. To figure out the formation mechanism of PCDD/Fs and reduce the emission, a field study was carried out in a full-scale HWI. Ca(OH)₂ & (NH₄)H₂PO₄ or CH₄N₂S & (NH₄)H₂PO₄ were injected into the quench tower, and the detailed inhibition effect on PCDD/Fs formation by the inhibitors coupled with quench tower was studied. Gas and ash samples were collected to analyze PCDD/Fs. XPS, EDS characterization and Principal component analysis were adopted to further analyze the de novo and precursors synthesis. The PCDD/Fs emissions reduced from 0.135 ng I-TEQ/Nm³ to 0.062 or 0.025 ng I-TEQ/Nm³ after the injection of Ca(OH)₂ & (NH₄)H₂PO₄ or CH₄N₂S & (NH₄)H₂PO₄, respectively. The quench tower was found mainly hindering de novo synthesis by reducing reaction time. CP-route was the dominant formation pathway of PCDD/Fs in quench tower ash. Ca(OH)₂ & (NH₄)H₂PO₄ effectively inhibit precursors synthesis and reduce proportions of organic chlorine from 4.11% to 2.86%. CH₄N₂S & (NH₄)H₂PO₄ show good control effects on both de novo and precursors synthesis by reducing chlorine content and inhibiting metal-catalysts. Sulfur-containing inhibitors can cooperate well with the quench tower to inhibit PCDD/Fs formation and will be effective to reduce dioxins formation in high chlorine flue gas. The results pave the way for further industrial application of inhibition to reduce PCDD/Fs emissions in the HWIs flue gas.

The analysis of microplastics in complex environmental samples requires the use of chemicals to reduce the organic matrix. This procedure should be evaluated in terms of the preservation of the microplastic's integrity, typically done with pristine reference microplastics. However, real microplastics are most likely degraded due to weathering, so pristine reference microplastics might not depict the appropriateness of the process. This study performed a purification process using sodium dodecyl sulfate and hydrogen peroxide on sewage sludge containing LLDPE, HDPE, PP, PS, PET, PA66 and SBR samples exposed to simulated environmental weathering. The degradation of the polymers was assessed by analyzing surface morphology, mass variation, and mechanical, thermal and chemical properties. Comparison with pristine polymers revealed that the purification process can lead to more detrimental effects if the polymers are weathered. After the purification process, some important observations were: 1) LLDPE, PP and SBR surfaces had cracks in the weathered samples that were not observed in the pristine samples, 2) weathered LLDPE, PP and PA66 experienced greater mass loss than pristine, 3) the fragmentation propensity of weathered LLDPE, HDPE, PP, PS and SBR increased compared to pristine samples and 4) the main characteristic peaks in FTIR spectrum could be identified and used for chemical identification of most polymers for pristine and weathered samples. Based on the findings of this study, when analyzing the efficiency and adequacy of a purification process with methods based on surface morphology, mass variation and particle counting indicators, it is recommended to consider the differences that potentially arise between pristine and weathered microplastics, especially for polyolefins (PEs and PP).

The geochemistry of iron (Fe), manganese (Mn) and sulfur (S) and their effects on arsenic (As) mobility in the mudflats of small river estuaries remain unclear. Here, diffusive gradient in thin films (DGT) and high-resolution dialysis (HR-Peeper) techniques combined with a sequential extraction procedure (BCR) were employed to investigate As, Fe, Mn and S geochemistry in the mudflat of the Jiuxi River estuary, Southeast China. Grain size analysis indicated that fine-grained particles were likely to be deposited in the estuarine intertidal zone and coastal area. DGT and HR-Peeper results revealed that in the estuary and coastal area, the dissolved As in sediment in summer was controlled by Mn geochemistry, which includes not only the release of As through Mn/Fe reduction but also the stabilization of dissolved As in pore water. This stabilization of dissolved As may due to the formation of As–Mn-OM complexes. In winter, the significant positive correlations between DGT-Fe, DGT-Mn, DGT-As and DGT-S indicated that sulfate reduction was the start of As mobilization in sediment in winter. In both the estuary and the coastal area, the easily reducible Fe, Mn and As contents in intertidal sediment were higher than those in the subtidal zone. Combined with the As flux across the sediment-overlying water interface (SWI), these phenomena suggested that As in subtidal sediment diffused into overlying water and that As in overlying water tended to accumulate in the intertidal sediment. The total organic carbon content (TOC) and DGT results in the lower reach, estuary and coastal areas indicated that organic matter is the controlling factor of Fe/Mn reduction, sulfate reduction and As mobilization. The BCR test results showed higher reactive fraction contents of Fe, Mn and As in winter sediment, which threaten the overlying water quality.

Polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) share similar toxicities and thermal origins, e.g., municipal solid waste incinerator (MSWI). Recently, PBDD/Fs from MSWI attracted rising concern because their important precursors, i.e., brominated flame retardants (BFRs), were frequently found in various wastes for landfill or MSWI feedstock. So far, however, little is known about PBDD/Fs and their associated risks in the vicinal environments of MSWI. Here we analyzed PBDD/Fs and PCDD/Fs in 29 soil samples collected around a multiyear large-scale MSWI, and compared their spatial distributions, sources and risks. PBDD/Fs demonstrated comparable concentrations and toxic equivalent quantities (TEQs) to PCDD/Fs in these samples. Spatially, both the concentrations of PBDD/Fs and PCDD/Fs decreased outwards from the MSWI, and exhibited significant linear correlations with the distances from the MSWI in the southeast downwind soil, suggesting the influence of the MSWI on its vicinal soil environment. However, the existence of other dioxin sources concealed its influence beyond 6 km. PBDD/Fs in the soils were characterized by highly-brominated PBDFs, especially Octa-BDF, and their sources were diagnosed as the MSWI and diesel exhaust; PCDD/Fs, however, were dominated by highly-chlorinated PCDDs, particularly Octa-CDD, and were contributed individually or jointly by the MSWI, automobile exhaust and pentachlorophenol (PCP)/Na-PCP. The non-carcinogenic risks of dioxins in all the soil samples were acceptable, but their carcinogenic risks in 17% of the samples were unacceptable. These samples were all located close to the MSWI and highways, therefore, the land use of these two high-risk zones should be cautiously planed.

Plastic film mulching and use of wastewaters for irrigation have been common agricultural practices for over half a century in Tunisia, especially in arid regions, resulting in the undesired creation of a pathway for microplastics (MPs) to enter farmland soil. In order to assess the extent and characteristics of soil contamination by MPs in the Moknine province, an area of intensive agricultural practices, 16 farmland soil samples were collected and characterized. The total concentration of targeted MPs was 50–880 items/kg; among them, the most common MPs type being polypropylene (PP), mainly occurring as white/transparent fibers with small size (cross section <0.3 mm). SEM images of MPs surfaces revealed multiple features related to environmental exposure and degradation. ATR-FTIR spectroscopy and pyrolysis-GC/MS analyses enabled the accurate identification of MPs separated from the embedding soil micro- and macro-aggregates. Finally, contamination of the polymeric microparticles with a broad range of metals was found by ICP-MS analysis, suggesting that MPs can be vectors for transporting heavy metals in the soil and indicators of soil contamination as a result of mismanagement of industrial wastewaters.

Polychlorinated biphenyls (PCBs) are a class of persistent organic pollutants (POPs) that have adverse effects on human health. However, the long-term health effects and potential mechanism of neonatal exposure to PCBs are still unclear. In this study, nursing male mice exposed to PCB138 at 0.5, 5, and 50 μg/kg body weight (bw) from postnatal day (PND) 3 to PND 21 exhibited increased serum uric acid levels and liver uric acid synthase activity at 210 days of age. We also found an increased kidney somatic index in the 50 μg/kg group and kidney fibrosis in the 5 and 50 μg/kg groups. Mechanistically, PCB138 induced mitochondrial dysfunction and endoplasmic reticulum (ER) stress, which might have led to inflammatory responses, such as activation of the NF-κB (nuclear factor kappa-B) and NLRP3 (NOD-like receptor protein 3) pathways. The inflammatory response might regulate renal fibrosis and hypertrophy. In summary, this study reports a long-term effect of neonatal PCB exposure on uric acid metabolism and secondary nephrotoxicity and clarifies the underlying mechanism. Our work also indicates that early life pollutant exposure may be an important cause of diseases later in life.

Selenium is an essential trace element for humans and obtained from diary diets. The consumption of selenium-rich agricultural food is an efficient way to obtain selenium, but the quality and safety of selenium-rich agro-food are always affected by their associated heavy metals, even poses a potential threaten to human health. In this research, a sampling survey of heavy metals contents in selenium-rich rice was conducted, 182 sets of selenium-rich rice samples were collected from five selenium-rich rice-producing areas of China, and the accumulation of selenium and cadmium were found to be associated in rice and soil. Subsequently, a pot experiment was performed in the greenhouse via treating the soil samples with 12 different concentrations of selenium and heavy metals, and the contents of selenium and cadmium in rice grain were confirmed to be significantly associated. Moreover, transcriptome analysis revealed that the up-regulation of transporter-coding may promote the absorption of selenium and cadmium. The expression of antioxidant-coding genes and cadmium chelator transporter coding-genes was up-regulated to reduce the toxicity of cadmium. Meanwhile, the up-regulation of key genes of the ascorbic acid-glutathione metabolic pathway were responsible for the association between selenium and cadmium in Se-rich rice. Our work suggested the correlation between selenium and cadmium accumulation in selenium-rich rice, clarified their accumulation mechanism, provides a direction for the scientific production of selenium-rich agro-foods.