Insertion of Arynes into N-Halo Bonds: A Direct Approach to o-Haloaminoarenes
2013
Hendrick, Charles E. | McDonald, Stacey L. | Wang, Qiu
A new approach to access o-haloaminoarenes has been achieved by insertion of arynes into a nitrogen–halide bond (N–X). This transition-metal-free transformation displays a broad substrate scope of arynes, good compatibility with functional groups, and high regioselectivity. Representative transformations of the o-haloaminoarenes are described to highlight their utility for rapid access to diversely functionalized aminoarene derivatives.
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