Synthesis of (+-)-sundiversifolide based on Lewis acid-mediated Claisen rearrangement
2007
Hashimoto, T.(Kobe Univ. (Japan)) | Tashiro, T. | Sasaki, M. | Takikawa, H.
A new and concise synthesis of (+-)-sundiversifolide (1), an allelopathic bisnor-sesquiterpene lactone isolated from germinating sunflower (Helianthus annuus L.) seeds, was achieved by employing Lewis acid-mediated Claisen rearrangement as the key step.
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