Automated synthesis of a tri-branched pentasaccharide: The application of the uni-chemo hydroxyl protection method to the automated synthesis of oligosaccharides
2009
Komba, S.(National Food Research Inst., Tsukuba, Ibaraki (Japan)) | Terauchi, T. | Machida, S.
A special hydroxyl protecting group, the uni-chemo hydroxyl protection (UCHP), was applied to automated oligosaccharide synthesis. The UCHP is a newly developed hydroxyl protecting group, which is comprised of oligomeric amino acid derivatives. The UCHP method is able to deprotect one hydroxyl after another, selectively, by repeating a simple deprotection protocol. The use of the UCHP group facilitated the automated synthesis of a tri-branched pentasaccharide.
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